3271-76-9 (还原绿3,Vat Green 3)

还原绿3;还原橄榄绿 B;C.I.还原绿3;还原橄榄绿2B;士林橄榄绿B;还原绿 3;还原橄榄绿B;

Vat Green 3;Vat Olive Green B;16H-Anthra[2,1,9-mna]naphth[2,3-h]acridin-5,10,15-trion;16H-anthra[2,1,9-mna]naphth[2,3-h]acridine-5,10,15-trione;Cibanone Olive 2B;Cibanone Olive 2BD;Cibanone Olive B;Cibanone Olive FB;Mayvat Olive Green B;Olive green B;Ponsol Green 2BL;Ponsol Green 2BLD;Tinon Olive B;Vat Dark Green Zh;Vat Green-3;AhcovatOlive Green BL;Ahcovat Olive Green BL-F;Ahcovat Olive Green BLD;AhcovatPrinting Olive Green BL;Amanthrene Olive Green B;Amanthrene Supra Olive GreenB;Arlanthrene Olive Green B;Atic Vat Olive Green B;Belanthrene Olive GreenB;Benzadone Olive Green B;C.I. 69500;C.I. 70311;C.I. Vat Green 3;CalcoloidOlive Green BD;Calcoloid Olive Green BDC;Calcoloid Olive Green BDL;CalcoloidOlive Green BN;Calcoloid Olive Green BNC;Caledon Olive Green B;CaledonPrinting Olive Green B;Carbanthrene Olive Green B;Fenanthren Olive Green B;Helanthrene Olive Green B;Indanthren Olive Green B;Indanthrene Olive Green B;Indanthrene Olive Green BA;Mikethrene Olive Green B;Nihonthrene Olive Green B;Nihonthrene Olive Green B Disperse Powder;NovaticOlive Green B;Nyanthrene Olive Green B;Ostanthren Olive Green B;PalanthreneOlive Green B;Pernithrene Olive Green B;Romantrene Olive Green FB;Sandothrene Olive N 2B;Solanthrene Dark Green F-J;Solanthrene Dark Green J;Tinon Olive BM;Tyrian Olive GreenI-B;Anthra[2,1,9-mna]naphth[2,3-h]acridine-5,10,15(16H)-trione;CibanoneOlive 2BD;Vat Green 3;Caledon Printing Olive Green B;BRN 0060973;Tyrian Olive Green I-B;Zelen kypova 3;NS00020638;Calcoloid Olive Green BD;Ahcoval Printing Olive Green BL;EINECS 221-897-7;Anthra(2,1,9-mna)naphth(2,3-h)acridine-5,10,15(16H)-trione;3271-76-9;Zelen olivova ostanthrenova B;SCHEMBL458628;Calcoloid Olive Green BN;Belanthrene Olive Green B;27-hydroxy-16-azaoctacyclo[18.10.2.02,15.05,14.07,12.017,31.021,26.028,32]dotriaconta-1,3,5(14),7,9,11,15,17(31),18,20(32),21,23,25,27,29-pentadecaene-6,13-dione;Zelen olivova ostanthrenova B [Czech];Ahcoval Olive Green BL-F;Zelen kypova 3 [Czech];DTXSID3062944;Ahcoval Olive Green BL;0-21-00-00571 (Beilstein Handbook Reference);Palanthrene Olive Green B;Romanthrene Olive Green FB;Amanthrene Supra Olive Green B;Ahcoval Olive Green BLD;

JERMRPUPFAXARG-UHFFFAOYSA-N

1S/C31H15NO3/c33-29-19-6-2-1-5-15(19)16-13-14-24-26-17(9-11-22(29)25(16)26)18-10-12-23-27(28(18)32-24)31(35)21-8-4-3-7-20(21)30(23)34/h1-14,33H

OC1=C2C=CC=CC2=C2C=CC3C4C(=CC=C1C=42)C1C=CC2C(C4C=CC=CC=4C(C=2C=1N=3)=O)=O

221-897-7

2933990090

主要用于棉织物的染色和印花,也可用于维/棉混纺织物的染色

以苯绕蒽酮和 1-氨基蒽醌为原料,首先将苯绕蒽酮溴化,然后与 1-氨基蒽醌缩合,碱熔、闭环得产物。经过滤、中和、洗涤、干燥、粉碎得成品。。在反应锅中加入 300-400L 水、50kg 盐酸 (30%)、90kg 苯绕蒽酮、2kg 氯苯、35kg 溴,升温至 70-75℃,保温 1.5h,然后缓慢加入 10%次氯酸钠溶液 (折 100% 130kg),约 1.5-2h 加完,继续搅拌 1h。达反应终点后,加入重亚硫酸钠溶液,分解未反应溴。冷却,过滤,水洗至中性,干燥,得约 118kg 溴代苯绕蒽酮。在缩合锅中加入 232.5kg 溴代苯绕蒽酮、160kg 1-氨基蒽醌、50kg 碳酸钠、4.5kg 氧化铜,混合 1h 后,缓慢升温至 200℃,保温 2h,达终点时冷却、粉碎得亚胺混合物。在碱熔锅中加入 1000kg 丁醇、200kg 氢氧化钾,升温至 100-120℃,使全部溶解后,再降温至 90℃,加入 240kg 亚胺混合物,再升温至 110℃反应 6h。然后用水蒸气蒸出丁醇,过滤,洗涤,经研磨、干燥得成品。