93-53-8 (2-苯基丙醛,2-Phenylpropanal)

_100%

反应条件：

1.1 Reagents: Hydrogen ; 16 h, 1000 psi, 50 °C

参考文献：

Metal supported on dendronized magnetic nanoparticles: highly selective hydroformylation catalysts

Abu-Reziq, Raed; Alper, Howard; Wang, Dashan; Post, Michael L., Journal of the American Chemical Society, 2006, 128(15), 5279-5282

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Rhodium (polymer-supported phosphine chloride complexes) Solvents: Carbon dioxide ; 7.5 h, 241 bar, 50 °C

参考文献：

Hydroformylation of styrene in supercritical carbon dioxide with fluoroacrylate polymer supported rhodium catalysts

Kani, Ibrahim; Flores, Roberto; Fackler, John P.; Akgerman, Aydin, Journal of Supercritical Fluids, 2004, 31(3), 287-294

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Amberlyst 15 Solvents: Ethyl acetate

参考文献：

Reaction of styrene oxide in the presence of ion-exchange resins

Kurata, Takeo; Kobayashi, Nobuyuki, Yukagaku, 1989, 38(1), 82-7

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Carbon (mineral acid-treated) , Nitric acid Solvents: Ethyl acetate

参考文献：

Preparation of phenylacetaldehyde and 1,3-dioxolanes from styrene oxide with mineral acid-treated activated carbon catalyst

Kurata, Takeo; Koshiyama, Takao, Yukagaku, 1987, 36(6), 436-40

合成路线：1 步

109141-70-0

_99%

反应条件：

1.1 Reagents: Water , Oxygen Catalysts: Cupric chloride Solvents: Acetonitrile ; 24 h, 1 atm, 40 °C

参考文献：

Oxidative cleavage of CC bond of 2-phenylpropionaldehyde using molecular oxygen

Tokunaga, Makoto; Aoyama, Hiroshi; Shirogane, Yuki; Obora, Yasushi; Tsuji, Yasushi, Catalysis Today, 2006, 117(1-3), 138-140

合成路线：1 步

21129-06-6

_99%

反应条件：

1.1 Catalysts: 1-Butyl-3-methylimidazolium tetrafluoroborate Solvents: Water , 1-Butyl-3-methylimidazolium tetrafluoroborate ; 3 - 5 h, rt

参考文献：

Mild and efficient conversion of aldehydes to gem-diacetates using 2nd generation ionic liquids

Yadav, J. S.; Reddy, B. V. S.; Sreedhar, P.; Kondaji, G.; Nagaiah, K., Catalysis Communications, 2008, 9(5), 590-593

合成路线：1 步

109141-70-0

_99%

反应条件：

1.1 Reagents: Water Catalysts: Cupric chloride Solvents: Acetonitrile ; 24 h, 40 °C

参考文献：

Copper-catalyzed oxidative cleavage of carbon-carbon double bond of enol ethers with molecular oxygen

Tokunaga, Makoto; Shirogane, Yuki; Aoyama, Hiroshi; Obora, Yasushi; Tsuji, Yasushi, Journal of Organometallic Chemistry, 2005, 690(23), 5378-5382

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Hydrogen , (1R,1′R,3aS,3′aS)-1,1′-(1,2-Phenylene)bis[hexahydro-2-phenyl-1H-pyrrolo[1,2-c][1… Catalysts: Dicarbonylrhodium acetylacetonate Solvents: Toluene

参考文献：

Rhodium-mediated asymmetric hydroformylation with a novel bis(diazaphospholidine) ligand

Breeden, Simon; Cole-Hamilton, David J.; Foster, Douglas F.; Schwarz, Gary J.; Wills, Martin, Angewandte Chemie, 2000, 39(22), 4106-4108

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Glycine, N3,N5-di-L-phenylalanyl-3,5-diaminobenzoyl-, homopolymer (resin-bound, rhodium complexes)

参考文献：

A Divergent, Solid-Phase Approach to Dendritic Ligands on Beads. Heterogeneous Catalysis for Hydroformylation Reactions

Arya, Prabhat; Rao, N. Venugopal; Singkhonrat, Jirada; Alper, Howard; Bourque, S. Christine; et al, Journal of Organic Chemistry, 2000, 65(6), 1881-1885

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Triphenylphosphine , Rhodium, [μ-[bis[(2R)-2-(mercapto-κS:κS)propyl] 1,2-benzenedicarboxylato(2-)]]bi… Solvents: Toluene

参考文献：

Binuclear and polynuclear rhodium complexes containing chiral dithiolate ligands derived from lactic acid

