931-59-9 (苯硫氯,Phenylsulfenyl Chloride)

_100%

反应条件：

1.1 Reagents: Hydrochloric acid , Sodium hypochlorite Solvents: Dichloromethane ; 30 min, 0 °C; 30 min, 0 °C

参考文献：

Safe and practical ex-situ chlorination of electronically diverse π-systems

Aguilar, Glen C.; Lis, Patrycja A. ; Wise, Dan E. ; Martinez, Jenny S.; Parasram, Marvin, Tetrahedron Letters, 2023, 124,

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Chlorosuccinimide Solvents: Dichloromethane ; 0 °C; 15 min, 0 °C

参考文献：

Bifunctional Polyene Cyclizations: Synthetic Studies on Pimarane Natural Products

Feilner, Julian M. ; Plangger, Immanuel ; Wurst, Klaus; Magauer, Thomas, Chemistry - A European Journal, 2021, 27(48), 12410-12421

合成路线：1 步

1666-13-3

_100%

反应条件：

1.1 Reagents: Sulfuryl chloride

参考文献：

Benzenesulfenyl chloride

Zelcans, Gunars; Hutton, Thomas K.; Rios, Ramon; Shibata, Norio, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2013, 1, 1-14

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Chlorine Solvents: Pentane ; 1 h, rt

参考文献：

The Endocyclic Restriction Test: The Geometries of Nucleophilic Substitutions at Sulfur(VI) and Sulfur(II)

Jarboe, Stephen G.; Terrazas, Michael S.; Beak, Peter, Journal of Organic Chemistry, 2008, 73(24), 9627-9632

合成路线：1 步

62167-00-4

_96%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Dichloromethane

参考文献：

Synthesis of [1c-13C]-Labelled Gangliosides GM3 and NMR-Spectroscopic Investigations in Cell Cultures

Gretzke, Dirk, 1998, , ,

合成路线：1 步

_96%

参考文献：

Concerning the mechanism of the formation of phosphoranes from the reaction of tricoordinated phosphorus compounds and alkyl benzenesulfenates

Denney, Donald B.; Denney, Dorothy Z.; Gavrilovic, Dragan M., Phosphorus and Sulfur and the Related Elements, 1981, 11(1), 1-9

合成路线：1 步

56-23-5

_96%

反应条件：

1.1 Reagents: Chlorine

参考文献：

Electrophilic additions to strained alkenes. II. The reaction of benzeneselenenyl chloride with tricyclo[4.2.2.02,5]deca-3,7-diene derivatives

Garratt, Dennis G.; Ryan, M. Dominic; Kabo, Ann, Canadian Journal of Chemistry, 1980, 58(22), 2329-39

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Iodobenzene dichloride Solvents: Dichloromethane ; 20 min, rt

参考文献：

Method for synthesizing aryl sulfenyl/selenenyl chloride

, China, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Chlorosuccinimide Solvents: Dichloromethane ; 0 °C; 15 min, 0 °C

参考文献：

Palladium-Catalyzed Regio- and Stereoselective Chlorothiolation of Terminal Alkynes with Sulfenyl Chlorides

Iwasaki, Masayuki; Fujii, Tomoya; Yamamoto, Arisa; Nakajima, Kiyohiko; Nishihara, Yasushi, Chemistry - An Asian Journal, 2014, 9(1), 58-62

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Dichloromethane ; 0 °C; 1 h, 0 °C

参考文献：

Synthesis and biological evaluation of nonsymmetrical aromatic disulfides as novel inhibitors of acetohydroxyacid synthase

Li, Zai-Shun; Wang, Wei-Min; Lu, Wei; Niu, Cong-Wei; Li, Yong-Hong; et al, Bioorganic & Medicinal Chemistry Letters, 2013, 23(13), 3723-3727

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Dichloromethane ; cooled; 1 h, cooled

参考文献：

Triazole-asymmetric disulfide compounds as herbicides and their preparation, agrochemical compositions and use in the control of weeds

