287-36-5 ((1,2-Oxaphosphetane)

快速询单

结构式：

1,2-OxaphosphetaneMOL文件

CAS号：

287-36-5

英文名称：

1,2-Oxaphosphetane

分子式：

C₂H₅OP

分子量：

76.0342614650726

1,2-Oxaphosphetane(287-36-5)名称与标识符

名称

英文别名：

1,2-Oxaphosphetane;oxaphosphetane;DTXSID90633467;287-36-5;

标识符

InChIKey：

JONKIUBSNSUGGZ-UHFFFAOYSA-N

Inchi：

1S/C2H5OP/c1-2-4-3-1/h4H,1-2H2

SMILES：

P1CCO1

1,2-Oxaphosphetane(287-36-5)物化性质

实验特性

LogP : 0.61010
PSA : 9.23

计算特性

精确分子量 : 76.00785
氢键供体数量 : 0
氢键受体数量 : 1
可旋转化学键数量 : 0
同位素质量 : 76.007801776g/mol
重原子数量 : 4
复杂度 : 22
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : -0.3
拓扑分子极性表面积 : 9.2Å²

1,2-Oxaphosphetane(287-36-5)相关文献

1. Ring opening of a sterically crowded 1,2-oxaphosphetane complex
A. W. Kyri,P. Brehm,G. Schnakenburg,R. Streubel Dalton Trans. 2017 46 2904
2. “Low-coordinate” 1,2-oxaphosphetanes – a new opportunity in coordination and main group chemistry
A. W. Kyri,F. Gleim,A. García Alcaraz,G. Schnakenburg,A. Espinosa Ferao,R. Streubel Chem. Commun. 2018 54 7123
3. A novel route to C-unsubstituted 1,2-oxaphosphetane and 1,2-oxaphospholane complexes
A. W. Kyri,G. Schnakenburg,R. Streubel Chem. Commun. 2016 52 8593
4. The crystal structure of a Wittig intermediate containing a fourmembered ring. 4,4-Bis(trifluoromethyl)2,2,2-triphenyl-3-(triphenyl-phosphoranylidene)-1,2-oxaphosphetane
G. Chioccola,J. J. Daly J. Chem. Soc. A 1968 568
5. Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands
Andreas Wolfgang Kyri,Florian Gleim,David Biskup,Gregor Schnakenburg,Arturo Espinosa Ferao,Rainer Streubel Chem. Commun. 2019 55 1615
6. Microwave-assisted periselective annulation of triarylphosphenes with aldehydes and ketones
Yun Luo,Zhicheng Fu,Xingyang Fu,Changle Du,Jiaxi Xu Org. Biomol. Chem. 2020 18 9526
7. Synthesis of 1,2-oxaphosphinane 2-oxides and 1,2-oxaphosphinine 2-oxides: δ-phosphonolactones and δ-phosphinolactones
Jiaxi Xu New J. Chem. 2023 47 5441
8. Synthesis of 1,2-oxaphosphinane 2-oxides and 1,2-oxaphosphinine 2-oxides: δ-phosphonolactones and δ-phosphinolactones
Jiaxi Xu New J. Chem. 2023 47 5441
9. Benchmarking the inversion barriers in σ3λ3-phosphorus compounds: a computational study
Arturo Espinosa Ferao,Antonio García Alcaraz New J. Chem. 2020 44 8763
10. Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes
Jesús García-López,Emma Peralta-Pérez,Angela Forcén-Acebal,Santiago García-Granda,Fernando López-Ortiz Chem. Commun. 2003 856