25756-87-0 ((Phosphinous acid(6CI,8CI,9CI))

快速询单

结构式：

Phosphinous acid(6CI,8CI,9CI)MOL文件

CAS号：

25756-87-0

英文名称：

Phosphinous acid(6CI,8CI,9CI)

分子式：

H₃OP

分子量：

49.9969809055328

Phosphinous acid(6CI,8CI,9CI)(25756-87-0)名称与标识符

名称

英文别名：

Phosphinous acid(6CI,8CI,9CI);Hydroxyphosphine;phosphinous acid;HPH2O;[PH2(OH)];Q27109992;hydroxyphosphorane;CHEBI:29260;25756-87-0;DTXSID80276387;dihydridohydroxidophosphorus;

标识符

InChIKey：

RYIOLWQRQXDECZ-UHFFFAOYSA-N

Inchi：

1S/H3OP/c1-2/h1H,2H2

SMILES：

Phosphinous acid(6CI,8CI,9CI)(25756-87-0)物化性质

实验特性

PSA : 20.23

计算特性

精确分子量 : 49.99219
氢键供体数量 : 1
氢键受体数量 : 1
可旋转化学键数量 : 0
同位素质量 : 49.992151713g/mol
重原子数量 : 2
复杂度 : 2
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : -0.6
拓扑分子极性表面积 : 20.2Å²

Phosphinous acid(6CI,8CI,9CI)(25756-87-0)相关文献

1. Coordination chemistry and catalysis with secondary phosphine oxides
Albert Gallen,Antoni Riera,Xavier Verdaguer,Arnald Grabulosa Catal. Sci. Technol. 2019 9 5504
2. Diastereoselective desymmetrization of diarylphosphinous acid-borane amides under Birch reduction
Marek Stankevi? Org. Biomol. Chem. 2015 13 6082
3. Synthesis and coordination chemistry of enantiopure t-BuMeP(O)H
Albert Gallen,Sílvia Orgué,Guillermo Muller,Eduardo C. Escudero-Adán,Antoni Riera,Xavier Verdaguer,Arnald Grabulosa Dalton Trans. 2018 47 5366
4. Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands
Sílvia Orgué,Areli Flores-Gaspar,Maria Biosca,Oscar Pàmies,Montserrat Diéguez,Antoni Riera,Xavier Verdaguer Chem. Commun. 2015 51 17548
5. Secondary phosphine oxide-triggered selective oxygenation of a benzyl ligand on palladium
Sayaka Oka,Yuma Shigehiro,Yasutaka Kataoka,Yasuyuki Ura Chem. Commun. 2020 56 12977
6. Highly efficient and well-defined phosphinous acid-ligated Pd(ii) precatalysts for Hirao cross-coupling reaction
Li-Hui Hong,Wei-Jung Feng,Wei-Chih Chen,Yu-Chang Chang Dalton Trans. 2023 52 5101
7. [RuCl2(η6-p-cymene)] complexes bearing phosphinous acid ligands: preparation, application in C–H bond functionalization and mechanistic investigations
Lionel V. Graux,Michel Giorgi,Gérard Buono,Hervé Clavier Dalton Trans. 2016 45 6491
8. Bis(allyl)-ruthenium(iv) complexes with phosphinous acid ligands as catalysts for nitrile hydration reactions
Eder Tomás-Mendivil,Javier Francos,Rebeca González-Fernández,Pedro J. González-Liste,Javier Borge,Victorio Cadierno Dalton Trans. 2016 45 13590
9. Catalytic hydration of cyanamides with phosphinous acid-based ruthenium(ii) and osmium(ii) complexes: scope and mechanistic insights
Rebeca González-Fernández,Daniel álvarez,Pascale Crochet,Victorio Cadierno,M. Isabel Menéndez,Ramón López Catal. Sci. Technol. 2020 10 4084
10. Chlorophosphines as auxiliary ligands in ruthenium-catalyzed nitrile hydration reactions: application to the preparation of β-ketoamides
Rebeca González-Fernández,Pedro J. González-Liste,Javier Borge,Pascale Crochet,Victorio Cadierno Catal. Sci. Technol. 2016 6 4398