Section 1 - Chemical Product ? MSDS Name:Bis(pentamethylcyclopentadienyl)manganese Material Safety Data Sheet
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS| CAS# | Chemical Name | content | EINECS# |
| 67506-86-9 | Bis(pentamethylcyclopentadienyl)mangan | | unlisted |
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION ? EMERGENCY OVERVIEW
Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Chronic manganese toxicity through inhalation may result in "manganism", which is a disease of the central nervous system involving psychic and neurological disorders.
Section 4 - FIRST AID MEASURES ? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES ? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES ? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE ? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Handle under argon.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under argon.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 67506-86-9: United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3 (as Mn) Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex organic compounds, as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC Mn) Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES ?
Physical State: Crystals
Color: orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 230 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C20H30Mn
Molecular Weight: 325.39
Section 10 - STABILITY AND REACTIVITY ? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, moisture, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION ? RTECS#:
CAS# 67506-86-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bis(pentamethylcyclopentadienyl)manganese - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION ?
Section 13 - DISPOSAL CONSIDERATIONS ? Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION ?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION ?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 67506-86-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67506-86-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67506-86-9 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION N/A
2269920866 
![ETHYL 2-(5-BROMOBENZO[D]THIAZOL-2-YL)ACETATE](http://hg.y866.cn/compound/lib/scimg/cas/150/791614-77-2.png "ETHYL 2-(5-BROMOBENZO[D]THIAZOL-2-YL)ACETATE")
