926-02-3 (叔丁基乙烯基醚,tert-Butyl vinyl ether -)

CAS号:
926-02-3
中文名称:
叔丁基乙烯基醚
英文名称:
tert-Butyl vinyl ether -
分子式:
C6H12O
分子量:
100.158882141113

叔丁基乙烯基醚(926-02-3)名称与标识符

名称

中文别名:
叔丁基乙烯基醚;叔丁基乙烯醚;乙烯基叔丁醚;
英文别名:
Tert-Butyl Vinyl Ether;2-ethenoxy-2-methylpropane;TERT-BUTYL VINYL ETHERL;2-(Ethenyloxy)-2-methylpropane (ACI);Ether, tert-butyl vinyl (6CI, 7CI, 8CI);2-Methyl-2-(vinyloxy)propane;t-Butyl vinyl ether;tert-Butoxyethene;tert-Butoxyethylene;TERT-BUTYLVINYLETHER;Q29448631;NS00039473;tertiary butyl vinyl ether;926-02-3;2-Methyl-2-vinyloxy-propane;C6H12O;DB-008718;EN300-117591;vinyl tertiary-butyl ether;AS-31067;MFCD00048246;tert-Butyl vinyl ether, 98%;DTXSID0061290;AKOS009156422;tertiarybutyl vinyl ether;SCHEMBL49310;Vinyltertiary-butylether;tert-butylvinyl ether;2-(Ethenyloxy)-2-methylpropane;Propane, 2-(ethenyloxy)-2-methyl-;

标识符

MDL:
MFCD00048246
InChIKey:
PGYJSURPYAAOMM-UHFFFAOYSA-N
Inchi:
1S/C6H12O/c1-5-7-6(2,3)4/h5H,1H2,2-4H3
SMILES:
O(C(C)(C)C)C=C

叔丁基乙烯基醚(926-02-3)物化性质

实验特性

  • LogP : 1.94500
  • PSA : 9.23000
  • 折射率 : 1.398
  • 水溶性 : Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
  • 沸点 : 75-76 ºC
  • 熔点 : -112°C
  • 闪点 : -17 ºC
  • 颜色与性状 : 浅黄色或无色透明液体
  • 稳定性 : Stable. Highly flammable. Incompatible with strong oxidizing agents. May be prone to the formation of peroxides when stored in contact with air.
  • 溶解性 : 微溶于水
  • 密度 : 0.762

计算特性

  • 精确分子量 : 100.08900
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 2
  • 同位素质量 : 100.089
  • 重原子数量 : 7
  • 复杂度 : 59.1
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 1.8
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 9.2A^2

叔丁基乙烯基醚(926-02-3)安全信息

叔丁基乙烯基醚(926-02-3)海关数据

海关编码:
2909199090
海关数据:

中国海关编码:

2909199090

概述:

2909199090. 其他无环醚及其卤化衍生物(包括磺化,硝化或亚硝化衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

叔丁基乙烯基醚(926-02-3)推荐厂家 更多厂家(71)

