6984-99-2 (氯五氟丙酮,Chloropentafluoroacetone monohydrate)

CAS号:
6984-99-2
中文名称:
氯五氟丙酮
英文名称:
Chloropentafluoroacetone monohydrate
安全信息:
分子式:
C3H2ClF5O2
分子量:
200.491797924042

氯五氟丙酮(6984-99-2)名称与标识符

名称

中文别名:
氯五氟丙酮一水合物;3-(3-吡啶基)吡咯烷;Chloropentafluoroacetone Monohydrate 氯五氟丙酮一水合物;氯五氟丙酮;
英文别名:
2-Propanone,1-chloro-1,1,3,3,3-pentafluoro-, hydrate (1:1);Chloropentafluoroacetone Monohydrate;1-chloro-1,1,3,3,3-pentafluoro-acetone;1-chloro-1,1,3,3,3-pentafluoropropan-2-one;chloropentafluoro-2-propanonhydrate;chloropentafluoro-acetonhydrate;Chloropentafluoroacetone hydrate;CHLOROPENTAFLUOROACETONEMONOHYDRATE;Chloropentafluoroacetone, monohydrate;A814493;2,2-Propanediol,1-chloro-1,1,3,3,3-pentafluoro-;1-chloro-1,1,3,3,3-pentafluoropropan-2-one hydrate;1-chloro-1,1,3,3,3-pentafluoro-2-propanone hydrate;1-chloranyl-1,1,3,3,3-pentakis(fluoranyl)propan-2-one hydra;6984-99-2;FS-4158;CS-0455038;2036-62-6;CMMNKPFHVMVGQH-UHFFFAOYSA-N;1-chloro-1,1,3,3,3-pentafluoropropan-2-one;hydrate;D89341;FT-0636330;AKOS007930110;FT-0623685;1-chloranyl-1,1,3,3,3-pentakis(fluoranyl)propan-2-one hydrate;MFCD00150647;DB-055354;

标识符

MDL:
MFCD00150647
InChIKey:
CMMNKPFHVMVGQH-UHFFFAOYSA-N
Inchi:
1S/C3ClF5O.H2O/c4-2(5,6)1(10)3(7,8)9;/h;1H2
SMILES:
ClC(C(C(F)(F)F)=O)(F)F.O

氯五氟丙酮(6984-99-2)物化性质

实验特性

  • LogP : 1.88510
  • PSA : 26.30000
  • 折射率 : 1.3450-1.3490
  • 沸点 : 40.6°C at 760 mmHg
  • 熔点 : 19°C
  • 闪点 : 19 °C
  • 颜色与性状 : 不可用
  • 溶解性 : 不可用
  • 密度 : 1,73 g/cm3

计算特性

  • 精确分子量 : 199.96600
  • 氢键供体数量 : 1
  • 氢键受体数量 : 7
  • 可旋转化学键数量 : 1
  • 同位素质量 : 199.966
  • 重原子数量 : 11
  • 复杂度 : 150
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 拓扑分子极性表面积 : 18.1

氯五氟丙酮(6984-99-2)安全信息

氯五氟丙酮(6984-99-2)海关数据

海关编码:
2915900090
海关数据:

中国海关编码:

2915900090

概述:

2915900090. 其他饱和无环一元羧酸及其酸酐(酰卤、过氧)化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

监管条件:

A.入境货物通关单
B.出境货物通关单

检验检疫类别:

R.进口食品卫生监督检验
S.出口食品卫生监督检验
M.进口商品检验
N.出口商品检验

Summary:

2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

氯五氟丙酮(6984-99-2)推荐厂家 更多厂家(8)

氯五氟丙酮(6984-99-2)参考资料

Reaxys RN:
1773589
PubChem CID:

氯五氟丙酮(6984-99-2) MSDS

基础信息

  Chloropentafluoroacetone Monohydrate
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Chloropentafluoroacetone Monohydrate    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 3    
    Category 2
  Acute toxicity (Dermal)
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger    
  Hazard statements        Toxic if swallowed    
    Fatal in contact with skin
  Precautionary statements:
    Do not get in eyes, on skin, or on clothing.
  [Prevention]
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves and eye/face protection.
    IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse
  [Response]
    mouth.
    IF ON SKIN: Gently wash with plenty of soap and water.
    Remove/Take off immediately all contaminated clothing.
    Wash contaminated clothing before reuse.
    Immediately call a POISON CENTER or doctor/physician.
    Store locked up.
  [Storage]
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        Chloropentafluoroacetone Monohydrate    
    >95.0%(T)
  Percent:
  CAS Number:        6984-99-2    
  Chemical Formula:        C3ClF5O·H2O    
  Chloropentafluoroacetone Monohydrate

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of    
    soap and water. Immediately call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing.Immediately call a POISON CENTER or
    doctor/physician.
  Ingestion:        Immediately call a POISON CENTER or doctor/physician. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (self-contained breathing apparatus). Keep    
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapour or mist. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  Personal protective equipment
  Respiratory protection:        Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied    
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.    
  Chloropentafluoroacetone Monohydrate

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Colorless - Pale reddish yellow    
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:19°C (Freezing point)
  Boiling point/range:        No data available    
  Flash point:        No data available    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        1.73    
  Solubility(ies):
  [Water]        No data available    
  [Other solvents]        No data available    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Hydrogen chloride
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        orl-rat LD50:85 mg/kg    
    skn-rbt LD50:81 mg/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
  NTP =        No data available    
  Reproductive toxicity:        No data available    
  RTECS Number:        UC1225000    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
    No data available
  Crustacea:
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
    No data available
  Henry's Law
  constant(PaM3/mol):
  Chloropentafluoroacetone Monohydrate

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local
    regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        6.1: Toxic substance.    
  UN-No:        2810    
  Proper shipping name:        Toxic liquid, organic, n.o.s.    
  Packing group:        III    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A