537-00-8 (乙酸铈,Cerium triacetate)

乙酸铈(537-00-8)名称与标识符

名称

中文别名:
乙酸铈;醋酸铈;醋酸铈(III);醋酸铈(III)倍半水合物;醋酸铈水合物;水合乙酸鈰(III);乙酸铈水合物;乙酸铈倍半水合物;
英文别名:
CERIUM ACETATE;Cerium(III) acetate hydrate;Cerium(III) acetate;aceticacid,cerium(3+)salt;aceticacid,cerium(3++)salt;ceriumtriacetate;ceticacid,cerium(3+)salt;CeriumacetatehydrateREOwhitepowder;cerium(3+) acetate;Cerium(III) acetate sesquihydrate;cerium acetate hydrate;Aceticacid, cerium(3+) salt (8CI,9CI);Cerium acetate (6CI,7CI);Cerous acetate;Cerium triacetate;cerium(3+) triacetate;Acetic acid, cerium(3+) salt;Cerium (Iii) Acetate;YYB5291R2H;Acetic acid, cerium(3+)salt (3:1);Acetic acid, cerium(3+) salt (3:1);KSC598M3L;Acetic Acid Cerium(III) Salt;cerium(3+) tris(acetate ion);Jsp003669;Triacetic acid cerium(III) salt;VGBWDOLBWVJTRZ-UHFFFAOYSA-K;cerium(III)acetate;NS00093550;C2974;J55.407C;cerium(3+);triacetate;Q15730268;AKOS030228513;537-00-8;DTXSID2027179;Cerium (III) acetate sesquihydrate, 99.99%, trace metals grade;Cerium (III) acetate sesquihydrate, 99.9%, trace metals grade;CERIUM(III)ACETATESESQUIHYDRATE,99.9%(REO);DB-044325;

标识符

MDL:
MFCD00051060
InChIKey:
VGBWDOLBWVJTRZ-UHFFFAOYSA-K
Inchi:
1S/3C2H4O2.Ce/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
SMILES:
[Ce+3].[O-]C(C)=O.[O-]C(C)=O.[O-]C(C)=O

乙酸铈(537-00-8)物化性质

实验特性

  • LogP : -3.73140
  • PSA : 120.39000
  • 水溶性 : Soluble in water.
  • 沸点 : No data available
  • 熔点 : 308°C (dec.)
  • 蒸气压 : No data available
  • 闪点 : No data available
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定

计算特性

  • 精确分子量 : 316.94500
  • 氢键供体数量 : 0
  • 氢键受体数量 : 6
  • 可旋转化学键数量 : 0
  • 同位素质量 : 316.945
  • 重原子数量 : 13
  • 复杂度 : 25.5
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 4
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 120

乙酸铈(537-00-8)国际标准相关数据

EINECS:
208-654-0

乙酸铈(537-00-8)生产方法和用途

用途:
用于汽车尾气净化、催化剂等

乙酸铈(537-00-8) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Cerium (III) acetate, hydrate(99.9%-Ce) (REO)    
   CAS Registry Number:       537-00-8    
   Formula:       Ce(OOCCH3)3.XH2O    
   EINECS Number:       208-654-0    
   Chemical Family:       metal acetate salt    
   Synonym:       Acetic acid, cerium(3+) salt, cerium triacetate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       537-00-8       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide or dry powder    
   If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       317.26    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, cerium oxide and organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       Intravenous (human); TDLo: 2mg/kg    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A