叔丁基乙烯基醚(926-02-3)合成路线

合成路线:1 步
反应条件:
参考文献:
Procedure for the production of tertiary-alkyl alkenyl ethers by the etherification of tertiary alkanols with alkynes in the presence of alkali metal bases
, Germany, , ,
合成路线:1 步
反应条件:
参考文献:
Process and catalysts for the preparation of alkenyl ethers by the addition reaction of alkynes with alcohols
, Germany, , ,
合成路线:1 步
反应条件:
参考文献:
Chemistry of acetylenic ethers. LII. Acetylenic tert-butyl ethers and other acetylenic ethers with branched alkyl groups. The preparation and pyrolysis of acetylenic ethers
van Daalen, J. J.; Kraak, A.; Arens, J. F., Recueil des Travaux Chimiques des Pays-Bas, 1961, 80, 810-18
合成路线:1 步
反应条件:
参考文献:
Synthesis of Allyl and Alkyl Vinyl Ethers Using an in Situ Prepared Air-Stable Palladium Catalyst. Efficient Transfer Vinylation of Primary, Secondary, and Tertiary Alcohols
Bosch, Martin; Schlaf, Marcel, Journal of Organic Chemistry, 2003, 68(13), 5225-5227
合成路线:1 步
反应条件:
参考文献:
Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor
Lyons, Thomas W.; Bezier, David; Brookhart, Maurice, Organometallics, 2015, 34(16), 4058-4062
合成路线:1 步
反应条件:
参考文献:
Process for preparation of tert-butyl vinyl ether
, China, , ,
合成路线:1 步
参考文献:
Product subclass 3: enol ethers
Milata, V.; Radl, S.; Voltrova, S., Science of Synthesis, 2008, 32, 589-756
合成路线:1 步
反应条件:
参考文献:
New method of production of vinyl ether by vapor phase intramolecular dehydration of glycol ether over solid catalysts
Shimasaki, Yuuji; Ariyoshi, Kimio; Kambe, Hideyuki; Yano, Hitoshi; Ugamura, Shukichi, Journal of Molecular Catalysis A: Chemical, 2006, 256(1-2), 37-42
合成路线:1 步
反应条件:
参考文献:
Positive photosensitive composition
, European Patent Organization, , ,
合成路线:1 步
反应条件:
参考文献:
Highly Isotactic Poly(vinyl alcohol). 2. Preparation and Characterization of Isotactic Poly(vinyl alcohol)
Ohgi, H.; Sato, T., Macromolecules, 1999, 32(8), 2403-2409
合成路线:1 步
反应条件:
参考文献:
Gas-phase intramolecular dehydration process for the manufacture of alkyl vinyl ethers from glycol ethers and distillation processes for product and unreacted starting material recovery
, European Patent Organization, , ,
合成路线:1 步
参考文献:
Total Synthesis of (+)-Haperforin G
Zhang, Wei; Zhang, Zhenyu; Tang, Jun-Chen; Che, Jin-Teng; Zhang, Hao-Yu; et al, Journal of the American Chemical Society, 2020, 142(46), 19487-19492
合成路线:1 步
参考文献:
An organic thiyl radical catalyst for enantioselective cyclization
Hashimoto, Takuya; Kawamata, Yu; Maruoka, Keiji, Nature Chemistry, 2014, 6(8), 702-705
合成路线:1 步
参考文献:
17O NMR spectra of vinyl ethers
Taskinen, Esko; Hellman, Jaakko, Magnetic Resonance in Chemistry, 1994, 32(6), 353-7
合成路线:1 步
参考文献:
Application of 1-tert-butoxy-3-[(trimethylsilyl)oxy]buta-1,3-diene in the preparation of functionalized β-hydroxycyclohexanone derivatives, including valuable precursors of daunomycinone analogs
Potman, R. P.; Janssen, N. J. M. L.; Scheeren, J. W.; Nivard, R. J. F., Journal of Organic Chemistry, 1984, 49(19), 3628-34
合成路线:1 步
参考文献:
Preparation of vinyl ethers by transetherification in the presence of molecular sieves
Yuki, Heimei; Hatada, Koichi; Nagata, Kazuhiko; Kajiyama, Kenichi, Bulletin of the Chemical Society of Japan, 1969, 42(12), 3546-50

叔丁基乙烯基醚(926-02-3)相关文献

叔丁基乙烯基醚(926-02-3) MSDS

基础信息

Name:tert-Butyl vinyl ether stabilized 98% Material Safety Data Sheet
Synonym:
CAS:926-02-3
Section 1 - Chemical Product ? MSDS Name:tert-Butyl vinyl ether stabilized 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
926-02-3tert-Butyl vinyl ether98%unlisted
Hazard Symbols: F
Risk Phrases: 11 52/53

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Highly flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable liquid and vapor.
Containers may explode if exposed to fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

Section 7 - HANDLING and STORAGE
? Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Refrigerator/flammables.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 926-02-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Liquid
Color: colorless to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 105mbar @20 deg C
Viscosity: 0.41 mPa.s @20 deg C
Boiling Point: 78 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 275 deg C ( 527.00 deg F)
Flash Point: -17 deg C ( 1.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.762
Molecular Formula: C6H12O
Molecular Weight: 100.16

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 926-02-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl vinyl ether - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
? Ecotoxicity:
Daphnia: Daphnia: TLm = 15 ppm; 48h; .

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: ETHERS, N.O.S.*
Hazard Class: 3
UN Number: 3271
Packing Group: II
IMO
Shipping Name: ETHERS, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing Group: II
RID/ADR
Shipping Name: ETHERS, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing group: II

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 926-02-3: No information available.
Canada
CAS# 926-02-3 is listed on Canada's NDSL List.
CAS# 926-02-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 926-02-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A