84-15-1 (1,2-三联苯,O-Terphenyl)

95-50-1

_100%

反应条件：

1.1 Reagents: Potassium hydroxide Catalysts: Palladium diacetate , 2′-(Dicyclohexylphosphino)-N,N-dimethyl[1,1′-biphenyl]-2-amine Solvents: Toluene ; 7 - 8 h, 90 °C

参考文献：

Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes

Vasil'ev, Andrei A.; Burukin, Alexander S.; Zhdankina, Galina M.; Zlotin, Sergei G., Mendeleev Communications, 2021, 31(3), 400-402

合成路线：1 步

52542-81-1

2113-51-1

_99%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Palladium Solvents: Ethanol ; 60 min

参考文献：

The impact of the physical state and the reaction phase in the direct mechanocatalytic Suzuki-Miyaura coupling reaction

Yoo, Kwangho; Fabig, Sven; Graetz, Sven; Borchardt, Lars, Faraday Discussions, 2023, 241, 206-216

合成路线：1 步

4688-76-0

108-90-7

_99%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: (SP-4-2)-[N,N-Bis[(diphenylphosphino-κP)methyl]-2-(trifluoromethyl)benzenamine]d… Solvents: Dimethylformamide , Water ; 7 h, 80 °C

参考文献：

Synthesis, characterization and catalytic activity of new aminomethyldiphosphine-Pd(II) complexes for Suzuki cross-coupling reaction

Keles, Mustafa; Y□lmaz, Mustafa Kemal, Applied Organometallic Chemistry, 2014, 28(2), 91-94

合成路线：1 步

95-50-1

_99%

反应条件：

1.1 Reagents: Cesium carbonate Catalysts: (SP-4-1)-[7,9-Bis[2,6-bis(1-methylethyl)phenyl]-7,9-dihydro-8H-acenaphth[1,2-d]i… Solvents: tert-Butanol ; 24 h, 80 °C

参考文献：

Robust Acenaphthoimidazolylidene Palladium Complexes: Highly Efficient Catalysts for Suzuki-Miyaura Couplings with Sterically Hindered Substrates

Tu, Tao; Sun, Zheming; Fang, Weiwei; Xu, Mizhi; Zhou, Yunfei, Organic Letters, 2012, 14(16), 4250-4253

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Sodium carbonate , Oxygen Catalysts: Palladium acetylacetonate , 3,9-Bis[2,6-bis(1,1-dimethylethyl)-4-methylphenyl]-2,4,8,10-tetraoxa-3,9-diphosp… Solvents: 1,4-Dioxane , Water ; 12 h, 90 °C
1.2 Reagents: Ammonium chloride Solvents: Water

参考文献：

Suzuki-Miyaura coupling reactions using phosphite ligands

Jang, Mihee; Jo, Youngshin; Oh, Il-Kwon; Jung, Hyun Min; Lee, Sunwoo, Synthesis, 2009, (12), 2073-2075

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: (SP-4-4)-Chloro[2-[(diphenylphosphino-κP)amino]-6-(1H-pyrazol-1-yl-κN2)phenyl-κC… Solvents: Water ; 2 h, 100 °C

参考文献：

A nonsymmetric pincer-type palladium catalyst in Suzuki, Sonogashira, and Hiyama couplings in neat water

Ines, Blanca; SanMartin, Raul; Churruca, Fatima; Dominguez, Esther; Urtiaga, Miren Karmele; et al, Organometallics, 2008, 27(12), 2833-2839

合成路线：1 步

615-42-9

_98%

反应条件：

1.1 Reagents: Sodium hydroxide Catalysts: Hydrochloric acid , Palladium chloride Solvents: 1,4-Dioxane ; 12 h, 120 °C

参考文献：

Exploring the coordination confinement effect of divalent palladium/zero palladium doped polyaniline-networking: As an excellent-performance nanocomposite catalyst for C-C coupling reactions

Wang, Gang; Wu, Zhiqiang; Liang, Yanping; Liu, Wanyi; Zhan, Haijuan; et al, Journal of Catalysis, 2020, 384, 177-188

