7790-48-9 (四碘化碲,Tellurium tetraiodide)

CAS号:
7790-48-9
中文名称:
四碘化碲
英文名称:
Tellurium tetraiodide
分子式:
I4Te
分子量:
635.217887878418
简介:
中文名称:四碘化碲
中文别名:碘化碲;碘化碲(IV)
英文名称:tellurium tetraiodide;tellurium(IV) iodide
分子式:TeI4
性质:青铜灰色结晶。密度5.05g/cm3。熔点280℃。在潮湿空气中稳定,灼热分解生成碘,水中分解生成二氧化碲和碘化氢,能溶于氢碘酸、碱液和氨水,略溶于丙酮。由六氢氧化碲和碘化氢反应制取。

四碘化碲(7790-48-9)名称与标识符

名称

中文别名:
四碘化碲;碘化碲;碘化碲(IV);
英文别名:
Tellurium(IV) iodide;Tellurium tetraiodide;E4-tellane;Tellur(IV) iodid;tellurium iodide;tetraiodo-;Tellurium iodide (TeI4), (T-4)-;ZB48I033V5;TeI4;Tellurium( cento) iodide;Tellurium iodide(TeI4), (T-4)-;Tellurium( cento) iodide (99.9%-Te);7790-48-9;TELLURIUM TETRAIODIDE [MI];Q2346228;DTXSID1064877;UNII-ZB48I033V5;MFCD00049578;EINECS 232-210-5;TELLURIUM(IV)IODIDE;(T4)Tellurium iodide (TeI4);DTXCID7048085;Tellurium iodide (TeI4), (T4);Tellurium (IV) iodide;

标识符

MDL:
MFCD00049578
InChIKey:
XCOKHDCPVWVFKS-UHFFFAOYSA-N
Inchi:
1S/I4Te/c1-5(2,3)4
SMILES:
I[Te](I)(I)I

四碘化碲(7790-48-9)物化性质

实验特性

  • LogP : 3.16200
  • PSA : 0.00000
  • Merck : 14,9127
  • 水溶性 : Decomposes slowly in cold water to TeO{2} and HI
  • 熔点 : 280°C
  • 颜色与性状 : 青铜灰色结晶。在潮解空气中稳定。
  • 敏感性 : Moisture Sensitive
  • 密度 : 5.05 g/mL at 25 °C(lit.)

计算特性

  • 精确分子量 : 637.52400
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 637.524095
  • 重原子数量 : 5
  • 复杂度 : 19.1
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

四碘化碲(7790-48-9)安全信息

四碘化碲(7790-48-9)国际标准相关数据

EINECS:
232-210-5

四碘化碲(7790-48-9)生产方法和用途

用途:
实验用
生产方法:
1.用原碲酸与氢碘酸反应即可生成四碘化碲。在室温下将高浓度的原碲酸Te(OH)6与稍稍过量的浓氢碘酸(相对密度为2 00)混合,即刻有灰色的四碘化碲沉淀出来。用玻璃砂芯漏斗吸滤,并尽量将其压干。常温下将母液蒸发浓缩,还可以得到相当多的产物。将所得的结晶产物干燥后,用纯的四氯化碳洗涤以除去其中的碘,洗涤时可将结晶在四氯化碳中弄碎,并时时更换洗涤液体,直至洗涤液不再有颜色为止。最后干燥并密封保存。

四碘化碲(7790-48-9)推荐厂家 更多厂家(25)

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上海吉至生化科技有限公司 18117592386
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JACS-郑州杰克斯化工产品有限公司 15981966935
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深圳市瑞吉特生物科技有限公司 15813841136
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上海创赛科技有限公司 15021221957
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凌度 2852351983
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铼博(上海)生化科技有限公司 13311756052
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南通众合化工新材料有限公司 18762756250
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南通众合化工新材料有限公司 18762756250
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四碘化碲(7790-48-9)上下游

四碘化碲(7790-48-9)相关文献

四碘化碲(7790-48-9) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Tellurium (IV) iodide (99.9%-Te)    
   CAS Registry Number:       7790-48-9    
   Formula:       TeI4    
   EINECS Number:       232-210-5    
   Chemical Family:       metal halide    
   Synonym:       Tellurium tetraiodide.    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       7790-48-9       100%       0.1mg/m3 (as Te)       0.1mg/m3 (as Te)    

Section 3: Hazards Identification
   Causes severe skin, eye and respiratory tract irritation with cough, breathing difficulty, nausea and vomiting.
   Emergency Overview:
   Prolonged exposure may produce a mild toxic syndrome known as iodism.
   Primary Routes of Exposure:       Contact with skin and eyes. Inhalation of dust.    
   Eye Contact:       Causes redness, pain, and blurred vision. Splashes from solutions may cause eye damage.    
   Skin Contact:       Causes severe irritation, ulcerations, itching, pimples, boils, hives, blisters and skin burns.    
   Inhalation:       Causes irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.    
   Ingestion:       May cause severe irritation to the gastrointestinal tract with abdominal pain, nausea, and vomiting.    
   May cause coughing, nausea, and vomiting. Skin and eye contact will cause severe irritation. Tellurium may
   Acute Health Affects:
   cause garlic odor of breath, metallic taste, sleepiness, headache and nausea.
   Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and
   Chronic Health Affects:       irritation of mucous membranes. Prolonged exposure to tellurium may cause drowsiness and loss of appetite.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
   Spill and Leak Procedures:
   raising dust.

SECTION 7: Handling and Storage
   Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of
   Handling and Storage:
   air or nitrogen. Prolonged exposure to the atmosphere may degrade the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       -4 mesh gran.    
   Molecular Weight:       635.22    
   Melting Point:       280°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       5.403    
   Odor:       none    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA 313.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A