54109-16-9 (2-溴-2'-(三氟甲基)乙酰苯,2-(Trifluoromethyl)phenacyl bromide)

CAS号:
54109-16-9
中文名称:
2-溴-2'-(三氟甲基)乙酰苯
英文名称:
2-(Trifluoromethyl)phenacyl bromide
安全信息:
分子式:
C9H6BrF3O
分子量:
267.042552471161

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)名称与标识符

名称

中文别名:
2-溴-2'-(三氟甲基)苯乙酮;α-溴代-2-三氟甲基苯乙酮;2-(三氟甲基)溴苯乙酮;2-Bromo-2'-(trifluoromethyl)acetophenone 2-溴-2'-(三氟甲基)苯乙酮;2-溴-1-(三氟甲基)苯基-1-乙酮;2-溴-2 -(三氟甲基)苯乙酮;2-溴-2'-三氟甲基苯乙酮;2-(三氟甲基)苯甲酰甲基溴;2-(三氟甲基)溴代甲基苯甲酰;2-三氟甲基溴代苯乙酮;2-溴-2'-(三氟甲基)乙酰苯;
英文别名:
2-Bromo-1-[2-(trifluoromethyl)phenyl]-1-ethanone;2'-(TRIFLUOROMETHYL)PHENACYL BROMIDE;2-(TRIFLUOROMETHYL)PHENACYL BROMIDE;2-Bromo-2'-(trifluoromethyl)acetophenone;2-(trifluoromethtl)phenacyl bromide;2-Bromo-1-(2-trifluoromethyl-phenyl)-ethanone;2-bromo-1-[2-(trifluoromethyl)phenyl]ethanone;2-Bromo-1-(2-trifluoromethylphenyl)ethanone;2-bromo-1-[2-(trifluoromethyl)phenyl]ethan-1-one;2-BROMO-1-(2-(TRIFLUOROMETHYL)PHENYL)ETHANONE;Ethanone, 2-bromo-1-[2-(trifluoromethyl)phenyl]-;2-trifluoromethyphenacyl bromide;2-trifluoromethylphenacyl bromide;2-trifluoromethyl phenac;

标识符

MDL:
MFCD03094304
InChIKey:
KWZCBMKXNYOQAK-UHFFFAOYSA-N
Inchi:
1S/C9H6BrF3O/c10-5-8(14)6-3-1-2-4-7(6)9(11,12)13/h1-4H,5H2
SMILES:
BrCC(C1C=CC=CC=1C(F)(F)F)=O

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)物化性质

实验特性

  • LogP : 3.28300
  • PSA : 17.07000
  • 水溶性 : Slightly soluble in water.
  • 沸点 : 257.8±40.0 ºC (760 Torr),
  • 熔点 : 28.0 to 32.0 deg-C
  • 闪点 : 109.7±27.3 ºC,
  • 溶解度 : Very 微溶 (0.21 g/L) (25 ºC),
  • 密度 : 1.592±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

  • 精确分子量 : 265.95500
  • 氢键供体数量 : 0
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 2
  • 重原子数量 : 14
  • 复杂度 : 215
  • 拓扑分子极性表面积 : 17.1

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)海关数据

海关编码:
2914700090
海关数据:

中国海关编码:

2914700090

概述:

2914700090 其他酮及醌的卤化、磺化衍生物(包括硝化和亚硝化衍生物). 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途, 丙酮报明包装

Summary:

HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)推荐厂家 更多厂家(30)

公司名称手机号/电话联系人QQ微信询单
上海源叶生物科技有限公司 15026964105
15026964105
汤思磊 2881489226
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湖北省荆祥科技有限公司 13357813287
025-57670629
杨经理 1938049192
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湖北诺纳科技有限公司 18995657604
027-59209883
吴经理 2933307129
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上海瀚思化工有限公司 18939883912
021-34536277
顾经理 3003949364
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上海绩祥生物科技有限公司 13093077543陆经理 3985448220
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铼博(上海)生化科技有限公司 13311756052
021-60536361 13311756052 13311756131
张经理 2851717387
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上海一基实业有限公司 13311756131
021-60548336 QQ:2355265332 QQ:2851717387
胡经理 2355265332
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上海一基实业有限公司 13311756052
021-60526763 13311756052 13311756131
胡经理 2355265332
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赫澎(上海)生物科技有限公司 13122891558
186-16545970
张硕 3418426269
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赫澎(上海)生物科技有限公司 13122891558
186-16545970
张硕 3418426269
询单

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)上下游

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9)参考资料

Reaxys RN:
4183222
PubChem CID:

2-溴-2'-(三氟甲基)乙酰苯(54109-16-9) MSDS

基础信息

Name:2-Bromo-1-[2-(trifluoromethyl)phenyl]-1-ethanone 95+% Material Safety Data Sheet
Synonym:
CAS:54109-16-9
Section 1 - Chemical Product ? MSDS Name:2-Bromo-1-[2-(trifluoromethyl)phenyl]-1-ethanone 95+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
54109-16-92-Bromo-1-[2-(trifluoromethyl)phenyl]-95+%unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
? Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 54109-16-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 52 deg C @0.03mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H6BrF3O
Molecular Weight: 267.04

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromine, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 54109-16-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromo-1-[2-(trifluoromethyl)phenyl]-1-ethanone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 54109-16-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 54109-16-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 54109-16-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A