65181-78-4 (N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺,N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine)

快速询单

结构式：

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺MOL文件

CAS号：

65181-78-4

中文名称：

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺

英文名称：

N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine

安全信息：

分子式：

C₃₈H₃₂N₂

分子量：

516.6741

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)名称与标识符

名称

中文别名：

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺;N,N'-二苯基-N,N'-二(间甲苯基)联苯胺;N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺;N,N'-二苯基-N,N'-二(间甲苯基)联苯胺(以升华法纯化);N,N -二苯基-N,N -二(间甲基苯基)联苯胺, 升华级;N,N\'-二苯基-N,N\'-二(3-甲基苯基)-1,1\'-联苯-4,4\'-二胺;N,N’-二苯基-N,N’-(3-甲基苯基)-1,1’-联苯-4,4’-二胺;N,N’-二苯基-N,N’-二(3-甲基苯基)-1,1’-联苯-4,4’-二胺;N,N’-双(3-甲基苯基)-N,N’-二苯基联苯胺;N,N′-二苯基-N,N′-(3-甲基苯基)-1,1′-联苯-4,4′-二胺;N,N′-二苯基-N,N′-(3-甲基苯基)-1,1′-联苯-4,4′-二胺（TPD）;N,N'-Diphenyl-N,N'-di(m-tolyl)benzidine N,N'-二苯基-N,N'-二(间甲苯基)联苯胺;N,N'-Diphenyl-N,N'-di(m-tolyl)benzidine (purified by sublimation) N,N'-二苯基-N,N'-二(间甲苯基)联苯胺(以升华法纯化);N,N''-二苯基-N,N''-(3-甲基苯基)-1,1''-联苯-4,4''-二胺;N,N-二苯基-N,N-(3-甲基苯基)-1,1-联苯-4,4-二胺;N,N''-二苯基-N,N''-二(3-甲基苯基)-1,1''-联苯-4,4''-二胺;N,N''-二苯基-N,N''-二(间甲基苯基)联苯胺, 升华级;N,N'-二苯基-N,N'-二(间甲基苯基)联苯胺, 升华级;二苯苯啶;"N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺 ";4,4'-双[N-苯基-N-(间甲苯基)氨基]联苯;N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺(TPD);N,N-二苯基-N,N-二(3-甲基苯基)-1,1-联苯-4,4-二胺;n,n'-双(3-甲苯基)-n,n'-二苯基联苯胺;N,N'-双(3-甲基苯基)-N,N'-二苯基-[1,1'-联苯]-4,4'-二胺;N,N'-双(3-甲基苯基)-N,N'-二苯基-1,1'-联苯-4,4'-二胺;N,N'-双(3-甲基苯基)-N,N'-二苯联苯胺;N,N'-双(3-甲基苯基)-N,N'-二苯基联苯胺 (升华提纯);4,4'-双[N-苯基-N-(m-甲苯基)氨基]联苯 (升华提纯);

英文别名：

N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine;N,N-Bis(3-methylphenyl)-N,N-diphenylbenzidine;N,N-Diphenyl-N,N-di(m-tolyl)benzidine;N,N-Dipehnyl-N,N-di(m-Tolyl)benzidine;N,N'-Diphenyl-N,N'-di(m-tolyl)benzidine;N,N'-Diphenyl-N,N'-di(m-tolyl)benzidine (purified by sublimation);N,N'-Diphenyl-N,N'-di(3-methylphenyl)benzidine;TPD;"N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine ";N,N'-Bis(3-methylphenyl)-N,N'-diphenylbenzidine (purified by sublimation);TPD (purified by sublimation);N,N'-Bis(3-methylphenyl)-N,N'-diphenylbenzidine;n4,n4'-diphenyl-n4,n4'-di-m-tolyl-[1,1'-biphenyl]-4,4'-diamine;N,N'-bis(3-methylphenyl)-N,N'-diphenyl-benzidine;OGGKVJMNFFSDEV-UHFFFAOYSA-N;[1,1'-Biphenyl]-4,4'-diamine, N,N'-bis(3-methylphenyl)-N,N'-diphenyl-;(1,1'-Biphenyl)-4,4'-diamine, N,N'-bis(3-methylphenyl)-N,N'-diphenyl-;3-methyl-N-[4-[4-[N-(m-tolyl)anilino]phenyl]phenyl]-N-phenyl-;