合成路线：1 步

591-51-5

_98%

反应条件：

1.1 Catalysts: (SP-4-1)-[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-yliden… ; 10 min, rt
1.2 Reagents: Ammonium chloride Solvents: Water ; rt

参考文献：

Fast, greener and scalable direct coupling of organolithium compounds with no additional solvents

Pinxterhuis, Erik B.; Giannerini, Massimo; Hornillos, Valentin; Feringa, Ben L., Nature Communications, 2016, 7,

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Tripotassium phosphate Catalysts: Styrene-4-vinylbenzyl chloride copolymer (reaction products with diphenylphosphine and complex with palladium) Solvents: Toluene , Water ; 90 min, 100 °C

参考文献：

An Efficient and Reusable Palladium Catalyst Supported on a Rasta Resin for Suzuki-Miyaura Cross-Couplings

Diebold, Carine; Becht, Jean-Michel; Lu, Jinni; Toy, Patrick H.; Le Drian, Claude, European Journal of Organic Chemistry, 2012, 2012(5), 893-896

合成路线：1 步

583-53-9

_98%

反应条件：

1.1 Reagents: Sodium carbonate Catalysts: Tetraamminedichloropalladium(2+) Solvents: Dimethylacetamide , Water ; 15 min, 100 °C

参考文献：

Pd-loaded NaY zeolite as a highly active catalyst for ligandless Suzuki-Miyaura reactions of aryl halides at low Pd loadings under aerobic conditions

Durgun, Gulay; Aksin, Ozge; Artok, Levent, Journal of Molecular Catalysis A: Chemical, 2007, 278(1-2), 189-199

合成路线：1 步

2633-57-0

_98%

反应条件：

1.1 Reagents: Tetrabutylammonium fluoride Solvents: Dimethyl sulfoxide , Water ; rt; 1 h, rt
1.2 Catalysts: Tricyclohexylphosphine , Palladium chloride ; rt; rt → 80 °C; 3 h, 80 °C; 80 °C → rt

参考文献：

Cross-coupling of triallyl(aryl)silanes with aryl bromides and chlorides: An alternative convenient biaryl synthesis

Sahoo, Akhila K.; Oda, Takuro; Nakao, Yoshiaki; Hiyama, Tamejiro, Advanced Synthesis & Catalysis, 2004, 346(13-15), 1715-1727

合成路线：1 步

2633-57-0

_98%

反应条件：

1.1 Reagents: Tetrabutylammonium fluoride Solvents: Dimethyl sulfoxide , Water ; 1 h, rt
1.2 Catalysts: Tricyclohexylphosphine , Palladium chloride Solvents: Dimethyl sulfoxide , Water ; 3 h, 80 °C
1.3 Reagents: Water Solvents: Dimethyl sulfoxide , Water

参考文献：

Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides

Nakao, Yoshiaki; Oda, Takuro; Sahoo, Akhila K.; Hiyama, Tamejiro, Journal of Organometallic Chemistry, 2003, 687(2), 570-573

合成路线：1 步

_97%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Palladium (complexes with an oxidized pillar[5]arene-p-xylylene dichloride copolymer) , 2351175-01-2 Solvents: Ethanol , Water ; 1 h, 80 °C

参考文献：

Pillarquinone-Based Porous Polymer for a Highly-Efficient Heterogeneous Organometallic Catalysis

Lan, Shang; Yang, Xuan; Shi, Kejia; Fan, Rong; Ma, Da, ChemCatChem, 2019, 11(12), 2864-2869

合成路线：1 步

615-42-9

143-66-8

_97%

反应条件：

1.1 Reagents: Sodium carbonate Catalysts: Palladium (complexes with polymers) Solvents: Isopropanol , Ethyl acetate , Water ; 1 s, 70 °C

参考文献：

Palladium membrane-installed microchannel devices for instantaneous Suzuki-Miyaura cross-coupling

Yamada, Yoichi M. A.; Watanabe, Toshihiro; Beppu, Tomohiko; Fukuyama, Naoshi; Torii, Kaoru; et al, Chemistry - A European Journal, 2010, 16(37), 11311-11319

合成路线：1 步

1252686-94-4

_97%