653-11-2 (2,3,5,6-四氟苯肼,2,3,5,6-tetrafluorophenylhydrazine)

快速询单

结构式：

2,3,5,6-四氟苯肼MOL文件

CAS号：

653-11-2

中文名称：

2,3,5,6-四氟苯肼

英文名称：

2,3,5,6-tetrafluorophenylhydrazine

分子式：

C₆H₄F₄N₂

分子量：

180.102974891663

2,3,5,6-四氟苯肼(653-11-2)名称与标识符

名称

中文别名：

2,3,5,6-四氟苯肼;2,3,5,6-四氟苯基肼;

英文别名：

2,3,5,6-tetrafluorophenylhydrazine;(2,3,5,6-tetrafluorophenyl)hydrazine;TYMFVEOXNZYYTF-UHFFFAOYSA-;MFCD00007575;BS-9882;EN300-20871;CS-0206258;NSC-97000;2,3,5,6-tetrafluoro-phenylhydrazine;653-11-2;AKOS001476488;1-(2,3,5,6-Tetrafluorophenyl)hydrazine #;NSC 97000;EINECS 211-494-4;Hydrazine, (2,3,5,6-tetrafluorophenyl)-;NSC97000;A835060;InChI=1/C6H4F4N2/c7-2-1-3(8)5(10)6(12-11)4(2)9/h1,12H,11H2;FT-0609433;1-(2,3,5,6-Tetrafluorophenyl)hydrazine;TNP7RSM8H6;UNII-TNP7RSM8H6;DTXSID90215641;NS00042260;SCHEMBL359362;BBL019220;DB-054795;STK503803;DTXCID20138132;ALBB-006279;G83744;

标识符

MDL：

MFCD00007575

InChIKey：

TYMFVEOXNZYYTF-UHFFFAOYSA-N

Inchi：

1S/C6H4F4N2/c7-2-1-3(8)5(10)6(12-11)4(2)9/h1,12H,11H2

SMILES：

FC1C(=CC(=C(C=1NN)F)F)F

BRN：

745777

2,3,5,6-四氟苯肼(653-11-2)物化性质

实验特性

LogP : 2.30190
PSA : 38.05000
折射率 : 1.527
沸点 : 136.3°C at 760 mmHg
熔点 : 91-93 °C(lit.)
闪点 : 36.2°C
颜色与性状 : 浅黄色至棕色结晶性粉末。
溶解性 : 未确定。
敏感性 : Light Sensitive
密度 : 1.4197 (estimate)

计算特性

精确分子量 : 180.03100
氢键供体数量 : 2
氢键受体数量 : 2
可旋转化学键数量 : 1
同位素质量 : 180.031
重原子数量 : 12
复杂度 : 143
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 无
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 38A^2

2,3,5,6-四氟苯肼(653-11-2)安全信息

2,3,5,6-四氟苯肼(653-11-2)国际标准相关数据

EINECS：

211-494-4

2,3,5,6-四氟苯肼(653-11-2)海关数据

海关编码：

2928000090

海关数据：

中国海关编码：

2928000090

概述：

2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

申报要素：

品名, 成分含量, 用途

Summary：

2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

2,3,5,6-四氟苯肼(653-11-2)推荐厂家更多厂家(6)

公司名称	手机号/电话	联系人	QQ	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
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JACS-郑州杰克斯化工产品有限公司	15981966935 0371-86259281	杰克斯JACS	893596907	询单
上海依赫生物科技有限公司	17721395025 021-68882955	张经理	2423903095	询单
广东翁江化学试剂有限公司	13927875076 0751-2815987	罗雪云	3007432263	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单

