基本信息
CAS号:
34872-98-5
分子式:
C22H40MoO6
分子量:
496.489410400391
名称与标识
名称
中文别名:
双(2,2,6,6 - 四甲基-3,5 - 庚二酮)二氧化钼(VI);
英文别名:
Molybdenum,dioxobis(2,2,6,6-tetramethyl-3,5-heptanedionato-kO,kO')-, (OC-6-21)- (9CI);MOLYBDENUM (VI) DIOXIDE BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE);MOLYBDENUM(VI) OXIDE BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE);Molybdenum(Vi)OxideBis(2,2,6,6-Tetramethyl-3,5-Hepta;Bis-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-molybdenum dioxide;Molybdenum(VI)dioxidebis(2,2,6,6-tetramethyl-3,5-heptanedionate),min.[O2Mo(TMHD)2];Molybdenumdioxidebistetramethylheptanedionatem;Molybdenum(VI) dioxide bis(2,2,6,6-tetramethyl-3,5-heptanedionate);34872-98-5;dioxomolybdenum;(Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one;MFCD00269827;
标识符
MDL:
MFCD00269827
InChIKey:
FLPSXHSSVOJARZ-KKUWAICFSA-N
Inchi:
1S/2C11H20O2.Mo.2O/c2*1-10(2,3)8(12)7-9(13)11(4,5)6;;;/h2*7,12H,1-6H3;;;/b2*8-7-;;;
SMILES:
[Mo](=O)=O.O/C(=C\C(C(C)(C)C)=O)/C(C)(C)C.O/C(=C\C(C(C)(C)C)=O)/C(C)(C)C
物化性质
实验特性
- LogP : 5.78740
- PSA : 86.74000
- 熔点 : 129-131°C
- 颜色与性状 : 未确定
- 溶解性 : 未确定
- 敏感性 : moisture sensitive
计算特性
- 精确分子量 : 496.17200
- 氢键供体数量 : 2
- 氢键受体数量 : 6
- 可旋转化学键数量 : 6
- 同位素质量 : 498.187893g/mol
- 重原子数量 : 29
- 复杂度 : 581
- 同位素原子数量 : 0
- 确定原子立构中心数量 : 0
- 不确定原子立构中心数量 : 0
- 确定化学键立构中心数量 : 2
- 不确定化学键立构中心数量 : 0
- 共价键单元数量 : 3
- 拓扑分子极性表面积 : 109Ų
安全信息
国际标准相关数据
EINECS:
双(2,2,6,6 - 四甲基-3,5 - 庚二酮)二氧化钼(VI)(34872-98-5)推荐厂家 更多厂家(4)
| 公司名称 | 手机号/电话 | 联系人 | 微信 | 询单 | |
|---|---|---|---|---|---|
| 上海瀚思化工有限公司 | 18939883912 021-34536277 | 顾经理 | 3003949364 | ![]() ![]() | 询单 |
| 上海源叶生物科技有限公司 | 15026964105 15026964105 | 汤思磊 | 2881489226 | ![]() ![]() | 询单 |
| 上海阿拉丁生化科技股份有限公司 | 13167063860 13167063860 | 阿拉丁 | 3004013043 | ![]() ![]() | 询单 |
| 北京浩克科技有限公司 | 张经理 | 询单 |
参考资料
Reaxys RN:
PubChem CID:
双(2,2,6,6 - 四甲基-3,5 - 庚二酮)二氧化钼(VI)(34872-98-5) MSDS
基础信息
Section 1: Product Identification
Chemical Name: Molybdenum (VI) dioxide bis(2,2,6,6-tetramethyl-3,5-heptanedionate), min. 98% [O2Mo(TMHD)2]
CAS Registry Number: 34872-98-5
Formula: MoO2(C11H19O2)2
EINECS Number: none
Chemical Family: metal beta-diketonate complexes
Synonym: Molybdenum oxo TMHD
Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 34872-98-5 100% 10mg/m3 (as 15mg/m3 (as
Section 3: Hazards Identification
Emergency Overview: No particular hazard associated with this material.
Primary Routes of Exposure: Ingestion, Inhalation of dust.
Eye Contact: May cause slight to mild irritation of the eyes.
Skin Contact: May cause slight to mild irritation of the skin.
Inhalation: Dust may be irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No information on the physiological effects of ingestion.
Acute Health Affects: May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a sealed container. Keep away from heat and moisture.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: yellow xtl.
Molecular Weight: 494.48
Melting Point: 129-131°
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: none
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, soot, and metal oxides and carbonates.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
SECTION 16 - ADDITIONAL INFORMATION
N/A

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