295-14-7 (1,4,7,10-四氮环十四烷,1,4,7,10-Tetraazacyclotridecane)

快速询单

结构式：

1,4,7,10-四氮环十四烷MOL文件

CAS号：

295-14-7

中文名称：

1,4,7,10-四氮环十四烷

英文名称：

1,4,7,10-Tetraazacyclotridecane

分子式：

C₉H₂₂N₄

分子量：

186.297781467438

1,4,7,10-四氮环十四烷(295-14-7)名称与标识符

名称

中文别名：

1,4,7,10-四氮环十四烷;1,4,7,10-四氮杂环十三烷;

英文别名：

1,4,7,10-Tetraazacyclotridecane;1,4,7,10-tetrazacyclotridecane;1,4,7,10-tetra-azacyclotridecane;1,4,7,11-tetraazacyclotridecane;1,4,7,8-tetra-azacyclotridecane;Cyclam 13;CHEMBL4518637;FT-0690538;DTXSID50467124;1, 4, 7, 10-tetrazacyclotridecane;295-14-7;SCHEMBL361036;LADZJJOUGVGJHM-UHFFFAOYSA-N;AKOS025295074;CS-0106263;MFCD06410986;

标识符

MDL：

MFCD06410986

InChIKey：

LADZJJOUGVGJHM-UHFFFAOYSA-N

Inchi：

1S/C9H22N4/c1-2-10-4-6-12-8-9-13-7-5-11-3-1/h10-13H,1-9H2

SMILES：

N1CCNCCNCCNCCC1

1,4,7,10-四氮环十四烷(295-14-7)物化性质

实验特性

LogP : 0.06370
PSA : 48.12000
折射率 : 1.425
水溶性 : Soluble in water.
沸点 : 300.5°Cat760mmHg
熔点 : 143 ºC
蒸气压 : 0.0±0.6 mmHg at 25°C
闪点 : 139.7°C
溶解度 : 极易溶解 (1000 g/L) (25 ºC),
颜色与性状 : 不可用
溶解性 : 不可用
敏感性 : Hygroscopic
密度 : 0.867±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

精确分子量 : 186.18400
氢键供体数量 : 4
氢键受体数量 : 4
可旋转化学键数量 : 0
同位素质量 : 186.18444672g/mol
重原子数量 : 13
复杂度 : 95.8
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : -1.4
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 48.1Å²

1,4,7,10-四氮环十四烷(295-14-7)安全信息

安全说明： H303+H313+H333
危害声明：H303+H313+H333
警示性声明：P264+P280+P305+P351+P338+P337+P313
储存条件： storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
信号词： warning

1,4,7,10-四氮环十四烷(295-14-7)海关数据

海关编码：

2933990090

海关数据：

中国海关编码：

2933990090

概述：

2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素：

品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

Summary：

2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1,4,7,10-四氮环十四烷(295-14-7)推荐厂家更多厂家(5)

公司名称	手机号/电话	联系人	QQ	询单
郑州阿尔法化工有限公司	15324716602 0371-55013243	刘经理	2853979810	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
上海阿拉丁生化科技股份有限公司	13167063860 13167063860	阿拉丁	3004013043	询单

1,4,7,10-四氮环十四烷(295-14-7)相关文献

1. Co-ordination of 1,4,7,10-tetraazacyclotridecane ([13]aneN4) to nickel(III). Crystal structure of [Ni([13]aneN4)Br2]Br
Hiroshi Miyamae,Kazuyo Yamauchi,Masahiro Yamashita J. Chem. Soc. Dalton Trans. 1991 2921
2. New macrocyclic dioxotetraamines bearing 2-pyridylmethyl as functional donor pendant(s): synthesis, properties and crystal structure of their copper(II) complexes??
Xian He Bu,Xi Chuan Cao,Dao Li An,Ruo Hua Zhang,Clifford Thomas,Eiichi Kimura J. Chem. Soc. Dalton Trans. 1998 433
3. A [two-step/one week] synthesis of C-functionalized homocyclens and cyclams. Application to the preparation of conjugable BCAs without chelating properties alteration
Nathalie Camus,Zakaria Halime,Nathalie le Bris,Hélène Bernard,Maryline Beyler,Carlos Platas-Iglesias,Rapha?l Tripier RSC Adv. 2015 5 85898
4. The 13-membered macrocyclic effect. Polarographic studies of copper(II)-1,4,7,10-tetra-azacyclotridecane complexation
Mutsuo Kodama,Eiichi Kimura J. Chem. Soc. Chem. Commun. 1975 891
5. New 1,4,7,10-tetraazacyclotridecane-11,13-dione ligands appended with additional donor(s) 8-methylquinoline(s): crystal structures and characterization of their copper(II) complexes
Xian He Bu,Dao Li An,Yun Ti Chen,Mitsuhiko Shionoya,Eiichi Kimura J. Chem. Soc. Dalton Trans. 1995 2289
6. Kinetics of acid-catalysed dissociation of tetraazamacrocyclic ligand complexes of copper(II)
Wei-Jen Lan,Chung-Sun Chung J. Chem. Soc. Dalton Trans. 1994 191
7. Kinetics of acid-catalysed dissociation of tetraazamacrocyclic ligand complexes of copper(II)
Wei-Jen Lan,Chung-Sun Chung J. Chem. Soc. Dalton Trans. 1994 191
8. Kinetics of acid-catalysed dissociation of tetraazamacrocyclic ligand complexes of copper(II)
Wei-Jen Lan,Chung-Sun Chung J. Chem. Soc. Dalton Trans. 1994 191
9. Kinetics of acid-catalysed dissociation of tetraazamacrocyclic ligand complexes of copper(II)
Wei-Jen Lan,Chung-Sun Chung J. Chem. Soc. Dalton Trans. 1994 191
10. When ring makes the difference: coordination properties of Cu2+/Cu+ complexes with sulfur-pendant polyazamacrocycles for radiopharmaceutical applications
Marianna Tosato,Matteo Pelosato,Sara Franchi,Abdirisak Ahmed Isse,Nóra Veronica May,Giordano Zanoni,Fabrizio Mancin,Paolo Pastore,Denis Badocco,Mattia Asti,Valerio Di Marco New J. Chem. 2022 46 10012

1,4,7,10-四氮环十四烷(295-14-7) MSDS

基础信息

Section 1: Product Identification
   Chemical Name:       1,4,7,10-Tetraazacyclotridecane, min. 98%
   CAS Registry Number:       295-14-7
   Formula:       C9H22N4
   EINECS Number:       none
   Chemical Family:       organic amine
   Synonym:       none

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 295-14-7 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract
   Primary Routes of Exposure:       Inhalation, skin, eyes
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes irritation to the skin
   Inhalation:       Causes irritation to the nose, mucous membranes and respiratory tract
   Ingestion:       No information on the physiological effects of ingestion. May be harmful if swallowed.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract
   Chronic Health Affects:       No information available on long-term chronic effects
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       no data
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry chemical or foam
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, this material may emit irritating organic fumes
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Keep in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to yellow powder
   Molecular Weight:       186.30
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       not determined
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       oxidizing agents
   Decomposition Products:       carbon dioxide, carbon monoxide, nitrogen oxides and organic fumes

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files
   Carcinogenic Effects:       No data
   Mutagenic Effects:       No data
   Tetratogenic Effects:       No data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A