943836-24-6 (4-(二联苯-4-基氨基)苯硼酸,4-(Dibiphenyl-4-ylamino)phenylboronic acid)

_91%

反应条件：

1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; 3 h, 90 °C; 90 °C → rt
1.2 Reagents: Water

参考文献：

Aromatic amine compounds and mixtures and compositions thereof for preparing organic electroluminescent devices

, China, , ,

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -100 - -80 °C; 1 h, -100 - -80 °C
1.2 Reagents: Tributyl borate ; -100 - -80 °C; 2 h, -100 - -80 °C
1.3 heated

参考文献：

Preparation of (thia)xanthone-containing tert-arylamine-based compounds for organic optoelectronic devices

, China, , ,

合成路线：1 步

_88%

反应条件：

1.1 Reagents: Potassium acetate , Bis(pinacolato)diborane Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Toluene ; rt → 120 °C; 16 h, 120 °C

参考文献：

Compound having triarylamine as core and application thereof

, World Intellectual Property Organization, , ,

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Toluene ; rt; 2.5 h, reflux

参考文献：

Aromatic amine compound containing carbazole group and its organic electroluminescent device

, China, , ,

合成路线：1 步

_83%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 2 h, -78 °C
1.2 Reagents: Triisopropyl borate ; -78 °C; -78 °C → rt; 12 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; pH 6

参考文献：

Diversification of carbazoles by LiCl-mediated catalytic CuI reaction

Cho, Joong Hyun; Ryu, Young-Sil; Oh, Se Hwan; Kwon, Jae Kwan; Yum, Eul Kgun, Bulletin of the Korean Chemical Society, 2011, 32(7), 2461-2464

合成路线：1 步

_81%

反应条件：

1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; rt → 110 °C; 3 h, 110 °C

参考文献：

Organic light-emitting compound, organic light-emitting device and its application

, China, , ,

合成路线：1 步

_81%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 3 h, -78 °C
1.2 Reagents: Triisopropyl borate ; overnight, -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; rt

参考文献：

Preparation of carbazole derivatives as green light host compounds for organic electroluminescence devices

, China, , ,

合成路线：1 步

_81%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; -78 °C; 30 min, -78 °C
1.2 Reagents: Triisopropyl borate ; -78 °C → -40 °C; 1 h, -40 °C
1.3 Reagents: Hydrochloric acid Solvents: Water

参考文献：

Biphenyl-diamine compounds as hole transport materials having high triplet energy and organic light emitting device thereby

, Korea, , ,

合成路线：1 步

1679-18-1

_80%

反应条件：

1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; rt → 120 °C; 14 h, 120 °C

参考文献：

Preparation of carbazole-containing triarylamine compounds for light-emitting devices

, China, , ,

合成路线：1 步

1679-18-1

_77%

反应条件：

1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; rt → 120 °C; 14 h, 120 °C

参考文献：

Preparation of carbazole compounds for organic electroluminescent devices

, China, , ,

合成路线：1 步

92-67-1

_76%

反应条件：

1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; rt → 110 °C; 6 h, 110 °C

参考文献：

Preparation of hole type organic electroluminescent compounds

, China, , ,

合成路线：1 步

_74%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 0.5 h, -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; -78 °C → rt; 30 min, rt

参考文献：

Organic luminescent compound used in OLED

, China, , ,

合成路线：1 步

_74%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 0.5 h, -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; -78 °C → rt; 30 min, rt

参考文献：

Benzopyrimidine derivative, preparation and application in OLED

, China, , ,

合成路线：1 步

_74%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 0.5 h, -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; -78 °C → rt; 30 min, rt

参考文献：

Fluorene derivative and its application in organic light emitting device

, China, , ,

合成路线：1 步

_67%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran , Water ; 1 h, -78 °C; 1 h, -78 °C
1.2 Reagents: Triisopropyl borate ; 3 h, -78 °C; -78 °C → rt; overnight, rt

参考文献：

Preparation of carbazole compounds and their application in organic electroluminescence devices

, China, , ,

合成路线：1 步

_66%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; rt → -78 °C; -78 °C; 1 h, -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; rt; 1 h, rt

参考文献：

Preparation of carbazole derivatives as organic electroluminescent materials

, Korea, , ,

合成路线：1 步

_57%

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 10 min, -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; 10 min, -78 °C; -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; 3 h, neutralized, rt

参考文献：

Anthraquinone-Based Intramolecular Charge-Transfer Compounds: Computational Molecular Design, Thermally Activated Delayed Fluorescence, and Highly Efficient Red Electroluminescence

Zhang, Qisheng; Kuwabara, Hirokazu; Potscavage, William J.; Huang, Shuping; Hatae, Yasuhiro; et al, Journal of the American Chemical Society, 2014, 136(52), 18070-18081

合成路线：1 步

反应条件：

1.1 Reagents: Butyllithium Solvents: Toluene , Hexane ; 1 h, -30 °C; -30 °C → -70 °C
1.2 Reagents: Triisopropyl borate ; -70 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: [1,1′-Biphenyl]-4,4′-diamine, N4′-[1,1′-biphenyl]-4-yl-2-(9H-carbazol-9-yl)-N4-(…

参考文献：

Preparation of biphenylcarbazole bistriarylamine organic compound for organic electroluminescence device

, China, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Potassium tert-butoxide Catalysts: Triphenylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; 12 h, reflux

参考文献：

Carbazole-containing organic compound and application thereof

, China, , ,

合成路线：1 步

106-37-6