Freixa, Z.; Martin, E.; Gladiali, S.; Bayon, J. C., Applied Organometallic Chemistry, 2000, 14(1), 57-65

合成路线：1 步

1123-85-9

反应条件：

1.1 Catalysts: Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene]hydro[(8-quinolinyl-κN)methyl-κC](t… Solvents: Tetrahydrofuran ; 23 °C; 22 h, 85 °C

参考文献：

An air-stable cationic iridium hydride as a highly active and general catalyst for the isomerization of terminal epoxides

Humbert, Nicolas; Vyas, Devendra J.; Besnard, Celine; Mazet, Clement, Chemical Communications (Cambridge, 2014, 50(73), 10592-10595

合成路线：1 步

_98%

反应条件：

1.1 Catalysts: Pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,1… Solvents: Chloroform-d , Water ; 18 h, 60 °C

参考文献：

Efficient epoxide isomerization within a self-assembled hexameric organic capsule

Caneva, Thomas; Sperni, Laura; Strukul, Giorgio; Scarso, Alessandro, RSC Advances, 2016, 6(87), 83505-83509

合成路线：1 步

1123-85-9

_98%

反应条件：

1.1 Reagents: Hydrogen peroxide Catalysts: 1-Butanaminium, N,N,N-tributyl-, ferratetetracosa-μ-oxoundecaoxo[μ12-[phosphato(… (silica composite) Solvents: Acetonitrile , Water ; 3 h, reflux

参考文献：

Synthesis, characterization and catalytic performance of a Fe polyoxometalate/silica composite in the oxidation of alcohols with hydrogen peroxide

Farsani, Mostafa Riahi; Yadollahi, Bahram, Journal of Molecular Catalysis A: Chemical, 2014, 392, 8-15

合成路线：1 步

_98%

反应条件：

1.1 Solvents: Dichloromethane ; rt → reflux; 2 h, reflux

参考文献：

Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

Robinson, Mathew W. C.; Davies, A. Matthew; Buckle, Richard; Mabbett, Ian; Taylor, Stuart H.; et al, Organic & Biomolecular Chemistry, 2009, 7(12), 2559-2564

合成路线：1 步

50-00-0

_98%

反应条件：

1.1 Reagents: 2,4,6-Tris[4-(diphenylphosphinyl)-3-methylphenyl]-1,3,5-triazine Catalysts: Dirhodium tetraacetate

参考文献：

Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3'-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks

Kostas, Ioannis D.; Andreadaki, Fotini J.; Medlycott, Elaine A.; Hanan, Garry S.; Monflier, Eric, Tetrahedron Letters, 2009, 50(16), 1851-1854

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Dicarbonylrhodium acetylacetonate , [(4S)-4,5-Dihydro-4-(1-methylethyl)-2-oxazolyl]methyl 6-(1,1-dimethylethyl)-2-ph… Solvents: Toluene

参考文献：

Probing new classes of π-acceptor ligands for rhodium catalyzed hydroformylation of styrene

Breit, Bernhard, Journal of Molecular Catalysis A: Chemical, 1999, 143(1-3), 143-154

合成路线：1 步

_97%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](N,N,N′,N′-tetramethyl-1,2-ethanedi… Solvents: Toluene ; 16 h, 1000 psi, 25 °C

参考文献：

Ionic diamine rhodium(i) complexes-highly active catalysts for the hydroformylation of olefins

Kim, Jai Jun; Alper, Howard, Chemical Communications (Cambridge, 2005, (24), 3059-3061

合成路线：1 步

_97%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Dicarbonylrhodium acetylacetonate , Pyridine, 2-[5-[(diphenylphosphinyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-, (4… Solvents: Benzene

参考文献：

Hydroformylation of some functionalized olefins catalyzed by rhodium(I) complexes with pydiphos and its P-oxide

Basoli, C.; Botteghi, C.; Cabras, M. A.; Chelucci, G.; Marchetti, M., Journal of Organometallic Chemistry, 1995, 488(1-2),

合成路线：1 步

_97%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Dicarbonylrhodium acetylacetonate , Phosphinous acid, diphenyl-, bicyclo[2.2.1]heptane-2,5-diyl ester, (endo,endo)- Solvents: Benzene

参考文献：

New ligands with a wide bite angle. Efficient catalytic activity in the Rh(I)-catalyzed hydroformylation of olefins

Yamamoto, Keiji; Momose, Satoru; Funahashi, Masakazu; Ebata, Satoshi; Ohmura, Hideaki; et al, Chemistry Letters, 1994, (2), 189-92

合成路线：1 步

_96%