41753-67-7 ((Silylium)

快速询单

结构式：

SilyliumMOL文件

CAS号：

41753-67-7

英文名称：

Silylium

分子式：

H₅Si

分子量：

33.1252009868622

Silylium(41753-67-7)名称与标识符

名称

英文别名：

SiH3+;Silylium ion;trihydridosilicon(1+);silylium;SiH3(+);CHEBI:30562;DTXSID301319144;Q27113871;41753-67-7;(SiH3)(+);silanylium;[SiH3](+);

标识符

InChIKey：

VDQVVCFZWSTBQL-UHFFFAOYSA-N

Inchi：

1S/H5Si/h1H5/q+1

SMILES：

[SiH5+]

Silylium(41753-67-7)物化性质

计算特性

精确分子量 : 31.000401630Da
氢键供体数量 : 0
氢键受体数量 : 0
可旋转化学键数量 : 0
同位素质量 : 31.000401630Da
重原子数量 : 1
复杂度 : 0
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
拓扑分子极性表面积 : 0Å²

Silylium(41753-67-7)相关文献

1. Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions
Antoine Barthélemy,Kim Glootz,Harald Scherer,Annaleah Hanske,Ingo Krossing Chem. Sci. 2022 13 439
2. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
Lukas Omann,Bimal Pudasaini,Elisabeth Irran,Hendrik F. T. Klare,Mu-Hyun Baik,Martin Oestreich Chem. Sci. 2018 9 5600
3. Investigations on non-classical silylium ions leading to a cyclobutenyl cation
Arthur Martens,Marvin Kreuzer,Alexander Ripp,Marius Schneider,Daniel Himmel,Harald Scherer,Ingo Krossing Chem. Sci. 2019 10 2821
4. Silylium ions in catalysis
Hendrik F. T. Klare,Martin Oestreich Dalton Trans. 2010 39 9176
5. Silaimidazolium and silaimidazolidinium ions
Annemarie Sch?fer,André Sch?fer,Thomas Müller Dalton Trans. 2010 39 9296
6. Imine-stabilized silylium ions: synthesis, structure and application in catalysis
Aymeric Dajnak,Limiao Shi,Gül Alt?nba? ?zp?nar,Romaric Lenk,Nathalie Saffon-Merceron,Antoine Baceiredo,Tsuyoshi Kato,Thomas Müller,Eddy Maerten Dalton Trans. 2023 52 3052
7. Atomistic insights into the hydrodefluorination of PFAS using silylium catalysts
Glen R. Jenness,Ashlyn M. Koval,Brian D. Etz,Manoj K. Shukla Environ. Sci.: Processes Impacts 2022 24 2085
8. Origin of the 29Si NMR chemical shift in R3Si–X and relationship to the formation of silylium (R3Si+) ions
Winn Huynh,Matthew P. Conley Dalton Trans. 2020 49 16453
9. Norbornene based-sulfide-stabilized silylium ions: synthesis, structure and application in catalysis
Aymeric Dajnak,Gül Alt?nba? ?zp?nar,Romaric Lenk,Nathalie Saffon-Merceron,Antoine Baceiredo,Tsuyoshi Kato,Thomas Müller,Eddy Maerten Dalton Trans. 2022 51 1407
10. Computed thermodynamic stabilities of silylium Lewis base adducts
Christina A. Roselli,Michel R. Gagné Org. Biomol. Chem. 2018 16 2318

41753-67-7 ((Silylium)

Silylium(41753-67-7)名称与标识符

名称

标识符

Silylium(41753-67-7)物化性质

计算特性

Silylium(41753-67-7)相关文献

目录