8007-40-7 (天然芥菜籽油,Mustardseed Oil)

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Section 1. Chemical Product and Company Identification
    Mustard oil, natural
    Common Name/
    Trade Name
    Mustard oil, natural

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Section 4. First Aid Measures
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least
    Eye Contact
    15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
    In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
    Skin Contact
    clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes
    before reuse. Get medical attention immediately.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention immediately.
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband.    
    If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation.
    WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled
    material is toxic, infectious or corrosive. Seek immediate medical attention.
    If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
    Ingestion
    an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
    immediately.
    Serious Ingestion        Not available.    

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Section 5. Fire and Explosion Data
    Flammability of the Product Flammable.
    Auto-Ignition Temperature Not available.
    CLOSED CUP: 44.444°C (112°F).
    Flash Points
    Not available.
    Flammable Limits
    These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
    Products of Combustion
    Fire Hazards in Presence of Flammable in presence of open flames and sparks, of heat.
    Various Substances
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards in
    Risks of explosion of the product in presence of static discharge: Not available.
    Presence of Various
    Slightly explosive in presence of heat.
    Substances
    Flammable liquid, soluble or dispersed in water.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemical powder.
    and Instructions
    LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent
    pressure build-up, autoignition or explosion.
    Vapor may travel considerable distance to source of ignition and flash back.
    Special Remarks on
    Contact with metals may evolve flammable hydrogen gas.
    Fire Hazards
    Vapor may form explosive mixtures with air.
    When heated to decomposition it emits highly toxic fumes of cyanides.
    Vapor may form explosive mixtures with air.
    Special Remarks on
    Explosion Hazards

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Section 6. Accidental Release Measures
    Absorb with an inert material and put the spilled material in an appropriate waste disposal.
    Small Spill
    Large Spill        Flammable liquid. Poisonous liquid.    
    Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or
    other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray to
    disposal.
    Mustard oil, natural

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Section 7. Handling and Storage
    Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
    Precautions
    ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,
    wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the
    label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
    Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
    Storage
    closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Sensitive to light. Store
    in light-resistant containers.

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Section 8. Exposure Controls/Personal Protection
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
    Engineering Controls
    respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
    location.
    Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
    Personal Protection
    Personal Protection in Case Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to
    avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
    of a Large Spill
    handling this product.
    Allyl isothiocyanate, natural
    Exposure Limits
    STEL: 1 from AIHA [United States] Inhalation
    STEL: 4 (mg/m3) from AIHA [United States] Inhalation
    Consult local authorities for acceptable exposure limits.

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Section 9. Physical and Chemical Properties
    Liquid. (Oily liquid.)        Pungent mustard. Irritant.    
    Physical state and        O dor    
    appearance
    Sharp biting.
    Taste
    Not applicable.
    Molecular Weight
    Colorless to light yellow.
    Color
    Not available.
    pH (1% soln/water)
    148°C (298.4°F) - 154 C.
    Boiling Point
    -80°C (-112°F)
    Melting Point
    Not available.
    Critical Temperature
    1.008 - 1.02(Water = 1)
    Specific Gravity
    0.5 kPa (@ 20°C)
    Vapor Pressure
    3.41 (Air = 1)
    Vapor Density
    Not available.
    Volatility
    The highest known value is 0.008 ppm (Allyl isothiocyanate)
    Odor Threshold
    Not available.
    Water/Oil Dist. Coeff.
    Not available.
    Ionicity (in Water)
    See solubility in water, diethyl ether.
    Dispersion Properties
    Soluble in diethyl ether.
    Solubility
    Slightly soluble in cold water.
    Solubility in Water: 5% @ 20 deg. C.
    Completely miscible with chloroform, benzene.
    Miscible with alcohol and most organic solvents.
    Solubility in 70% alcohol: 1 ml dissolves in 10 ml.
    Solubility in 80% Ethanol: 1 ml dissolves in 8 ml.
    Soluble in Carbon disulfide.
    Mustard oil, natural

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Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Not available.
    Instability Temperature
    Conditions of Instability Heat, ignition sources (flames, sparks, etc.), incompatible materials
    Incompatibility with various Reactive with oxidizing agents, acids, alkalis.
    substances
    Non-corrosive in presence of glass.
    Corrosivity
    Tends to darken on aging.
    Special Remarks on
    Incompatible with amines, alcohols.
    Reactivity
    Dangerous on contact with acids or acid fumes. It emits highly toxic fumes of cyanides. Sensitive to light.
    Not available.
    Special Remarks on
    Corrosivity
    Will not occur.
    Polymerization

