635-84-7 (2'-氯代联苯乙酮,1-{1,1'-biphenyl-4-yl}-2-chloroethan-1-one)

快速询单

结构式：

2'-氯代联苯乙酮MOL文件

CAS号：

635-84-7

中文名称：

2'-氯代联苯乙酮

英文名称：

1-{1,1'-biphenyl-4-yl}-2-chloroethan-1-one

安全信息：

分子式：

C₁₄H₁₁ClO

分子量：

230.689543008804

2'-氯代联苯乙酮(635-84-7)名称与标识符

名称

中文别名：

2'-氯代联苯乙酮;2-氯-4'-苯基苯乙酮;2-氯-4''-苯基苯乙酮;2-Chloro-4'-phenylacetophenone 2-氯-4'-苯基苯乙酮;2鈥氯代联苯乙酮;2-氯-4 -苯基苯乙酮;2''-氯代联苯乙酮;2-氯代联苯乙酮;2’-氯代联苯乙酮;4-氯代联苯乙酮;4-苯基苯甲酰甲基氯;

英文别名：

4-Phenylphenacyl chloride;2-Chloro-4'-phenylacetophenone;1-(1,1'-Biphenyl-4-yl)-2-chloroethanone;2-chloro-1-(4-phenylphenyl)ethanone;4-Chloroacetylbiphenyl;p-Phenylphenacyl chloride;1-([1,1'-biphenyl]-4-yl)-2-chloroethanone;1-(biphenyl-4-yl)-2-chloroethanone;Ethanone, 1-[1,1'-biphenyl]-4-yl-2-chloro-;IQEIGQFNDLINOT-UHFFFAOYSA-N;Ethanone, 1-(1,1'-biphenyl)-4-yl-2-chloro-;1-([1,1-Biphenyl]-4-yl)-2-chloroethanone;1-([1,1'-biphenyl]-4-yl)-2-chloroethan-1-one;NSC41668;p-Chloroacety;1-{1,1'-biphenyl-4-yl}-2-chloroethan-1-one;

标识符

MDL：

MFCD00058937

InChIKey：

IQEIGQFNDLINOT-UHFFFAOYSA-N

Inchi：

1S/C14H11ClO/c15-10-14(16)13-8-6-12(7-9-13)11-4-2-1-3-5-11/h1-9H,10H2

SMILES：

ClCC(C1C=CC(=CC=1)C1C=CC=CC=1)=O

2'-氯代联苯乙酮(635-84-7)物化性质

实验特性

LogP : 3.77510
PSA : 17.07000
熔点 : 126.0 to 131.0 deg-C
颜色与性状 : 类似氨气味的黄色液体。
溶解性 : 极易溶于水。
密度 : 1.1670

计算特性

精确分子量 : 230.05000
氢键供体数量 : 0
氢键受体数量 : 1
可旋转化学键数量 : 3
重原子数量 : 16
复杂度 : 225
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 4.4
互变异构体数量 : 2
表面电荷 : 0
拓扑分子极性表面积 : 17.1

2'-氯代联苯乙酮(635-84-7)安全信息

符号： GHS07
安全说明： S26; S36/37/39
风险术语： R36/37/38
危害声明：H315-H319
警示性声明：P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
提示语：警告
危险类别码： R36/37/38：对眼睛、呼吸道和皮肤有刺激作用。

2'-氯代联苯乙酮(635-84-7)国际标准相关数据

EINECS：

41668

2'-氯代联苯乙酮(635-84-7)海关数据

海关编码：

2914700090

海关数据：

中国海关编码：

2914700090

概述：

2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 丙酮报明包装

Summary：

HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2'-氯代联苯乙酮(635-84-7)推荐厂家更多厂家(24)

公司名称	手机号/电话	联系人	QQ	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单
湖北云镁科技有限公司	18327059871 027-59206672	方经理	235010015	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
上海创赛科技有限公司	15021221957 021-59553580	凌度	2852351983	询单
赫澎（上海）生物科技有限公司	13122891558 186-16545970	张硕	3418426269	询单
铼博（上海）生化科技有限公司	13311756052 021-60536361 13311756052 13311756131	张经理	2851717387	询单
上海一基实业有限公司	13311756131 021-60548336 QQ：2355265332 QQ:2851717387	胡经理	2355265332	询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单

2'-氯代联苯乙酮(635-84-7)相关文献

1. 95. Evidence for the homolytic bond fission of “positive halogen” compounds
Alan Robertson,William A. Waters J. Chem. Soc. 1947 492
2. 693. The synthesis of acetylenes and allenes from enol phosphates
J. Cymerman Craig,M. Moyle J. Chem. Soc. 1963 3712
3. A novel coupling reaction of α-halo ketones promoted by SmI3/CuI
Yongjun Liu,Hengmin Zhao,Guang Tian,Feng Du,Yan Qi,Yonghong Wen RSC Adv. 2016 6 26317
4. Photochemical reactions of halogenated aromatic 1,3-diketones in solution studied by steady state, one- and two-color laser flash photolyses
Minoru Yamaji,Yurie Suwa,Rieko Shimokawa,Cecilia Paris,Miguel ángel Miranda Photochem. Photobiol. Sci. 2015 14 1673

2'-氯代联苯乙酮(635-84-7)参考资料

Reaxys RN：

1241565

PubChem CID：

87565412

2'-氯代联苯乙酮(635-84-7) MSDS

基础信息

2-Chloro-4'-phenylacetophenone Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: 2-Chloro-4'-phenylacetophenone

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statement        Causes skin irritation
    Causes serious eye irritation
  Precautionary statements
  [Prevention]        Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Component(s):        2-Chloro-4'-phenylacetophenone
  Percent:        >99.0%(T)
  CAS Number:        635-84-7
  Synonyms:        4-Chloroacetylbiphenyl , 4-Phenylphenacyl Chloride
  Chemical Formula:        C14H11ClO

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  2-Chloro-4'-phenylacetophenone

Section 4. FIRST AID MEASURES
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.
  Storage
    Keep container tightly closed. Store in a cool and dark place.
  Storage conditions:
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        crystal - powder
  Color:        White - Slightly pale yellow
  Odor:        No data available
  pH: No data available
  2-Chloro-4'-phenylacetophenone

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Melting point/freezing point:126 °C
  Boiling Point/Range:        No data available
  Flash Point:        No data available
  Explosive limits
  Lower:        No data available
    No data available
  Upper:
  Density:        No data available
    No data available
  Solubility:

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
  Reactivity:        No special reactivity has been reported.
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not Listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.
  2-Chloro-4'-phenylacetophenone

SECTION 16 - ADDITIONAL INFORMATION
N/A