937-41-7 (丙烯酸苯酯,Phenyl acrylate)

反应条件：

1.1 Reagents: Sodium carbonate , Hantzsch ester Solvents: Dimethyl sulfoxide ; 2.5 h, rt

参考文献：

Hantzsch Ester as a Photosensitizer for the Visible-Light-Induced Debromination of Vicinal Dibromo Compounds

Chen, Wenxin; Tao, Huachen; Huang, Wenhao; Wang, Guoqiang; Li, Shuhua; et al, Chemistry - A European Journal, 2016, 22(28), 9546-9550

合成路线：1 步

_96%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; 0 °C → rt; 12 h, rt

参考文献：

Acid- and Base-Switched Palladium-Catalyzed γ-C(sp3)-H Alkylation and Alkenylation of Neopentylamine

Zhang, Jinquan ; Zhang, Shuaizhong; Zou, Hongbin, Organic Letters, 2021, 23(9), 3466-3471

合成路线：1 步

335223-19-3

_96%

反应条件：

1.1 Catalysts: Cesium carbonate ; 1 h, 25 °C

参考文献：

Preparation of the (meth) acrylate

, Japan, , ,

合成路线：1 步

625-36-5

_96%

反应条件：

1.1 Reagents: Triethylamine , Phosphorus pentoxide Solvents: Toluene

参考文献：

Preparation of acrylate esters

, World Intellectual Property Organization, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 20 min, 0 °C; 2 h, 0 °C

参考文献：

Synthesis of 2-amino-3-[(3-(benzyloxy)-3-oxopropyl)thio]propanoic acid

Jin, Biao; Zhang, Jing-dong; Wang, Si-hong, Huaxue Shiji, 2018, 40(10), 1002-1004

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; rt → 0 °C
1.2 Solvents: Dichloromethane ; 30 min, 0 °C; 0 °C → rt; overnight, rt

参考文献：

Synthesis of α,ω-heterotelechelic PVP for bioconjugation, via a one-pot orthogonal end-group modification procedure

Reader, Paul. W.; Pfukwa, Rueben; Jokonya, Simbarashe; Arnott, Gareth E.; Klumperman, Bert, Polymer Chemistry, 2016, 7(42), 6450-6456

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; 0 °C → rt; overnight, rt

参考文献：

1,4-Diazabicyclo[2.2.2]octane-Promoted Aminotrifluoromethylthiolation of α,β-Unsaturated Carbonyl Compounds: N-Trifluoromethylthio-4-nitrophthalimide Acts as Both the Nitrogen and SCF3 Sources

Xiao, Qing; He, Qijie; Li, Juncheng; Wang, Jun, Organic Letters, 2015, 17(24), 6090-6093

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran ; 20 min, -30 °C; 2 h, -30 °C

参考文献：

Antimicrobial activity of p-hydroxyphenyl acrylate derivatives

Kim, Jung Hee; Park, Eun-Soo; Shim, Jae Hun; Kim, Mal-Nam; Moon, Woong-Sik; et al, Journal of Agricultural and Food Chemistry, 2004, 52(25), 7480-7483

合成路线：1 步

_92%

反应条件：

1.1 Solvents: Pyridine

参考文献：

Preparation of aromatic acrylates by reaction of acryloyl chloride with phenols

Magagnini, Pier L.; Pizzirani, Giovanna, Gazzetta Chimica Italiana, 1966, 96(8-9), 1035-45

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)pyridine Solvents: Dichloromethane ; 6 h, rt
1.2 Reagents: Sodium bicarbonate

参考文献：

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(III) sulphate as the reoxidant

Fernandes, Rodney A.; Yadav, Sandhya S.; Kumar, Praveen, Organic & Biomolecular Chemistry, 2022, 20(2), 427-443

合成路线：1 步

7446-81-3

_87%

反应条件：

1.1 Reagents: (Diethylamino)sulfur trifluoride Catalysts: 4-(Dimethylamino)pyridine Solvents: Acetonitrile ; rt; 24 h, rt

参考文献：

Acylation of phenols to phenolic esters with organic salts

Zhang, Zhanrong; Zhao, Ziwei; Liu, Mingyang; Liu, Huizhen; Li, Qian; et al, Green Chemistry, 2022, 24(24), 9763-9771

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; rt → 0 °C
1.2 0 °C; 1 h, 0 °C; 1 h, rt

参考文献：

Process for preparation of 6-hydroxy-1-indanone

, China, , ,

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Potassium fluoride , 18-Crown-6 Solvents: Dichloromethane ; 4 h, rt

参考文献：

O-Arylation of carboxylic acids using (phenyl)[2-(trimethylsilyl)phenyl]iodonium triflate as a precursor of arynes

Xue, Jian; Huang, Xian, Synthetic Communications, 2007, 37(13), 2179-2185

合成路线：1 步

79-10-7

_80%

反应条件：

1.1 Reagents: Thionyl chloride ; rt; 1 h, heated; 20 min, reflux

参考文献：

Heat-resistant and salt-resistant betaine-type acrylic polymer fluid loss reducer and preparation method

, China, , ,

合成路线：1 步

_80%

反应条件：

1.1 Reagents: Potassium carbonate Solvents: Acetone , Water ; 4 h, 0 °C

参考文献：

Development of n-type semiconductor based on cyclopentene- or cyclohexene-fused [C60]-fullerene derivatives

Yamane, Yu; Sugawara, Kiyotaka; Nakamura, Naoshi; Hayase, Shuichi; Nokami, Toshiki; et al, Journal of Organic Chemistry, 2015, 80(9), 4638-4649

合成路线：1 步

79-10-7

_80%

反应条件：

1.1 Reagents: Thionyl chloride ; rt; 1 h, heated

参考文献：

Synthesis and Micellar Behaviors of an Anionic Polymerizable Surfactant

Ma, Lihua; Guo, Yongjun; Feng, Rusheng; Xiang, Panpan; Li, Chunhui, Journal of the Chinese Chemical Society (Weinheim, 2014, 61(5), 583-588

合成路线：1 步

79-10-7

_78%

反应条件：

1.1 Reagents: Di-tert-butyl dicarbonate Catalysts: Sulfuric acid magnesium salt (1:1) , Lithium bromide ; 24 h, 25 °C

参考文献：

Preparation of carboxylate esters in the presence of dicarbonates, magnesium compounds, and alkali metal compounds

, World Intellectual Property Organization, , ,

合成路线：1 步

_76%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 24 h, rt

参考文献：

Different reaction patterns in the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone, phenyl acrylate and phenyl thioacrylate

Shi, Min; Li, Chao-Qun; Jiang, Jian-Kang, Molecules, 2002, 7(10), 721-733

合成路线：1 步

_75%

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 0 °C; 0 °C → rt; 5 h, rt

参考文献：

Direct Synthesis of Adipic Esters and Adiponitrile via Photoassisted Cobalt-Catalyzed Alkene Hydrodimerization

Ren, Cheng; Ji, Guanghao; Li, Xiankai; Zhang, Jing, Chemistry - A European Journal, 2022, 28(53),

合成路线：1 步

_75%