927-45-7 (7-十三醇,7-Tridecanol)

_97%

反应条件：

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran ; overnight, 56 °C

参考文献：

Autoresolution of Segregated and Mixed p-n Stacks by Stereoselective Supramolecular Polymerization in Solution

Narayan, Bhawani; Bejagam, Karteek K.; Balasubramanian, Sundaram; George, Subi J., Angewandte Chemie, 2015, 54(44), 13053-13057

合成路线：1 步

_96%

反应条件：

1.1 Reagents: Sodium borohydride Solvents: Methanol ; 10 min, 0 °C; 1 h, rt

参考文献：

A combinatorial library of lipid nanoparticles for RNA delivery to leukocytes

Ramishetti, Srinivas; Hazan-Halevy, Inbal; Palakuri, Ramesh; Chatterjee, Sushmita; Naidu Gonna, Somu; et al, Advanced Materials (Weinheim, 2020, 32(12),

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ; 0 °C; 8 h, reflux; overnight, rt
1.2 Solvents: Water ; rt

参考文献：

An Intramolecular Iodine-Catalyzed C(sp3)-H Oxidation as a Versatile Tool for the Synthesis of Tetrahydrofurans

Koch, Vanessa; Brase, Stefan, European Journal of Organic Chemistry, 2021, 2021(24), 3478-3483

合成路线：1 步

3761-92-0

_94%

反应条件：

1.1 Solvents: Diethyl ether ; reflux; 10 min, reflux
1.2 Reagents: Sulfuric acid , Water Solvents: Water ; reflux

参考文献：

Novel NIR-absorbing conjugated polymers for efficient polymer solar cells: effect of alkyl chain length on device performance

Yue, Wei; Zhao, Yun; Shao, Shuyan; Tian, Hongkun; Xie, Zhiyuan; et al, Journal of Materials Chemistry, 2009, 19(15), 2199-2206

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ; rt → 0 °C; 0 °C; 30 min, rt; overnight, reflux; reflux → rt

参考文献：

Optical and Photophysical Properties of Indolocarbazole Derivatives

Belletete, Michel; Blouin, Nicolas; Boudreault, Pierre-Luc T.; Leclerc, Mario; Durocher, Gilles, Journal of Physical Chemistry A, 2006, 110(51), 13696-13704

合成路线：1 步

544-10-5

111-71-7

_90%

反应条件：

1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Diethyl ether ; 25 °C

参考文献：

Long-Range Self-Assembly of an Electron-Deficient Hexaazatrinaphthylene with Out-of-Plane Substituents

Chen, Yi-Ru ; Zhang, Yong-Yun; Yeh, Ming-Che; Luo, Ying-Ting; Ong, Chi Wi, ChemPlusChem, 2020, 85(4), 613-618

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Sodium borohydride Solvents: Methanol , Tetrahydrofuran ; 0 °C; 1 h, rt
1.2 Reagents: Ammonium chloride Solvents: Water

参考文献：

Preparation of ionizable cationic lipids for RNA delivery

, World Intellectual Property Organization, , ,

合成路线：1 步

_88%

反应条件：

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran ; rt; overnight, rt
1.2 Reagents: Ammonium chloride Solvents: Methanol , Water ; rt

参考文献：

Synthesis and characterization of novel low-bandgap triphenylamine-based conjugated polymers with main-chain donors and pendent acceptors for organic photovoltaics

Sahu, Duryodhan; Padhy, Harihara; Patra, Dhananjaya; Huang, Jen-hsien; Chu, Chih-wei; et al, Journal of Polymer Science, 2010, 48(24), 5812-5823

合成路线：1 步

3761-92-0

_88%

反应条件：

1.1 Solvents: Tetrahydrofuran ; -78 °C; overnight, rt
1.2 Reagents: Methanol , Ammonium chloride Solvents: Water ; rt

参考文献：

Synthesis and applications of 2,7-carbazole-based conjugated main-chain copolymers containing electron deficient bithiazole units for organic solar cells

