92152-01-7 (联苯-3,4’-二羧酸,Biphenyl-3,4'-dicarboxylic acid)

快速询单

结构式：

联苯-3,4’-二羧酸MOL文件

CAS号：

92152-01-7

中文名称：

联苯-3,4’-二羧酸

英文名称：

Biphenyl-3,4'-dicarboxylic acid

分子式：

C₁₄H₁₀O₄

分子量：

242.226804256439

联苯-3,4’-二羧酸(92152-01-7)名称与标识符

名称

中文别名：

4-(3-羧基联苯)苯甲酸;联苯-3,4’-二羧酸;

英文别名：

[1,1'-Biphenyl]-3,4'-dicarboxylic acid;3-(4-carboxyphenyl)benzoic acid;4-(3-CARBOXYPHENYL)BENZOIC ACID;BIPHENYL-3,4-DICARBOXYLIC ACID;3.4'-H2bpdc;Biphenyl-3,4'-dicarbonsaeure;BIPHENYL-3,4'-DICARBOXYLIC ACID;Diphenyl-dicarbonsaeure-(3.4');H2(3,4'-BPDC);3,4′-Biphenyldicarboxylic acid (7CI);3,4′-Bibenzoic acid;3,4′-Dicarboxybiphenyl;

标识符

MDL：

MFCD00728324

InChIKey：

GSYIVQLTSZFJRV-UHFFFAOYSA-N

Inchi：

1S/C14H10O4/c15-13(16)10-6-4-9(5-7-10)11-2-1-3-12(8-11)14(17)18/h1-8H,(H,15,16)(H,17,18)

SMILES：

O=C(C1C=CC(C2C=C(C(O)=O)C=CC=2)=CC=1)O

联苯-3,4’-二羧酸(92152-01-7)物化性质

实验特性

LogP : 2.75000
PSA : 74.60000

计算特性

精确分子量 : 242.05800

联苯-3,4’-二羧酸(92152-01-7)海关数据

海关编码：

2917399090

海关数据：

中国海关编码：

2917399090

概述：

2917399090 其他芳香多元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分

Summary：

2917399090 aromatic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

联苯-3,4’-二羧酸(92152-01-7)推荐厂家更多厂家(20)

公司名称	手机号/电话	联系人	QQ	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
郑州阿尔法化工有限公司	15324716602 0371-55013243	刘经理	2853979810	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
上海绩祥生物科技有限公司	18605105771	李经理	1799924424	询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136	询单
广东元丰化学试剂有限公司	13380732450 0751-2829979	元丰化学小郑	3828157387	询单
深圳市瑞吉特生物科技有限公司	15813841136 0755-89459231	钦先生	1029374309	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单

联苯-3,4’-二羧酸(92152-01-7)合成路线

合成路线：1 步

25487-66-5

74-11-3

_99%

92152-01-7

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Palladium diacetate , [1,1′-Biphenyl]-3-sulfonic acid, 2′-(dicyclohexylphosphino)-2,6-dimethoxy-, sodi… Solvents: Water ; 8 h, 50 °C

参考文献：

Transition-metal-catalyzed carbon-nitrogen and carbon-carbon bond-forming reactions

, World Intellectual Property Organization, , ,

合成路线：1 步

25487-66-5

74-11-3

_99%

92152-01-7

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Palladium diacetate , [1,1′-Biphenyl]-3-sulfonic acid, 2′-(dicyclohexylphosphino)-2,6-dimethoxy-, sodi… Solvents: Water ; 2 - 8 h, 50 °C

参考文献：

General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water

Anderson, Kevin W.; Buchwald, Stephen L., Angewandte Chemie, 2005, 44(38), 6173-6177

合成路线：1 步

55676-76-1

_97%

92152-01-7

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Tetrahydrofuran , Water ; 24 h, reflux

参考文献：

Synthesis and characterization of a nematic fully aromatic polyester based on biphenyl 3,4'-dicarboxylic acid

Heifferon, Katherine V.; Spiering, Glenn A.; Talley, Samantha J.; Hegde, Maruti; Moore, Robert B.; et al, Polymer Chemistry, 2019, 10(31), 4287-4296

合成路线：1 步

14047-29-1

585-76-2

_95%

92152-01-7

反应条件：

1.1 Reagents: Sodium carbonate Catalysts: Tetrabutylammonium bromide , Tetrakis(triphenylphosphine)palladium Solvents: Ethanol , Toluene , Water ; 15 h, reflux; reflux → rt
1.2 Reagents: Hydrogen peroxide Solvents: Water ; 1 h, rt

参考文献：

A green, one-pot route to the biphenyldicarboxylic acids: useful intermediates in polymer synthesis

Clary, Richard S.; Lee, Christopher D.; Monroe, William G.; Vaughn, David A.; Ragheb, Ragy T.; et al, International Journal of Organic Chemistry, 2013, 3(2), 143-147

