3378-82-3 (1-溴-2-萘醛,1-Bromo-2-naphthaldehyde)

CAS号:
3378-82-3
中文名称:
1-溴-2-萘醛
英文名称:
1-Bromo-2-naphthaldehyde
安全信息:
分子式:
C11H7BrO
分子量:
235.076682329178

1-溴-2-萘醛(3378-82-3)名称与标识符

名称

中文别名:
1-溴-2-萘甲醛;1-Bromo-2-naphthaldehyde 1-溴-2-萘甲醛;1-溴-2-萘醛;
英文别名:
2-Naphthalenecarboxaldehyde,1-bromo-;1-Bromo-2-naphthaldehyde;1-bromo-2-Naphthalenecarboxaldehyde;1-bromonaphthalene-2-carbaldehyde;DTXSID60187442;AM9906;AS-18640;1-bromo-2-naphtaldehyde;CYGUXEZVBLMVRV-UHFFFAOYSA-N;MFCD00046368;AC-27834;Z1269163342;NS00029546;1-bromo-naphthalene-2-carbaldehyde;1-Bromo-2-naphthaldehyde, >=96.0% (HPLC);2-Naphthalenecarboxaldehyde, 1-bromo-;F10408;EINECS 222-180-1;B1647;EN300-266648;FT-0634812;AE-641/03232057;CS-W004895;3378-82-3;SB66995;SY052201;A854502;AKOS015898956;SCHEMBL950436;DB-048494;

标识符

MDL:
MFCD00046368
InChIKey:
CYGUXEZVBLMVRV-UHFFFAOYSA-N
Inchi:
1S/C11H7BrO/c12-11-9(7-13)6-5-8-3-1-2-4-10(8)11/h1-7H
SMILES:
BrC1C(C=O)=CC=C2C=CC=CC2=1

1-溴-2-萘醛(3378-82-3)物化性质

实验特性

  • LogP : 3.41480
  • PSA : 17.07000
  • 折射率 : 1.7
  • 沸点 : 347 ºC
  • 熔点 : 115.0 to 120.0 deg-C
  • 闪点 : 120 ºC
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定
  • 敏感性 : 对空气敏感
  • 密度 : 1.552

计算特性

  • 精确分子量 : 233.96800
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 1
  • 同位素质量 : 233.968
  • 重原子数量 : 13
  • 复杂度 : 193
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 3.3
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 17.1A^2

1-溴-2-萘醛(3378-82-3)国际标准相关数据

EINECS:
222-180-1

1-溴-2-萘醛(3378-82-3)海关数据

海关编码:
2913000090
海关数据:

中国海关编码:

2913000090

概述:

2913000090 品目2912所列产品的其他衍生物〔指卤化,磺化,硝化或亚硝化的衍生物〕. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

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1-溴-2-萘醛(3378-82-3)相关文献

1-溴-2-萘醛(3378-82-3)参考资料

Reaxys RN:
2613639
Beilstein:
2613639
PubChem CID:

1-溴-2-萘醛(3378-82-3) MSDS

基础信息

  1-Bromo-2-naphthaldehyde      Revision number: 1    
  SAFETY DATA SHEET

Section 1. BASE INFORMATION
  Product name:        1-Bromo-2-naphthaldehyde    

  Revision number:        1    

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A    
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Warning    
  Hazard statement        Causes skin irritation    
    Causes serious eye irritation
  Precautionary statements
  [Prevention]        Wash hands thoroughly after handling.    
    Wear protective gloves/eye protection/face protection.
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,    
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Component(s):        1-Bromo-2-naphthaldehyde    
  Percent:        >96.0%(GC)    
  CAS Number:        3378-82-3    
  Chemical Formula:        C11H7BrO    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of    
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  1-Bromo-2-naphthaldehyde

Section 4. FIRST AID MEASURES
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to    
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing    
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.    
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.    
  Storage
    Keep container tightly closed. Store in a cool and dark place.
  Storage conditions:
    Store under inert gas.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be    
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
    Solid
  Physical state (20°C):
  Form:        crystal - powder    
  Color:        Very pale yellow - Pale yellow    
  Odor:        No data available    
  pH: No data available
  Melting point/freezing point:118 °C
  1-Bromo-2-naphthaldehyde

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Boiling Point/Range:        No data available    
  Flash Point:        No data available    
  Explosive limits
    No data available
  Lower:
  Upper:        No data available    
    No data available
  Density:
  Solubility:        Soluble in : Methanol    

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.    
  Reactivity:        No special reactivity has been reported.    
  Conditions to avoid:        Air-sensitive    
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available    
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not Listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.
  1-Bromo-2-naphthaldehyde


SECTION 16 - ADDITIONAL INFORMATION
N/A