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89743-52-2 (N-BOC-2-(甲基丙烯酰氧基)乙胺,2-((tert-Butoxycarbonyl)amino)ethyl methacrylate)

结构式：

N-BOC-2-(甲基丙烯酰氧基)乙胺结构式图片|89743-52-2结构式图片

N-BOC-2-(甲基丙烯酰氧基)乙胺MOL文件

CAS号：

89743-52-2

中文名称：

N-BOC-2-(甲基丙烯酰氧基)乙胺

英文名称：

2-((tert-Butoxycarbonyl)amino)ethyl methacrylate

分子式：

C₁₁H₁₉NO₄

分子量：

229.27286362648

相关分类：

溶剂及有机化学品 > 有机化合物 > Organic acids and derivatives > Carboxylic acids and derivatives > Amino acids, peptides, and analogues > Amino acids and derivatives

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)名称与标识符

名称

中文别名：

2-((叔丁氧基羰基)氨基)乙基甲基丙烯酸酯;(2-BOC-氨基)甲基丙烯酸乙酯;N-BOC-2-(甲基丙烯酰氧基)乙胺;2-((叔丁氧基羰基)氨基)甲基丙烯酸乙酯;甲基丙烯酸(2-BOC-氨基)乙酯;

英文别名：

2-((tert-Butoxycarbonyl)amino)ethyl methacrylate;(2-Boc-amino)ethyl methacrylate;2-[(2-methylpropan-2-yl)oxycarbonylamino]ethyl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-,2-[[(1,1-dimethylethoxy)carbonyl]amino]ethyl ester;2-[[(1,1-Dimethylethoxy)carbonyl]amino]ethyl 2-methyl-2-propenoate (ACI);2-(N-tert-Butoxycarbonylamino)ethyl methacrylate;2-(tert-Butoxycarbonylamino)ethyl methacrylate;2-[[(tert-Butoxy)carbonyl]amino]ethyl 2-methylprop-2-enoate;Boc-AEMA;2-Methyl-2-propenoic acid 2-[[(1,1-dimethylethoxy)carbonyl]amino]ethyl ester;BOC protected aminoethyl methacrylate;(2-Boc-amino)ethyl methacrylate 99% (GC);2-Propenoic acid, 2-methyl-, 2-[[(1,1-dimethylethoxy)carbonyl]amino]ethyl ester;

标识符

MDL：

MFCD23140962

InChIKey：

HZWCSJMONGVKJV-UHFFFAOYSA-N

Inchi：

1S/C11H19NO4/c1-8(2)9(13)15-7-6-12-10(14)16-11(3,4)5/h1,6-7H2,2-5H3,(H,12,14)

SMILES：

C(OCCNC(OC(C)(C)C)=O)(=O)C(C)=C

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)物化性质

实验特性

沸点 : 330.4±25.0 °C(Predicted)
熔点 : 78-84°C
酸度系数(pKa) : 11.77±0.46(Predicted)
密度 : 1.038±0.06 g/cm3(Predicted)

计算特性

氢键供体数量 : 1
氢键受体数量 : 5
可旋转化学键数量 : 8
重原子数量 : 16

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)安全信息

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)推荐厂家更多厂家(14)

公司名称	手机号/电话	联系人	QQ	微信	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982		询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220		询单
北京百灵威科技有限公司	18210857532	翟先生	3650742139		询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364		询单
上海一基实业有限公司	13311756131 021-60548336 QQ：2355265332 QQ:2851717387	胡经理	2355265332		询单
上海一基实业有限公司	13311756052 021-60526763 13311756052 13311756131	胡经理	2355265332		询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136		询单
赫澎（上海）生物科技有限公司	13122891558 186-16545970	张硕	3418426269		询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232		询单
上海颖心实验室设备有限公司	17002132182 021-59178156	墨航琪	3146474380		询单

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)合成路线

合成路线：1 步

_80%

反应条件：

1.1 Reagents: Diisopropylethylamine Solvents: Dichloromethane ; 30 min, 0 °C; 0 °C → 25 °C; 24 h, 25 °C

参考文献：

Design and synthesis of a star-like polymeric micelle modified with AS1411 aptamer for targeted delivery of camptothecin for cancer therapy

Jabbari, Atena; Yaghoobi, Elnaz; Azizollahi, Hamid; Shojaee, Saeed; Ramezani, Mohammad; et al, International Journal of Pharmaceutics (Amsterdam, 2022, 611,

