51114-94-4 (甲基硅醇钠盐,(2-Carboxyethyl)-triphenylphosphonium Bromide)

CAS号:
51114-94-4
中文名称:
甲基硅醇钠盐
英文名称:
(2-Carboxyethyl)-triphenylphosphonium Bromide
安全信息:
分子式:
C21H20BrO2P
分子量:
415.26006603241
相关分类:

甲基硅醇钠盐(51114-94-4)名称与标识符

名称

中文别名:
(2-羧乙基)三苯基溴化磷;2-羧乙基三苯基溴化磷;2-(羧乙基)三苯基溴化膦;(2-羧基乙基)三苯基鏻溴化物;(2-羧基乙基)三苯基溴化膦;(2-羧乙基)三苯基溴化鏻;2-羧乙基三苯基溴化鏻;甲基硅醇钠盐;(2-羧基乙基)三苯基溴化鏻;
英文别名:
(2-Carboxyethyl)triphenylphosphonium bromide;NSC 84145;2-Carboxyethyl triphenylphosponium bromide;NSC84145;Phosphonium, (2-carboxyethyl)triphenyl-, bromide;C21H20O2P.Br;BVKRDNIULHRLCO-UHFFFAOYSA-N;2854AH;OR18825;SY067471;2-carboxyethyl-triphenylphosphonium bromide;2-carboxyethyl tripheny;2-carboxyethyl triphenylphosphonium bromide;2-carboxyethyl(triphenyl)phosphanium;bromide;51114-94-4;EN300-211928;C3309;2-carboxyethyl(triphenyl)phosphonium bromide;(2-Carboxy-ethyl)-triphenyl-phosphonium bromide;AKOS017345147;(2-carboxyethyl)triphenylphosphonium bromide, 97 %;NSC-84145;SCHEMBL174432;(2-carboxyethyl)triphenylphosphanium bromide;(2-Carboxyethyl) triphenylphosphonium Bromide;A828444;BCA11494;CHEMBL1970728;MFCD00031698;CS-M0693;(2-CARBOXYETHYL)TRIPHENYLPHOSPHONIUMBROMIDE;F10039;AS-10181;

标识符

MDL:
MFCD00031698
InChIKey:
BVKRDNIULHRLCO-UHFFFAOYSA-N
Inchi:
1S/C21H19O2P.BrH/c22-21(23)16-17-24(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20;/h1-15H,16-17H2;1H
SMILES:
[Br-].[P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)CCC(=O)O

甲基硅醇钠盐(51114-94-4)物化性质

实验特性

  • LogP : 0.45920
  • PSA : 50.89000
  • 沸点 : °Cat760mmHg
  • 熔点 : 195.0 to 199.0 deg-C
  • 闪点 : °C
  • 颜色与性状 : 无可用
  • 溶解性 : 无可用
  • 密度 : 1.5±0.1 g/cm3

计算特性

  • 精确分子量 : 414.03800
  • 氢键供体数量 : 1
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 6
  • 同位素质量 : 414.038
  • 重原子数量 : 25
  • 复杂度 : 345
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 4.1
  • 表面电荷 : 1
  • 拓扑分子极性表面积 : 37.3

甲基硅醇钠盐(51114-94-4)推荐厂家 更多厂家(64)

甲基硅醇钠盐(51114-94-4)参考资料

Reaxys RN:
4072247
PubChem CID:

甲基硅醇钠盐(51114-94-4) MSDS

基础信息

Name:2-Carboxyethyl triphenylphosphonium bromide Material Safety Data Sheet
Synonym:
CAS:51114-94-4
Section 1 - Chemical Product ? MSDS Name:2-Carboxyethyl triphenylphosphonium bromide Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
51114-94-42-Carboxyethyl triphenylphosphonium brca100unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 51114-94-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C21H20BrO2P
Molecular Weight: 415.26

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not currently available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 51114-94-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Carboxyethyl triphenylphosphonium bromide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 51114-94-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 51114-94-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 51114-94-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A