, China, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Dichloromethane ; 0 °C; 1 h, 0 °C

参考文献：

Preparation of heterocyclic ring-containing asymmetric aromatic sulfide compound as AHAS inhibitors useful as herbicides

, China, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Dichloromethane ; 0 °C; 1 h, 0 °C

参考文献：

Synthesis, Crystal Structure, in Vitro Acetohydroxyacid Synthase Inhibition, in Vivo Herbicidal Activity, and 3D-QSAR of New Asymmetric Aryl Disulfides

Shang, Jun; Wang, Wei-Min; Li, Yong-Hong; Song, Hai-Bin; Li, Zheng-Ming; et al, Journal of Agricultural and Food Chemistry, 2012, 60(34), 8286-8293

合成路线：1 步

_92%

反应条件：

1.1 Reagents: Chlorosuccinimide Solvents: Dichloromethane ; 0 °C; 15 min, 0 °C

参考文献：

In Situ Activation of Disulfides for Multicomponent Reactions with Isocyanides and a Broad Range of Nucleophiles

Lei, Xiaofang; Wang, Yuanyuan; Fan, Erkang; Sun, Zhihua, Organic Letters, 2019, 21(5), 1484-1487

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Chlorine

参考文献：

Studies of aromatic disulfides. VII. Synthesis of asymmetric aromatic and aliphatic-aromatic disulfides

Stepanov, B. I.; Rodionov, V. Ya.; Chibisova, T. A.; Yagodina, L. A.; Stankevich, A. D., Zhurnal Organicheskoi Khimii, 1977, 13(2), 370-4

合成路线：1 步

_89%

反应条件：

1.1 Reagents: Triethylamine Solvents: Benzene ; 15 min, 0 °C
1.2 Reagents: Sulfuryl chloride Solvents: Dichloromethane ; 0 °C

参考文献：

Synthesis and deployment of an elusive fluorovinyl cation equivalent: Access to quaternary α-(1'-fluoro)vinyl amino acids as potential PLP enzyme inactivators

McCune, Christopher D.; Beio, Matthew L.; Sturdivant, Jill M.; de la Salud-Bea, Roberto; Darnell, Brendan M.; et al, Journal of the American Chemical Society, 2017, 139(40), 14077-14089

合成路线：1 步

_89%

反应条件：

1.1 Reagents: Chlorine

参考文献：

Cyclofunctionalization of 2-allylphenols with sulfur chlorides. III. 2-(Arylthiomethyl)-2,3-dihydrofuro[3,2-h]quinolines from 7-allyl- and 7-methallyl-8-hydroxyquinoline, respectively, and arylsulfenyl chlorides

Meinhold, H.; Muehlstaedt, M.; Muslih, R. M., Journal fuer Praktische Chemie (Leipzig), 1989, 331(1), 136-40

合成路线：1 步

_88%

反应条件：

1.1 Reagents: Sulfuryl chloride Solvents: Pentane ; 0.5 h, 0 °C; 0 °C → rt; 1 h, rt

参考文献：

Catalytic Thia-Sommelet-Hauser Rearrangement: Application to the Synthesis of Oxindoles

Li, Yuye; Shi, Yi; Huang, Zhong-Xing; Wu, Xin-Hu; Xu, Peng-Fei; et al, Organic Letters, 2011, 13(5), 1210-1213

合成路线：1 步

_88%

反应条件：

1.1 Reagents: Chlorine Solvents: Carbon tetrachloride ; 3 h, < 20 °C; 2 - 4 h, rt
1.2 Reagents: Sodium bicarbonate Solvents: Water

参考文献：

Preparation and characterization of o- or p-phenylthio substituted phenol compounds

Feng, Baicheng; Yu, Fanuan; Li, Peipei, Qingdao Keji Daxue Xuebao, 2010, 31(3), 231-233

合成路线：1 步

_88%