合成路线：1 步

1201925-74-7

_90%

92152-01-7

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Methanol , Tetrahydrofuran , Water ; overnight, rt

参考文献：

Metal-Organic Hendecahedra Assembled from Dinuclear Paddlewheel Nodes and Mixtures of Ditopic Linkers with 120° and 90° Bend Angles

Li, Jian-Rong; Zhou, Hong-Cai, Angewandte Chemie, 2009, 48(45), 8465-8468

合成路线：1 步

7383-90-6

_86%

92152-01-7

反应条件：

1.1 Reagents: Oxygen Catalysts: Manganese , Cobalt , Bromine Solvents: Acetic acid , Water ; 1 h, 500 psi, 170 °C

参考文献：

Preparation process and use of biphenyldicarboxylic acids

, World Intellectual Property Organization, , ,

合成路线：1 步

618-51-9

14047-29-1

_80%

92152-01-7

反应条件：

1.1 Reagents: Sodium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: Water
1.2 Reagents: Sodium carbonate Solvents: Water ; 1.5 h, reflux
1.3 Reagents: Hydrochloric acid Solvents: Water

参考文献：

Suzuki cross-coupling reactions using reverse-phase glass beads in aqueous media

Lawson Daku, Kokovi M.; Newton, Roger F.; Pearce, Simon P.; Vile, Julia; Williams, Jonathan M. J., Tetrahedron Letters, 2003, 44(27), 5095-5098

合成路线：1 步

14047-29-1

585-76-2

_75%

92152-01-7

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: Methyl ether , Water ; 1 d, 80 °C; 80 °C → rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; acidified
1.3 Reagents: Methanol
1.4 Reagents: Sodium hydroxide Solvents: Water ; reflux
1.5 Reagents: Hydrochloric acid Solvents: Water ; acidified

参考文献：

Supramolecular Isomerism of Metal-Organic Frameworks Derived from a Bicarboxylate Linker with Two Distinct Binding Motifs

Feng, Lu; Chen, Zhenxia; Liao, Tengbiao; Li, Peng; Jia, Yu; et al, Crystal Growth & Design, 2009, 9(3), 1505-1510

合成路线：1 步

55676-76-1

92152-01-7

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Tetrahydrofuran , Water ; 24 h, reflux

参考文献：

Liquid crystalline polyester compositions and methods

, United States, , ,

合成路线：1 步

92152-01-7

参考文献：

Formation of cyclopent[a]indene and acenaphthylene from allyl esters of biphenylmono- and dicarboxylic acids and from biphenyldicarboxylic anhydrides on flash vacuum pyrolysis at 1000-1100°C

Bapat, Jayant B.; Brown, Roger F. C.; Bulmer, Glenn H.; Childs, Trevor; Coulston, Karen J.; et al, Australian Journal of Chemistry, 1997, 50(12), 1159-1182

合成路线：1 步

92152-01-7

参考文献：

Method of producing naphthalenedicarboxylic acids and bis[benzoic acids]

, European Patent Organization, , ,

合成路线：1 步

反应条件：

1.1 Catalysts: Cobalt diacetate Solvents: Acetic acid ; 2 h, 500 psi, 130 °C

参考文献：

A process for selective aerobic oxidation of dimethylbiphenyl derivatives

, United States, , ,

联苯-3,4’-二羧酸(92152-01-7) MSDS

基础信息

Material Safety Data Sheet

Section 1. Identi?cation of the substance
Product Name: Biphenyl-3,4’-dicarboxylic acid
Synonyms:

Section 2. Hazards identi?cation
Harmful by inhalation, in contact with skin, and if swallowed.

Section 3. Composition/information on ingredients.
Ingredient name: Biphenyl-3,4’-dicarboxylic acid
CAS number: 92152-01-7

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
    ?ushing of the eyes by separating the eyelids with ?ngers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section 5. Fire ?ghting measures
    In the event of a ?re involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator
    Hand precaution:        Wear suitable gloves/gauntlets
    Skin protection:        Wear suitable protective clothing
    Eye protection:        Wear suitable eye protection
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly quali?ed
    in the handling and use of potentially hazardous chemicals, who should take into account the ?re,
    health and chemical hazard data given on this sheet.
    Store in closed vessels.
    Storage:

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not speci?ed
    Boiling point:        No data
    No data
    Melting point:
    Flash point:        No data
    Density:        No data
    Molecular formula:        C14H10O4
    Molecular weight:        242.2

Section 10. Stability and reactivity
    Conditions to avoid: Heat, ?ames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide.

Section 11. Toxicological information
No data.

Section 12. Ecological information
No data.

Section 13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.

SECTION 16 - ADDITIONAL INFORMATION
N/A