2,3,5,6-四氟苯肼(653-11-2)相关文献

1. Predicting the photoinduced electron transfer thermodynamics in polyfluorinated 1,3,5-triarylpyrazolines based on multiple linear free energy relationships
Manjusha Verma,Aneese F. Chaudhry,Christoph J. Fahrni Org. Biomol. Chem. 2009 7 1536
2. Predicting the photoinduced electron transfer thermodynamics in polyfluorinated 1,3,5-triarylpyrazolines based on multiple linear free energy relationships
Manjusha Verma,Aneese F. Chaudhry,Christoph J. Fahrni Org. Biomol. Chem. 2009 7 1536
3. 512. Aromatic polyfluoro-compounds. Part XVII. The reaction of bispentafluorophenylmercury with nucleophiles
J. Burdon,P. L. Coe,M. Fulton,J. C. Tatlow J. Chem. Soc. 1964 2673
4. Notes
G. M. Badger,P. Cheuychit,W. H. F. Sasse,T. C. W. Mak,J. Trotter,A. R. Battersby,D. J. Le Count,W. P. Griffith,Z. S. Krzeminski,S. J. Angyal,B. H. M. Billinge,B. G. Gowenlock,G. M. Brooke,J. Burdon,J. C. Tatlow,S. J. Gregg,R. F. S. Tyson,W. Carruthers,J. R. Plimmer,D. Lavie,Y. Shvo,O. R. Gottlieb,R. B. Desai,M. L. Khorana,A. Holland,Leo A. Pohoryles,Izhar Gat,Shalom Sarel,J. D. Loudon,A. D. B. Sloan,Peter Bladon,Thomas Sleigh,W. Hewertson,R. A. Shaw,B. C. Smith,J. Chatt,B. L. Shaw,A. A. Williams,M. Halmann,L. Kugel,G. W. Kirby,G. Shaw,A. Yeadon,H. J. Emeléus,G. L. Hurst,John G. Carey,Ian T. Millar,Stanley S. Brown,Roy Wade,D. H. Brown,D. J. Alner J. Chem. Soc. 1962 3241
5. New catecholato oxorhenium(V) complexes
Catherine F. Edwards,William P. Griffith,Andrew J. P. White,David J. Williams J. Chem. Soc. Dalton Trans. 1992 957
6. Organobismuth compounds with the pincer ligand 2,6-(Me2NCH2)2C6H3: Monoorganobismuth(iii) carbonate, sulfate, nitrate, and a diorganobismuthenium(iii) salt
Hans J. Breunig,Mihai G. Nema,Cristian Silvestru,Albert P. Soran,Richard A. Varga Dalton Trans. 2010 39 11277
7. s-Block chalcogenoether chemistry – thio- and selenoether coordination with hard Group 2 ions
Paolo Farina,William Levason,Gillian Reid Dalton Trans. 2013 42 89
8. Structural studies in metal–purpurate complexes. Part 5. Crystal structure of di-μ-aqua-tetrakis(purpurato)distrontium tridecahydrate
Colin L. Raston,Allan H. White,Anthony C. Willis J. Chem. Soc. Dalton Trans. 1977 1368
9. Crystal structures of complexes between alkali-metal salts and cylic polyethers. Part 11. Complexes formed between 2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin (benzo-15-crown-5) and sodium perchlorate (1 : 1), sodium perchlorate (2 : 1), and sodium tetraphenylborate (2 : 1)
John D. Owen J. Chem. Soc. Dalton Trans. 1980 1066
10. Crystal structures of complexes between alkali-metal salts and cylic polyethers. Part 11. Complexes formed between 2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin (benzo-15-crown-5) and sodium perchlorate (1 : 1), sodium perchlorate (2 : 1), and sodium tetraphenylborate (2 : 1)
John D. Owen J. Chem. Soc. Dalton Trans. 1980 1066

2,3,5,6-四氟苯肼(653-11-2) MSDS

基础信息

Name:	2 3 5 6-Tetrafluorophenylhydrazine 97+% Material Safety Data Sheet
Synonym:	None Known
CAS:	653-11-2

Section 1 - Chemical Product ? MSDS Name:2 3 5 6-Tetrafluorophenylhydrazine 97+% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
653-11-2	2,3,5,6-Tetrafluorophenylhydrazine	97+%	211-494-4

Hazard Symbols: XN
Risk Phrases: 20/21

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 653-11-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Flakes
Color: light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 91.00 - 93.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H4F4N2
Molecular Weight: 180.10

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas, nitrogen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 653-11-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,5,6-Tetrafluorophenylhydrazine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 653-11-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 653-11-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 653-11-2 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A