5780-36-9 (2-(甲硫基)噻吩,2-(Methylthio)thiophene)

CAS号:
5780-36-9
中文名称:
2-(甲硫基)噻吩
英文名称:
2-(Methylthio)thiophene
安全信息:
分子式:
C5H6S2
分子量:
130.231138706207

2-(甲硫基)噻吩(5780-36-9)名称与标识符

名称

中文别名:
2-(甲硫基)噻吩;2-(甲基硫代)噻吩;2-甲硫基噻吩;
英文别名:
2-(Methylthio)thiophene;2-(Methylmercapto)thiophene~Methyl 2-thienyl sulphide;2-methylsulfanylthiophene;FT-0608840;2-(Methylsulfanyl)thiophene;PS-5054;AKOS005258191;2-(Mehtylthio)thiophene;DTXSID30206497;J-506504;2-(Methylsulfanyl)thiophene #;MFCD00052382;SCHEMBL438913;5780-36-9;ZLSMPEVZXWDWEK-UHFFFAOYSA-N;Thiophene, 2-(methylthio)-;2-methylmercaptothiophene;STL557971;BBL104157;DB-025716;

标识符

MDL:
MFCD00052382
InChIKey:
ZLSMPEVZXWDWEK-UHFFFAOYSA-N
Inchi:
1S/C5H6S2/c1-6-5-3-2-4-7-5/h2-4H,1H3
SMILES:
S1C=CC=C1SC
BRN:
106272

2-(甲硫基)噻吩(5780-36-9)物化性质

实验特性

  • LogP : 2.47000
  • PSA : 53.54000
  • 折射率 : 1.5960
  • 沸点 : 100 °C
  • 闪点 : 82-84°C/15mm
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定
  • 密度 : 1.18

计算特性

  • 精确分子量 : 129.99100
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 1
  • 同位素质量 : 129.991
  • 重原子数量 : 7
  • 复杂度 : 54
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 2.4
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 53.5A^2

2-(甲硫基)噻吩(5780-36-9)安全信息

2-(甲硫基)噻吩(5780-36-9)国际标准相关数据

EINECS:
MFCD00052382

2-(甲硫基)噻吩(5780-36-9)海关数据

海关编码:
2934999090
海关数据:

中国海关编码:

2934999090

概述:

2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素:

品名, 成分含量, 用途

Summary:

2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-(甲硫基)噻吩(5780-36-9)生产方法和用途

方法:
HPLC

2-(甲硫基)噻吩(5780-36-9)推荐厂家 更多厂家(22)

2-(甲硫基)噻吩(5780-36-9)相关文献

2-(甲硫基)噻吩(5780-36-9)参考资料

Beilstein:
106272
PubChem CID:

2-(甲硫基)噻吩(5780-36-9) MSDS

基础信息

Name:2-(Methylthio)thiophene 97% Material Safety Data Sheet
Synonym:
CAS:5780-36-9
Section 1 - Chemical Product ? MSDS Name:2-(Methylthio)thiophene 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
5780-36-92-(Methylthio)thiophene97%unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5780-36-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Liquid
Color: yellow
Odor: stench - pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 82 - 84 deg C @15mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H6S2
Molecular Weight: 130

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 5780-36-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-(Methylthio)thiophene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: AVIATION REGULATED LIQUID, N.O.S.*
Hazard Class: 9
UN Number: 3334
Packing Group:
IMO
Shipping Name:
Hazard Class:
UN Number: 3334
Packing Group:
RID/ADR
Shipping Name:
Hazard Class:
UN Number: 3334
Packing group:

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5780-36-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5780-36-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5780-36-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A