934-56-5 (三甲基苯基锡,Trimethylphenyltin)

100-58-3

_100%

反应条件：

1.1 Solvents: Tetrahydrofuran
1.2 Reagents: Ammonium chloride Solvents: Water

参考文献：

Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines

Hayashi, T.; Ishigedani, M., Tetrahedron, 2001, 57(13), 2589-2595

合成路线：1 步

17946-71-3

1089-59-4

_99%

反应条件：

1.1 Solvents: Tetrahydrofuran

参考文献：

Reactions of trialkylstannane anions, R3Sn-, with arylstannanes, ArSnR3

Mochida, Kunio, Bulletin of the Chemical Society of Japan, 1987, 60(9), 3299-306

合成路线：1 步

591-50-4

_96%

反应条件：

1.1 Catalysts: Dibromobis(triphenylphosphine)palladium Solvents: Toluene

参考文献：

The Stille reaction

Farina, Vittorio; Krishnamurthy, Venkat; Scott, William J., Organic Reactions (Hoboken, 1997, 50,

合成路线：1 步

16643-09-7

98-04-4

_89%

反应条件：

1.1 Solvents: Ammonia

参考文献：

Synthesis of Arylstannanes from Arylamines

Chopa, Alicia B.; Lockhart, Maria T.; Silbestri, Gustavo, Organometallics, 2001, 20(15), 3358-3360

合成路线：1 步

2510-86-3

_85%

反应条件：

1.1 Reagents: Sodium Solvents: Ammonia
1.2 -

参考文献：

Phenols as Starting Materials for the Synthesis of Arylstannanes via SRN1

Chopa, Alicia B.; Lockhart, Maria T.; Dorn, Viviana B., Organometallics, 2002, 21(7), 1425-1429

合成路线：1 步

100-58-3

_84%

反应条件：

1.1 Solvents: Diethyl ether ; overnight, reflux

参考文献：

Synthesis of Thiophene 1,1-Dioxides and Tuning Their Optoelectronic Properties

Tsai, Chia-Hua; Chirdon, Danielle N.; Maurer, Andrew B.; Bernhard, Stefan; Noonan, Kevin J. T., Organic Letters, 2013, 15(20), 5230-5233

合成路线：1 步

23265-32-9

_83%

反应条件：

1.1 Solvents: Acetonitrile ; rt

参考文献：

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

Lian, Chang; Yue, Guanglu; Mao, Jinshan; Liu, Danyang; Ding, Yi; et al, Organic Letters, 2019, 21(13), 5187-5191

合成路线：1 步

36719-40-1

_80%

反应条件：

1.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ; rt; 30 min, rt

参考文献：

Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature

Mao, Shuai ; Chen, Zhengkai ; Wang, Lu; Khadka, Daulat Bikram; Xin, Minhang ; et al, Journal of Organic Chemistry, 2019, 84(1), 463-471

合成路线：1 步

108-86-1

_78%

反应条件：

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran

参考文献：

Synthesis and spectroscopic characteristics of aryltrimethylsilicon, -germanium, and -tin compounds

Moerlein, S. M., Journal of Organometallic Chemistry, 1987, 319(1), 29-39

合成路线：1 步

108-86-1

_77%

反应条件：

1.1 Reagents: Butyllithium Solvents: Diethyl ether , Hexane
1.2 Solvents: Tetrahydrofuran

参考文献：

Phenyl-substituted 2,2':6',2''-terpyridine as a new series of fluorescent compounds-their photophysical properties and fluorescence tuning

Mutai, Toshiki; Cheon, Jin-Dong; Arita, Shinpei; Araki, Koji, Journal of the Chemical Society, 2001, (7), 1045-1050

合成路线：1 步

455-32-3

_70%

反应条件：

1.1 Catalysts: Palladium chloride , 1,1′-(1,4-Butanediyl)bis[1,1-dicyclohexylphosphine] Solvents: o-Xylene ; 10 h, 140 °C

参考文献：

Synthesis of Arylstannanes via Palladium-Catalyzed Decarbonylative Coupling of Aroyl Fluorides

Kayumov, Muzaffar; Zhao, Jian-Nan; Mirzaakhmedov, Sharafitdin; Wang, Dong-Yu; Zhang, Ao, Advanced Synthesis & Catalysis, 2020, 362(4), 776-781

合成路线：1 步

591-50-4

_63%

反应条件：

1.1 Reagents: Diisopropylethylamine Solvents: Acetonitrile ; 1 h, rt

参考文献：

Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

Chen, Kai; He, Pei; Zhang, Shuai; Li, Pengfei, Chemical Communications (Cambridge, 2016, 52(58), 9125-9128

合成路线：1 步

62-53-3

_63%

反应条件：

1.1 Reagents: tert-Butyl nitrite Catalysts: p-Toluenesulfonic acid Solvents: 1,2-Dichloroethane ; 4 h, 0 °C

参考文献：

Synthesis method of aryltin compounds from aromatic amine, distannane and alkyl nitrite

, China, , ,

合成路线：1 步

120086-07-9

_56%

反应条件：

1.1 Catalysts: Bis(1,5-cyclooctadiene)nickel Solvents: Toluene

参考文献：

Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes

Shirakawa, Eiji; Nakao, Yoshiaki; Yoshida, Hiroto; Hiyama, Tamejiro, Journal of the American Chemical Society, 2000, 122(37), 9030-9031

合成路线：1 步

62-53-3

_53%

反应条件：

1.1 Reagents: p-Toluenesulfonic acid , tert-Butyl nitrite Solvents: 1,2-Dichloroethane ; 4 h, 0 °C

参考文献：

Synthesis of aryl trimethylstannanes from aryl amines: a Sandmeyer-type stannylation reaction

Qiu, Di; Meng, He; Jin, Liang; Wang, Shuai; Tang, Shengbo; et al, Angewandte Chemie, 2013, 52(44), 11581-11584

合成路线：1 步

462-06-6

_50%

反应条件：

1.1 Reagents: Sodium Solvents: Hexamethylphosphoramide ; 20 min, rt; 2 - 3 h, rt
1.2 20 min, rt

参考文献：

Reactions of trimethylstannide and trimethylsiliconide anions with aromatic and heteroaromatic substrates

Postigo, Al; Vaillard, Santiago E.; Rossi, Roberto A., Journal of Physical Organic Chemistry, 2002, 15(12), 889-893

合成路线：1 步

873-55-2

_38%

反应条件：

1.1 Reagents: Silver carbonate Catalysts: Bis(tri-tert-butylphosphine)palladium Solvents: Dimethylacetamide ; 1 h, 140 °C

参考文献：

Synthesis of arylstannanes by palladium-catalyzed desulfitative coupling reaction of sodium arylsulfinates with distannanes

Lian, Chang; Yue, Guanglu; Zhang, Haonan; Wei, Liyan; Liu, Danyang; et al, Tetrahedron Letters, 2018, 59(45), 4019-4023

合成路线：1 步

591-51-5

参考文献：

Stille coupling via C-N bond cleavage

Wang, Dong-Yu; Kawahata, Masatoshi; Yang, Ze-Kun; Miyamoto, Kazunori; Komagawa, Shinsuke; et al, Nature Communications, 2016, 7,

合成路线：1 步

108-86-1

反应条件：

1.1 Reagents: Magnesium

参考文献：

A Molecular Tetrapod for Organic Photovoltaics

Yang, Jianzhong; Zhang, Zhen; Qin, Yang, ACS Applied Materials & Interfaces, 2016, 8(34), 22392-22401

合成路线：1 步

25149-64-8

591-51-5