标识符

MDL：

MFCD00144965

InChIKey：

OGGKVJMNFFSDEV-UHFFFAOYSA-N

Inchi：

1S/C38H32N2/c1-29-11-9-17-37(27-29)39(33-13-5-3-6-14-33)35-23-19-31(20-24-35)32-21-25-36(26-22-32)40(34-15-7-4-8-16-34)38-18-10-12-30(2)28-38/h3-28H,1-2H3

SMILES：

N(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1=C([H])C([H])=C([H])C(C([H])([H])[H])=C1[H])C1C([H])=C([H])C(=C([H])C=1[H])C1C([H])=C([H])C(=C([H])C=1[H])N(C1C([H])=C([H])C([H])=C([H])C=1[H])C1=C([H])C([H])=C([H])C(C([H])([H])[H])=C1[H]

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)物化性质

实验特性

LogP : 10.91000
PSA : 6.48000
折射率 : 1.671
沸点 : 680.1°C at 760 mmHg
熔点 : 168.0 to 172.0 deg-C
闪点 : 303.1±19.3 °C
颜色与性状 : 固体。
稳定性 : Stable. Incompatible with strong oxidizing agents.
溶解性 : 未确定。
密度 : 1.1±0.1 g/cm3

计算特性

精确分子量 : 516.25700
氢键供体数量 : 0
氢键受体数量 : 2
可旋转化学键数量 : 7
同位素质量 : 516.257
重原子数量 : 40
复杂度 : 660
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 10.8
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 6.5

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)安全信息

符号： GHS09
WGK Germany： 2
安全说明： S26; S36/37/39; S61
风险术语： R36/37/38
危险品标志： N
危险品运输编号： 3077
危害声明：H411
警示性声明：P273
储存条件： Store at 4°C,-4℃下存储更优
PackingGroup： III
危险类别码： 51/53
信号词： Warning
HazardClass： 9

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)国际标准相关数据

EINECS：

413-810-8

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)海关数据

海关编码：

2921590090

海关数据：

中国海关编码：

2921590090

概述：

2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)生产方法和用途

用途：

正孔传送材料的有机电致发光器件;

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N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)上下游

间氯甲苯氯苯 3-甲基二苯胺 4,4'-二碘代联苯 N,N'-二苯基联苯胺间溴甲苯间碘甲苯 4,4'-二溴联苯联苯胺

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N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4)参考资料

Reaxys RN：

4278249

Beilstein：

413-810-8

PubChem CID：

87568875

N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺(65181-78-4) MSDS

基础信息

Name:	N N -Diphenyl-N N -Di-M-Tolyl-Benzidine Material Safety Data Sheet
Synonym:	N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine
CAS:	65181-78-4

Section 1 - Chemical Product ? MSDS Name:N N -Diphenyl-N N -Di-M-Tolyl-Benzidine Material Safety Data Sheet
Synonym:N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
65181-78-4	N,N'-Diphenyl-N,N'-di-m-tolylbenzidine	100	413-810-8

Hazard Symbols: N
Risk Phrases: 51/53

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use dry chemical, carbon dioxide, or halon extinguisher.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 65181-78-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystals
Color: yellowish-white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 168 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C38H32N2
Molecular Weight: 516.2374

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, various hydrocarbons.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 65181-78-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N'-Diphenyl-N,N'-di-m-tolylbenzidine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 65181-78-4: No information available.
Canada
CAS# 65181-78-4 is listed on Canada's NDSL List.
CAS# 65181-78-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 65181-78-4 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A