Patra, Dhananjaya; Sahu, Duryodhan; Padhy, Harihara; Kekuda, Dhananjay; Chu, Chih-Wei; et al, Journal of Polymer Science, 2010, 48(23), 5479-5489

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran
1.2 -

参考文献：

Cation Effect on the Binary and Ternary Phase Behaviors of Double-Tailed Methanesulfonate Amphiphiles

Ontiveros, Jesus F. ; Hong, Bing; Aramaki, Kenji; Pierlot, Christel; Aubry, Jean-Marie; et al, Journal of Surfactants and Detergents, 2021, 24(3), 401-410

合成路线：1 步

_82%

反应条件：

1.1 Reagents: Sodium borohydride Solvents: Isopropanol , Water ; 9 h, rt

参考文献：

Derivatives of tridecan-X-ones (X = 2-7): Synthesis and spectral data

Gibka, Julia; Glinski, Marek, Zeszyty Naukowe - Politechnika Lodzka, 2004, 68, 23-31

合成路线：1 步

3761-92-0

_74%

反应条件：

1.1 Solvents: Tetrahydrofuran ; 25 °C; 0 °C; 15 h, rt
1.2 Reagents: Ammonium chloride Solvents: Water ; rt

参考文献：

Preparation of ionizable cationic lipids for RNA delivery

, World Intellectual Property Organization, , ,

合成路线：1 步

_43%

反应条件：

1.1 Reagents: Phenylsilane , Oxygen Catalysts: (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)manganese Solvents: Isopropanol , 1,2-Dichloroethane

参考文献：

Ionic and organometallic-catalyzed organosilane reductions

Larson, Gerald L.; Fry, James L., Organic Reactions (Hoboken, 2008, 71, 1-737

合成路线：1 步

_43%

反应条件：

1.1 Reagents: Phenylsilane , Oxygen Catalysts: (OC-6-11)-Tris(2,2,6,6-tetramethyl-3,5-heptanedionato-κO3,κO5)manganese Solvents: Isopropanol , Dichloromethane

参考文献：

Acceleration of the reduction of aldehydes and ketones using Mn(dpm)3 catalyst and phenylsilane in the presence of dioxygen

Magnus, P.; Fielding, M. R., Tetrahedron Letters, 2001, 42(38), 6633-6636

合成路线：1 步

反应条件：

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran ; 1 h, -10 °C
1.2 Solvents: Tetrahydrofuran ; < 10 °C; 6 h, 10 °C → rt
1.3 Reagents: Ammonium chloride Solvents: Water ; rt
1.4 Reagents: Hydrochloric acid Solvents: Water ; acidified, rt

参考文献：

Coupled Metabolic Cycles Allow Out-of-Equilibrium Autopoietic Vesicle Replication

Engwerda, Anthonius H. J. ; Southworth, Josh; Lebedeva, Maria A.; Scanes, Robert J. H.; Kukura, Philipp; et al, Angewandte Chemie, 2020, 59(46), 20361-20366

合成路线：1 步

反应条件：

1.1 Reagents: Lithium aluminum hydride Solvents: Diethyl ether

参考文献：

Stabilization of long-chain intermediates in solution. Tridecyl radicals and cations

Teodorovic, Aleksandar V.; Badjuk, Dalibor M.; Stevanovic, Nenad; Pavlovic, Radoslav Z., Journal of Molecular Structure, 2015, 1083, 357-363

合成路线：1 步

反应条件：

1.1 Reagents: Sodium borohydride Solvents: Isopropanol

参考文献：

Synthesis and odor characteristics of isomeric aliphatic tridecanones and their derivatives

Gibka, Julia; Gora, Jozef; Wojcicka, Anna, Zeszyty Naukowe - Politechnika Lodzka, 2002, 66, 85-90

合成路线：1 步

反应条件：

1.1 Reagents: Isopropanol Catalysts: Magnesium oxide

参考文献：

Catalytic hydrogen transfer over magnesia, XV. Preliminary studies of active centers of catalysts

Glinski, Marek, Reaction Kinetics and Catalysis Letters, 2001, 72(1), 133-137

合成路线：1 步

75-09-2

30038-49-4