255897-36-0 (2,2-双(二环己膦基)-1,1-联苯,Phosphine,1,1'-[1,1'-biphenyl]-2,2'-diylbis[1,1-dicyclohexyl-)

CAS号:
255897-36-0
中文名称:
2,2-双(二环己膦基)-1,1-联苯
英文名称:
Phosphine,1,1'-[1,1'-biphenyl]-2,2'-diylbis[1,1-dicyclohexyl-
分子式:
C36H52P2
分子量:
546.74561214447

2,2-双(二环己膦基)-1,1-联苯(255897-36-0)名称与标识符

名称

中文别名:
2,2'-双(二环己基膦)-1,1'-联苯;2,2'' - 双(二环己基)-1,1'' - 联苯;2,2' - 双(二环己基)-1,1' - 联苯;2,2''-双(二环己膦基)-1,1''-联苯;2,2-双(二环己膦基)-1,1-联苯;1,1'-联苯-2,2'-二基双(二环己基膦);
英文别名:
Phosphine,1,1'-[1,1'-biphenyl]-2,2'-diylbis[1,1-dicyclohexyl-;2,2'-Bis(dicyclohexylphosphino)-1,1'-biphenyl;dicyclohexyl-[2-(2-dicyclohexylphosphanylphenyl)phenyl]phosphane;1,1'-Biphenyl-2,2'-diylbis(dicyclohexylphosphine);2-(dicyclohexylphosphino)biphenyl;AG-E-78680;Phosphine,[1,1'-biphenyl]-2,2'-diylbis[dicyclohexyl- (9CI);MFCD07368358;2,2'-bis(dicyclohexylphosphino)biphenyl;2,2'-bis-dicyclohexylphosphanyl-biphenyl;SCHEMBL520084;FT-0716184;255897-36-0;dicyclohexyl-({2-[2-(dicyclo hexylphosphanyl)phenyl]phenyl})phosphane;CS-0035221;D94916;BSSFMHHLTVJPGW-UHFFFAOYSA-N;DTXSID20648049;([1,1'-Biphenyl]-2,2'-diyl)bis(dicyclohexylphosphane);2,2a?Bis(dicyclohexylphosphino)biphenyl;DB-009476;dicyclohexyl[2'-(dicyclohexylphosphanyl)-[1,1'-biphenyl]-2-yl]phosphane;

标识符

MDL:
MFCD07368358
InChIKey:
BSSFMHHLTVJPGW-UHFFFAOYSA-N
Inchi:
1S/C36H52P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h13-16,25-32H,1-12,17-24H2
SMILES:
P(C1=CC=CC=C1C1=CC=CC=C1P(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1

2,2-双(二环己膦基)-1,1-联苯(255897-36-0)物化性质

实验特性

  • LogP : 10.89880
  • PSA : 27.18000
  • 溶解度 : Insuluble (8.2E-9 g/L) (25 ºC),
  • 颜色与性状 : 无可用
  • 溶解性 : 无可用

计算特性

  • 精确分子量 : 546.35400
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 7
  • 同位素质量 : 546.354
  • 重原子数量 : 38
  • 复杂度 : 573
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 9.9
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0A^2

2,2-双(二环己膦基)-1,1-联苯(255897-36-0)推荐厂家 更多厂家(12)

2,2-双(二环己膦基)-1,1-联苯(255897-36-0) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       2,2'-Bis(dicyclohexylphosphino)-1,1'-biphenyl, min. 97%    
   CAS Registry Number:       255897-36-0    
   Formula:       C36H52P2    
   EINECS Number:       none    
   Chemical Family:       organophosphine ligand    
   Synonym:       2,2'-Bis-dicyclohexylphosphanyl-biphenyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       255897-36-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes irritation to eyes    
   Skin Contact:       Causes irritation to skin    
   Inhalation:       Inhalation of dust is irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to pale yellow powder    
   Molecular Weight:       546.75    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorus pentoxide, organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A