合成路线：1 步

_77%

反应条件：

1.1 Reagents: Diisopropylethylamine Solvents: Dichloromethane ; -78 °C; -78 °C → rt; overnight, rt

参考文献：

Amphiphilic Polymethacrylate Derivatives as Antimicrobial Agents

Kuroda, Kenichi; DeGrado, William F., Journal of the American Chemical Society, 2005, 127(12), 4128-4129

合成路线：1 步

_75%

反应条件：

1.1 Reagents: Sodium bicarbonate Solvents: Tetrahydrofuran , Water ; overnight, 25 °C

参考文献：

Nonionic star polymers with upper critical solution temperature in aqueous solutions

Aliakseyeu, Aliaksei; Hlushko, Raman; Sukhishvili, Svetlana A., Polymer Chemistry, 2022, 13(18), 2637-2650

合成路线：1 步

_75%

参考文献：

The study of relationships between pKa value and siRNA delivery efficiency based on tri-block copolymers

Du, Lili; Wang, Changrong; Meng, Lingwei; Cheng, Qiang; Zhou, Junhui; et al, Biomaterials, 2018, 176, 84-93

合成路线：1 步

_72%

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Tetrahydrofuran ; rt; overnight, rt
1.2 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; overnight, 0 °C

参考文献：

Cationic Spacer Arm Design Strategy for Control of Antimicrobial Activity and Conformation of Amphiphilic Methacrylate Random Copolymers

Palermo, Edmund F.; Vemparala, Satyavani; Kuroda, Kenichi, Biomacromolecules, 2012, 13(5), 1632-1641

合成路线：1 步

_70%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; overnight, rt

参考文献：

Cationic Methacrylate Polymers as Topical Antimicrobial Agents against Staphylococcus aureus Nasal Colonization

Thoma, Laura M.; Boles, Blaise R.; Kuroda, Kenichi, Biomacromolecules, 2014, 15(8), 2933-2943

合成路线：1 步

_65%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; cooled; rt

参考文献：

Multiamino polymeric capping of fluorescent silver nanodots as an effective protective, amphiphilic and pH/thermo-responsive coating

Garcia-Bosch, N.; Liras, M.; Quijada-Garrido, I.; Garcia, O., RSC Advances, 2016, 6(72), 67643-67650

合成路线：1 步

_60%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; 1 h, 0 °C; 12 h, rt

参考文献：

Mixed-Charged Zwitterionic Polymeric Micelles for Tumor Acidic Environment Responsive Intracellular Drug Delivery

Qin, Zhihui; Chen, Tingting; Teng, Wenzhuo; Jin, Qiao ; Ji, Jian, Langmuir, 2019, 35(5), 1242-1248

N-BOC-2-(甲基丙烯酰氧基)乙胺(89743-52-2)相关文献

1. Folic acid targeted pH-responsive amphiphilic polymer nanoparticles conjugated with near infrared fluorescence probe for imaging-guided drug delivery
Liyi Fu,Le Liu,Zheng Ruan,Houbing Zhang,Lifeng Yan RSC Adv. 2016 6 40312
2. Combining the incompatible: Block copolymers consecutively displaying activated esters and amines and their use as protein-repellent surface modifiers with multivalent biorecognition
Daniel Hoenders,Thomas Tigges,Andreas Walther Polym. Chem. 2015 6 476
3. Multiamino polymeric capping of fluorescent silver nanodots as an effective protective, amphiphilic and pH/thermo-responsive coating
N. García-Bosch,M. Liras,I. Quijada-Garrido,O. García RSC Adv. 2016 6 67643
4. Nonionic star polymers with upper critical solution temperature in aqueous solutions
Aliaksei Aliakseyeu,Raman Hlushko,Svetlana A. Sukhishvili Polym. Chem. 2022 13 2637
5. PPEGMEMA-based cationic copolymers designed for layer-by-layer assembly
Tao Jiang,Saeed Zajforoushan Moghaddam,Esben Thormann RSC Adv. 2019 9 26915
6. Covalent immobilization of gold nanoparticles on a plastic substrate and subsequent immobilization of biomolecules
Mimari Matsumoto,Kazuki Kaneko,Manami Hara,Masaki Matsui,Kenta Morita,Tatsuo Maruyama RSC Adv. 2021 11 23409

目录

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960化工网为您提供N-BOC-2-(甲基丙烯酰氧基)乙胺专业化合物百科信息，包括中文名，英文名，分子式，分子量，以及该化合物的CasNo.89743-52-2,相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等。 WAP版:89743-52-2 国际站:89743-52-2

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