847978-62-5 (4-[N-(4-溴苯基)-N-苯胺]苯甲醛,4-(N-(4-bromophenyl)anilino)benzaldehyde)

_99%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; 1 h, 0 °C; 12 h, 50 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ; 12 h, neutralized, 70 °C

参考文献：

Synthesis of sensitizers containing donor cascade of triarylamine and dimethylarylamine moieties for dye-sensitized solar cells

Zhang, Lu; Liu, Yongkang; Wang, Zhongyuan; Liang, Mao; Sun, Zhe; et al, Tetrahedron, 2010, 66(18), 3318-3325

合成路线：1 步

_98%

反应条件：

1.1 Reagents: N-Bromosuccinimide Solvents: Chloroform ; rt

参考文献：

Synthesis, characterization and two-photon PDT efficacy studies of triads incorporating tumor targeting and imaging components

Spangler, C. W.; Starkey, J.; Rebane, A.; Drobizhev, M.; Meng, F.; et al, Proceedings of SPIE, 2008, 6845,

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Bromine Solvents: Dichloromethane ; 8 h, rt; overnight, rt

参考文献：

Synthesis and properties of new two-photon absorption chromophores containing 3,5-dicyano-2,4,6-tristyrylpyridine as the core

Wang, Hongli; Li, Zhen; Shao, Pin; Liang, Yanke; Wang, Hui; et al, New Journal of Chemistry, 2005, 29(6), 792-797

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; 0 °C; 30 min, 0 °C; 5 h, 50 °C
1.2 Reagents: Water ; pH 7, cooled

参考文献：

Synthesis and optoelectronic properties of a dinuclear iridium (III) complex containing a picolinic acid derivative by nonconjugated linkage with a D-A-D core

Xiong, Wenjing; He, Keqi; Zhang, Deyuan; Yang, Jiajing; Peng, Mingsheng; et al, Journal of Organometallic Chemistry, 2022, 959,

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; 0 °C; 20 min, rt
1.2 Solvents: Dimethylformamide ; rt; 2 h, 60 °C; 60 °C → rt
1.3 Reagents: Water ; cooled
1.4 Reagents: Sodium bicarbonate Solvents: Water ; pH 7

参考文献：

Effects of Self-Assembly on the Photogeneration of Radical Cations in Halogenated Triphenylamines

Hossain, Muhammad Saddam; Sindt, Ammon J.; Goodlett, Rachel L.; Shields, Dylan J.; O'Connor, Colin J.; et al, Journal of Physical Chemistry C, 2021, 125(36), 19991-20002

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; cooled; 20 min, cooled
1.2 5 min, 110 °C; 2 h, 110 °C → 60 °C; 60 °C → rt
1.3 Reagents: Sodium bicarbonate Solvents: Water ; neutralized, cooled

参考文献：

Guest Inclusion Modulates Concentration and Persistence of Photogenerated Radicals in Assembled Triphenylamine Macrocycles

Sindt, Ammon J.; DeHaven, Baillie A. ; Goodlett, Rachel L.; Hartel, Johannes O.; Ayare, Pooja J.; et al, Journal of the American Chemical Society, 2020, 142(1), 502-511

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; 0 °C; 20 min, rt
1.2 rt → 110 °C; 2 h, 110 °C → 60 °C; 60 °C → rt
1.3 Reagents: Sodium bicarbonate Solvents: Water ; neutralized

参考文献：

UV-irradiation of self-assembled triphenylamines affords persistent and regenerable radicals

Sindt, Ammon J.; De Haven, Baillie A.; McEachern, David F.; Dissanayake, D. M. M. Mevan; Smith, Mark D.; et al, Chemical Science, 2019, 10(9), 2670-2677

合成路线：1 步

_91%

反应条件：

1.1 Reagents: Phosphorus oxychloride Solvents: Dimethylformamide ; 30 min, 0 °C; 0 °C → 60 °C; overnight, 60 °C; 60 °C → rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ; neutralized, 0 °C

参考文献：

Self-assembled AIEgen nanoparticles for multiscale NIR-II vascular imaging

Li, Yaxi; Hu, Dehong; Sheng, Zonghai; Min, Tianliang; Zha, Menglei; et al, Biomaterials, 2021, 264,

合成路线：1 步

_91%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; 12 h, 15 °C

参考文献：

Two-Photon Luminescence and Second-Harmonic Generation in Organic Nonlinear Surface Comprised of Self-Assembled Frustum Shaped Organic Microlasers

Venkatakrishnarao, Dasari; Narayana, Yemineni S. L. V.; Mohaiddon, Mahamad A.; Mamonov, Evgeniy A.; Mitetelo, Nikolai; et al, Advanced Materials (Weinheim, 2017, 29(15),

合成路线：1 步

_91%

反应条件：

1.1 Reagents: Phosphorus oxychloride Solvents: 1,2-Dichloroethane ; 24 h, reflux

参考文献：

Photoinduced processes of newly synthesized bis-ferrocene- and bis-fullerene-substituted tetrads with a triphenylamine central block

Seok, Jai Han; Park, Seung Ho; El-Khouly, Mohamed E.; Araki, Yasuyuki; Ito, Osamu; et al, Journal of Organometallic Chemistry, 2009, 694(12), 1818-1825

合成路线：1 步

_91%

反应条件：

1.1 Reagents: Phosphorus oxychloride ; rt

参考文献：

Hybrids of Triphenylamine-Functionalized Polyacetylenes and Multiwalled Carbon Nanotubes: High Solubility, Strong Donor-Acceptor Interaction, and Excellent Photoconductivity

Zhao, Hui; Yuan, Wang Zhang; Tang, Li; Sun, Jing Zhi; Xu, Haipeng; et al, Macromolecules (Washington, 2008, 41(22), 8566-8574

合成路线：1 步

_89%

反应条件：

1.1 Reagents: Phosphorus oxychloride Solvents: Dimethylformamide ; 0 °C; 45 °C; 2 h, 45 °C; 45 °C → rt
1.2 Reagents: Sodium carbonate Solvents: Water ; pH 7, rt

参考文献：

Synthesis and Properties of Novel Borondipyrromethene (BODIPY)-Tethered Triphenylamine Conjugates

Wang, Yucai; Liao, Junxu; Wang, Bangying; Chen, Hongbiao; Zhao, Hongbin; et al, Australian Journal of Chemistry, 2015, 68(10), 1485-1491

合成路线：1 步

_89%

反应条件：

1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide ; 30 min, -10 °C → 50 °C; overnight, 50 °C
1.2 Reagents: Hydrochloric acid Solvents: Water

参考文献：

Optimization of multiple electron donor and acceptor in carbazole-triphenylamine-based molecules for application of dye-sensitized solar cells

Yang, Chien-Hsin; Liao, Shao-Hong; Sun, Yu-Kuang; Chuang, Yao-Yuan; Wang, Tzong-Liu; et al, Journal of Physical Chemistry C, 2010, 114(49), 21786-21794

合成路线：1 步

_86%

反应条件：

1.1 Reagents: N-Bromosuccinimide Solvents: Acetic acid , Chloroform ; 20 h, rt
1.2 Solvents: Water ; rt

参考文献：

A fluorescent probe for intracellular cysteine overcoming the interference by glutathione

Tian, Minggang; Guo, Fuqiang; Sun, Yuming; Zhang, Weijia; Miao, Fang; et al, Organic & Biomolecular Chemistry, 2014, 12(32), 6128-6133

合成路线：1 步

_85%