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Section 11. Toxicological Information
    Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
    Routes of Entry
    Acute oral toxicity (LD50): 117 mg/kg (Rat) (Calculated value for the mixture).
    Toxicity to Animals
    Acute dermal toxicity (LD50): 92 mg/kg (Rabbit) (Calculated value for the mixture).
    Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Allyl isothiocyante, natural].
    MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Allyl isothiocyanate, natural]. Mutagenic for
    bacteria and/or yeast. [Allyl isothiocyanate, natural].
    Other Toxic Effects on        Very hazardous in case of skin contact (permeator).    
    Humans        Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).    
    Not available.
    Special Remarks on
    Toxicity to Animals
    Special Remarks on        May affect genetic material (mutagenic).    
    Chronic Effects on Humans May cause adverse reproductive effects.
    May cause cancer based on animal test data (Allyl isothiocyanate, natural)
    Acute Potential Health Effects:
    Special Remarks on other
    Skin: Causes skin irritation and possible blistering and burns. May be fatal if absorbed through skin.
    Toxic Effects on Humans
    Eyes: Causes eye irritation. Lachrymator (substance which increases the flow of tears).
    Inhalation: Causes respiratory tract irritation.
    Ingestion: Harmful if swallowed. Causes gastroenteritis (gastrointestinal tract irritation) with nausea vomiting,
    diarrhea.
    Chronic Potential Health Effects:
    Skin: Prolonged or repeated skin contact may cause skin sensitization, an allergic reaction.\
    Inhalation: Prolonged or repeated inhalation of vapor or mist may cause allergy type reaction to develop with watery
    eyes, sneezing, runny nose and symptoms of asthma (coughing, wheezing, and chest tightness). One allery develops,
    even very limited exposures can cause symptoms to develop.
    Ingestion: Prolonged or repeated ingestion of larger amounts may affect the liver, blood (changes in serum
    composition), and behavior/central nervous system (somnolence).

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Section 12. Ecological Information
    Not available.
    Ecotoxicity
    Not available.
    BOD5 and COD
    Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    arise.
    The products of degradation are less toxic than the product itself.
    Toxicity of the Products
    of Biodegradation
    Mustard oil, natural
    Not available.
    Special Remarks on the
    Products of Biodegradation

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Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental control    
    regulations.

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Section 14. Transport Information
    DO T Cl assi fi cati on        CLASS 3: Flammable liquid.    
    CLASS 6.1: Poisonous material.
    : Allyl isothiocyanate, stabilized (Mustard oil, synthetic) UNNA: 1545 PG: II
    Identification
    Not available.
    Special Provisions for
    Transport
    DO T (Pi ctograms)

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Section 15. Other Regulatory Information and Pictograms
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    Federal and State
    cause birth defects which would require a warning under the statute: No products were found.
    Regulations
    Pennsylvania RTK: Allyl isothiocyanate; Mustard oil, natural
    Minnesota: Allyl isothiocyanate
    Massachusetts RTK: Allyl isothiocyanate
    Massachusetts spill list: Allyl isothiocyanate
    New Jersey: Allyl isothiocyanate
    California Director's List of Hazardous Substances: Allyl isothiocyanate
    TSCA 8(b) inventory: Allyl isothiocyanate; Mustard oil, natural
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    California
    cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause birth defects which would require a warning under the statute: No products were found.
    OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
    Other Regulations
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
    232-358-0).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Korea: Listed on Natioinal Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C
    Other Classifications        WHMIS (Canada)    
    (200°F).
    CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
    DSCL (EEC)        R10- Flammable.        S16- Keep away from sources of ignition - No    
    R24/25- Toxic in contact with skin and if        smoking.    
    swallowed.        S26- In case of contact with eyes, rinse    
    R36/37/38- Irritating to eyes, respiratory        immediately with plenty of water and seek    
    system and skin.        medical advice.    
    S28- After contact with skin, wash immediately
    with plenty of soap and water
    S36/37/39- Wear suitable protective clothing,
    gloves and eye/face protection.
    S45- In case of accident or if you feel unwell,
    seek medical advice immediately (show the
    label where possible).
    Mustard oil, natural
    Health Hazard
    HMIS (U.S.A.)        3 National Fire Protection    
    2 Flammability
    2 Association (U.S.A.)
    Fire Hazard
    3 1 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    h
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG(Canada)
    (Pictograms)
    3
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Vapor respirator. Be sure to use an
    approved/certified respirator or equivalent.
    Wear appropriate respirator when ventilation
    is inadequate.
    Splash goggles.

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SECTION 16 - ADDITIONAL INFORMATION
N/A