945865-80-5 (3,5-二甲酰基苯基硼酸频哪醇酯,5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene-1,3-dicarbaldehyde)

_89%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 24 h, 90 °C

参考文献：

Preparation of covalent organic frameworks via one-pot Suzuki coupling and Schiff's base reaction for ethene/propene separation

Han, Xiang-Hao; Gong, Ke; Huang, Xin; Yang, Jian-Wei; Feng, Xiao ; et al, Angewandte Chemie, 2022, 61(25),

合成路线：1 步

_87%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,2-Dimethoxyethane ; 1 d, 80 °C

参考文献：

Second Generation Self-Assembling Dendrimer Combining Supramolecular and Dynamic Covalent Chemistry

Wetzel, Darte ; Luening, Ulrich, European Journal of Organic Chemistry, 2022, 2022(43),

合成路线：1 步

_87%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; rt → 90 °C; 16 h, 90 °C

参考文献：

Three-dimensional microporous and mesoporous covalent organic frameworks based on cubic building units

Liao, Li; Guan, Xinyu; Zheng, Haorui; Zhang, Zerong; Liu, Yaozu; et al, Chemical Science, 2022, 13(32), 9305-9309

合成路线：1 步

_87%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; rt → 90 °C; 16 h, 90 °C

参考文献：

Inducing Social Self-Sorting in Organic Cages To Tune The Shape of The Internal Cavity

Abet, Valentina ; Szczypinski, Filip T.; Little, Marc A. ; Santolini, Valentina ; Jones, Christopher D.; et al, Angewandte Chemie, 2020, 59(38), 16755-16763

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,2-Dimethoxyethane ; 24 h, reflux

参考文献：

Reversible Multistimuli Switching of a Spiropyran-Functionalized Organic Cage in Solid and Solution

Mondal, Bijnaneswar; Ghosh, Aloke Kumar; Mukherjee, Partha Sarathi, Journal of Organic Chemistry, 2017, 82(15), 7783-7790

合成路线：1 步

_80%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; rt → 95 °C; 24 h, 95 °C

参考文献：

Bottom-Up Synthesis of 8-Connected Three-Dimensional Covalent Organic Frameworks for Highly Efficient Ethylene/Ethane Separation

Jin, Fazheng; Lin, En; Wang, Tonghai; Geng, Shubo; Wang, Ting; et al, Journal of the American Chemical Society, 2022, 144(12), 5643-5652

合成路线：1 步

480424-62-2

76-09-5

_77%

反应条件：

1.1 Solvents: Tetrahydrofuran ; 18 h, rt

参考文献：

Regioselective 15-Bromination and Functionalization of a Stable Synthetic Bacteriochlorin

Fan, Dazhong; Taniguchi, Masahiko; Lindsey, Jonathan S., Journal of Organic Chemistry, 2007, 72(14), 5350-5357

合成路线：1 步