7598-26-7 (2-氨基-3-硝基-5-甲基吡啶,5-Methyl-3-nitropyridin-2-amine)

2-氨基-3-硝基-5-甲基吡啶(7598-26-7)名称与标识符

名称

中文别名:
2-氨基-3-硝基-5-甲基吡啶;2-氨基-5-甲基-3-硝基吡啶;5-甲基-2-氨基-3-硝基吡啶;6-氨基-5-硝基-3-甲基吡啶;
英文别名:
5-Methyl-3-nitropyridin-2-amine;2-Amino-3-Nitro-5-Methyl Pyridine;2-Amino-3-nitro-5-picoline;2-AMino-5-Methyl-3-nitropyridine;2-Pyridinamine, 5-methyl-3-nitro-;6-AMino-5-nitro-3-picoline;5-Methyl-3-nitro-2-aminopyridine;2-amino-3-nitro-5-methylpyridine;5-methyl-3-nitro-2-pyridylamine;NSC403371;PubChem1273;ZJKGRSJMFDIRPX-UHFFFAOYSA-N;SBB051814;5-methyl-3-nitro-pyridin-2-ylamine;AB02050;MCULE-4;AKOS006340936;CS-W022413;SCHEMBL307869;MFCD00047442;5-methyl-3-nitro-pyridin-2-amine;7598-26-7;AM87176;BDBM626103;FT-0636531;AC-25198;A9642;2-Pyridinamine,5-methyl-3-nitro-;DS-12902;EN300-214418;NSC-403371;DTXSID50323216;5-Methyl-3-nitropyridin-2-amine;2-Amino-3-nitro-5-methylpyridine;A2565;pyridine, 2-amino-5-methyl-3-nitro-;DB-056007;

标识符

MDL:
MFCD00047442
InChIKey:
ZJKGRSJMFDIRPX-UHFFFAOYSA-N
Inchi:
1S/C6H7N3O2/c1-4-2-5(9(10)11)6(7)8-3-4/h2-3H,1H3,(H2,7,8)
SMILES:
[O-][N+](C1C(N)=NC=C(C)C=1)=O

2-氨基-3-硝基-5-甲基吡啶(7598-26-7)物化性质

实验特性

  • LogP : 1.98480
  • PSA : 84.73000
  • 沸点 : 318.9°C at 760 mmHg
  • 熔点 : 189-193 °C
  • 闪点 : 146.7 °C
  • 颜色与性状 : 赭色结晶性粉末
  • 溶解性 : 未确定
  • 密度 : 1.354

计算特性

  • 精确分子量 : 153.05400
  • 氢键供体数量 : 1
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 0
  • 同位素质量 : 153.053826
  • 重原子数量 : 11
  • 复杂度 : 156
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 1.2
  • 互变异构体数量 : 2
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 84.7

2-氨基-3-硝基-5-甲基吡啶(7598-26-7)海关数据

海关编码:
2933399090
海关数据:

中国海关编码:

2933399090

概述:

2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素:

品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期

Summary:

2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-氨基-3-硝基-5-甲基吡啶(7598-26-7)推荐厂家 更多厂家(30)

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2-氨基-3-硝基-5-甲基吡啶(7598-26-7) MSDS

基础信息

Name:6-Amino-5-nitro-3-picoline Material Safety Data Sheet
Synonym:2-Amino-5-methyl-3-nitropyridine
CAS:7598-26-7
Section 1 - Chemical Product ? MSDS Name:6-Amino-5-nitro-3-picoline Material Safety Data Sheet
Synonym:2-Amino-5-methyl-3-nitropyridine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
7598-26-76-Amino-5-nitro-3-picoline100unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7598-26-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H7N3O2
Molecular Weight: 153.14

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 7598-26-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
6-Amino-5-nitro-3-picoline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7598-26-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7598-26-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7598-26-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A