614-31-3 (α-苄基苯基肼,1-Benzyl-1-phenylhydrazine)

快速询单

结构式：

α-苄基苯基肼MOL文件

CAS号：

614-31-3

中文名称：

α-苄基苯基肼

英文名称：

1-Benzyl-1-phenylhydrazine

安全信息：

分子式：

C₁₃H₁₄N₂

分子量：

198.263662815094

α-苄基苯基肼(614-31-3)名称与标识符

名称

中文别名：

1-苄基-1-苯基肼;1-Benzyl-1-phenylhydrazine 1-苄基-1-苯基肼;1-苄基-1-苯肼;Alpha-苄基苯基肼;α-苄基苯基肼;

英文别名：

Hydrazine,1-phenyl-1-(phenylmethyl)-;1-Benzyl-1-phenylhydrazine;1-Benzylphenylhydrazine;N-Benzyl-N-phenylhydrazine;NSC 7145;alpha-Benzylphenylhydrazine;1-Phenyl-1-(phenylmethyl)-hydrazine;Q9EG0RBA6B;Benzylphenylhydrazin;Enamine_004985;1-benzyl-1-phenyl-hydrazine;NSC7145;SQMOOVFBFVTTGF-UHFFFAOYSA-N;HMS1408C13;BBL034708;6703AE;STK500247;VZ21179;IDI1_007572;W-109575;EN300-03635;CS-0454206;SCHEMBL544819;UNII-Q9EG0RBA6B;AS-58798;EINECS 210-377-5;Hydrazine, 1-phenyl-1-(phenylmethyl)-;AKOS000264774;MFCD00059186;ALBB-006671;1-PHENYL-1-(PHENYLMETHYL)HYDRAZINE;F1905-7118;B1157;614-31-3;D88762;NS00034687;NSC-7145;DB-053884;.ALPHA.-BENZYLPHENYLHYDRAZINE;HYDRAZINE, 1-BENZYL-1-PHENYL-;DTXSID60210320;

标识符

MDL：

MFCD00059186

InChIKey：

SQMOOVFBFVTTGF-UHFFFAOYSA-N

Inchi：

1S/C13H14N2/c14-15(13-9-5-2-6-10-13)11-12-7-3-1-4-8-12/h1-10H,11,14H2

SMILES：

N(C1C=CC=CC=1)(CC1C=CC=CC=1)N

α-苄基苯基肼(614-31-3)物化性质

实验特性

LogP : 3.26720
PSA : 29.26000
折射率 : 1.6180-1.6210
沸点 : 218°C/38mmHg(lit.)
熔点 : 164-166 ºC
闪点 : 186 ºC
颜色与性状 : 不可用
溶解性 : 不可用
密度 : 1.130

计算特性

精确分子量 : 198.11600
氢键供体数量 : 1
氢键受体数量 : 2
可旋转化学键数量 : 3
同位素质量 : 198.115698455g/mol
重原子数量 : 15
复杂度 : 169
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.5
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 29.3

α-苄基苯基肼(614-31-3)安全信息

符号： GHS07
安全说明： S26-S36/37/39
风险术语： R20/21/22
危害声明：H315-H319
警示性声明：P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
提示语：警告
危险类别码： 20/21/22-36/37/38
HazardClass： IRRITANT

α-苄基苯基肼(614-31-3)国际标准相关数据

EINECS：

7145

α-苄基苯基肼(614-31-3)海关数据

海关编码：

2928000090

海关数据：

中国海关编码：

2928000090

概述：

2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

申报要素：

品名, 成分含量, 用途

Summary：

2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

α-苄基苯基肼(614-31-3)推荐厂家更多厂家(13)

公司名称	手机号/电话	联系人	QQ	询单
上海创赛科技有限公司	15021221957 021-59553580	凌度	2852351983	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
JACS-郑州杰克斯化工产品有限公司	15981966935 0371-86259281	杰克斯JACS	893596907	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
上海麦克林生化科技股份有限公司	15221275939 021-50706066	沈经理	269348414	询单
天成化工（江苏）有限公司	15251950002 0512-83500002	陈小姐		询单
梯希爱（上海）化成工业发展有限公司	13061970904	张泽原	862682778	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单

α-苄基苯基肼(614-31-3)参考资料

Reaxys RN：

513980

Beilstein：

B152453

PubChem CID：

87564097

α-苄基苯基肼(614-31-3) MSDS

基础信息

1-Benzyl-1-phenylhydrazine Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: 1-Benzyl-1-phenylhydrazine

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statement        Causes skin irritation
    Causes serious eye irritation
  Precautionary statements
  [Prevention]        Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Component(s):        1-Benzyl-1-phenylhydrazine
  Percent:        >98.0%(T)
  CAS Number:        614-31-3
  Chemical Formula:        C13H14N2

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  1-Benzyl-1-phenylhydrazine

Section 4. FIRST AID MEASURES
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapor or mist. Wash hands and face thoroughly after handling.
    Use a ventilation, local exhaust if vapor or aerosol will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
    Liquid
  Physical state (20°C):
  Form:        clear
  Color:        Pale yellow - Reddish yellow
  Odor:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  1-Benzyl-1-phenylhydrazine

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Boiling Point/Range:        218 °C/5.1kPa
  Flash Point:        No data available
  Explosive limits
    No data available
  Lower:
  Upper:        No data available
    1.10
  Density:
  Solubility:        No data available

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
  Reactivity:        No special reactivity has been reported.
  Conditions to avoid:        Light-sensitive
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local
regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not Listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.
  1-Benzyl-1-phenylhydrazine

SECTION 16 - ADDITIONAL INFORMATION
N/A