34171-69-2 (三氰基甲烷化钾,Potassium tricyanomethanide)

CAS号:
34171-69-2
中文名称:
三氰基甲烷化钾
英文名称:
Potassium tricyanomethanide
安全信息:
分子式:
C4KN3
分子量:
129.161200523376

三氰基甲烷化钾(34171-69-2)名称与标识符

名称

中文别名:
三氰基甲烷化钾;三氰基甲基钾;
英文别名:
Potassium tricyanomethanide;potassium,methanetricarbonitrile;Kalium-tricyanmethan;methanetricarbonitrile potassium salt;Potassium cyanoform;potassium ion tricyanomethanide;potassium tricyanmethanide;potassium tricyanomethanate;potassium tricyanomethylide;Tricyanomethanate potassium salt;Tricyanomethanide Potassium Salt;Potassium Methanetricarbonitrile;(tricyanomethyl)potassium;ZKJPYQKGNUBNOA-UHFFFAOYSA-N;P2538;AM20090522;A822111;FT-0693862;T72330;potassium;methanetricarbonitrile;J-019479;34171-69-2;MFCD00058850;DTXSID90449949;AKOS040767604;SCHEMBL2399805;Potassium Tricyanomethanide, >/=98%;tricyanomethylpotassium;

标识符

MDL:
MFCD00058850
InChIKey:
ZKJPYQKGNUBNOA-UHFFFAOYSA-N
Inchi:
1S/C4N3.K/c5-1-4(2-6)3-7;/q-1;+1
SMILES:
[K+].N#C[C-](C#N)C#N

三氰基甲烷化钾(34171-69-2)物化性质

实验特性

  • LogP : 0.26514
  • PSA : 71.37000
  • 水溶性 : Soluble in water.
  • 沸点 : 178.9℃ at 760mmHg
  • 熔点 : 298°C(lit.)
  • 闪点 : No data available
  • 颜色与性状 : 白色晶体
  • 溶解性 : 可溶于水
  • 密度 : No data available

计算特性

  • 精确分子量 : 128.97300
  • 氢键供体数量 : 0
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 0
  • 同位素质量 : 128.973
  • 重原子数量 : 8
  • 复杂度 : 155
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 71.4

三氰基甲烷化钾(34171-69-2)海关数据

海关编码:
2926909090
海关数据:

中国海关编码:

2926909090

概述:

2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

三氰基甲烷化钾(34171-69-2)生产方法和用途

用途:
本品用于有机合成。

三氰基甲烷化钾(34171-69-2)上下游

三氰基甲烷化钾(34171-69-2)相关文献

三氰基甲烷化钾(34171-69-2)参考资料

Reaxys RN:
3699935
PubChem CID:

三氰基甲烷化钾(34171-69-2) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Potassium tricyanomethanide, min. 98%    
   CAS Registry Number:       34171-69-2    
   Formula:       KC(CN)3    
   EINECS Number:       none    
   Chemical Family:       metal cyano complex    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       34171-69-2       100%       no data       5mg/m3 (as CN - skin)    

Section 3: Hazards Identification
   Emergency Overview:       Toxic material by ingestion, inhalation and skin absorption.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       May cause moderate to severe irritation of the eyes    
   Skin Contact:       May cause slight to mild irritation of the skin, Skin adsorption may result in toxic effects.    
   May be irritating to the nose, mucous membranes and respiratory tract. Decomposition products may include
   Inhalation:
   toxic hydrogen cyanide gas.
   Toxic if swallowed. High doses may cause vomiting, bloody diarrhea, twitching of facial muscles, convulsions,
   Ingestion:
   cyanosis, coma and death.
   Toxic by inhalation, in contact with skin and if swallowed. Cyanides may cause headache, dizziness, vomiting,
   Acute Health Affects:
   weak and irregular heart beat, unconsciousness, convulsions, coma and death.
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Handle and store the material under a dry inert atmosphere of nitrogen or argon.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       off-white to beige powder    
   Molecular Weight:       129.16    
   Melting Point:       none    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, nitrogen oxide, cyanides and potassium salts.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Toxic solids, organic, N.O.S.    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 2811    
   Shipping Name (IATA):       Toxic solid, organic, N.O.S.    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 2811    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A