951776-24-2 (([1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I))

_97%

反应条件：

1.1 Solvents: Dichloromethane ; 40 min, rt

参考文献：

Structural Elucidation and Total Synthesis of Trichodermotin A, A Natural α-Glucosidase Inhibitor from Trichoderma asperellum

Yu, Muyuan; Wang, Fengqing; Yao, Si; Zang, Yi; Dai, Chong; et al, Chinese Journal of Chemistry, 2022, 40(18), 2219-2225

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Potassium tert-amylate Solvents: Toluene ; rt
1.2 Reagents: Oxygen Solvents: Benzene ; rt

参考文献：

Expedient Syntheses of Neutral and Cationic Au(I)-NHC Complexes

Veenboer, Richard M. P. ; Gasperini, Danila; Nahra, Fady ; Cordes, David B.; Slawin, Alexandra M. Z.; et al, Organometallics, 2017, 36(18), 3645-3653

合成路线：1 步

1240328-73-7

_91%

反应条件：

1.1 Solvents: Benzene ; 6 h, rt

参考文献：

New [Au(NHC)(OH)] Complexes for Silver-Free Protocols

Patrick, Scott R.; Gomez-Suarez, Adrian; Slawin, Alexandra M. Z.; Nolan, Steven P., Organometallics, 2014, 33(1), 421-424

合成路线：1 步

1240328-73-7

_91%

反应条件：

1.1 Solvents: Benzene ; 6 h, rt

参考文献：

A N-heterocyclic carbene gold hydroxide complex: a golden synthon

Gaillard, Sylvain; Slawin, Alexandra M. Z.; Nolan, Steven P., Chemical Communications (Cambridge, 2010, 46(16), 2742-2744

合成路线：1 步

_90%

反应条件：

1.1 Solvents: Dichloromethane ; 5 min, 23 °C

参考文献：

Sequential O-H/C-H Bond Insertion of Phenols Initiated by the Gold(I)-Catalyzed Cyclization of 1-Bromo-1,5-enynes

Speck, Klaus; Karaghiosoff, Konstantin; Magauer, Thomas, Organic Letters, 2015, 17(8), 1982-1985

合成路线：1 步

1694659-83-0

_89%

反应条件：

1.1 Solvents: Benzene-d6 ; 5 min, rt

参考文献：

Gold-Acetonyl Complexes: From Side-Products to Valuable Synthons

Gasperini, Danila; Collado, Alba; Gomez-Suarez, Adrian; Cordes, David B.; Slawin, Alexandra M. Z.; et al, Chemistry - A European Journal, 2015, 21(14), 5403-5412

合成路线：1 步

_88%

反应条件：

1.1 Solvents: Dichloromethane ; 4 h, rt

参考文献：

Dioxazoles, a new mild nitrene transfer reagent in gold catalysis: highly efficient synthesis of functionalized oxazoles

Chen, Ming; Sun, Ning; Chen, Haoyi; Liu, Yuanhong, Chemical Communications (Cambridge, 2016, 52(37), 6324-6327

合成路线：1 步

_83%

反应条件：

1.1 Reagents: Silver oxide (Ag2O) Solvents: Dichloromethane ; overnight, rt
1.2 Reagents: Gold, chloro[thiobis[methane]]- Solvents: Dichloromethane ; overnight, rt
1.3 Solvents: Dichloromethane ; 1 h, rt

参考文献：

Gold(I)-Catalyzed Formation of Naphthalene/Acenaphthene Heterocyclic Acetals

Michalska, Malina; Grudzien, Krzysztof; Malecki, Pawel; Grela, Karol, Organic Letters, 2018, 20(4), 954-957

合成路线：1 步

_81%

反应条件：

1.1 Solvents: Dichloromethane ; 5 min, rt

参考文献：

Synthesis and Reactivity of Air-Stable N-Heterocyclic Carbene Gold(I) Bis(trifluoromethanesulfonyl)imidate Complexes

Ricard, Louis; Gagosz, Fabien, Organometallics, 2007, 26(19), 4704-4707

合成路线：1 步

_80%

反应条件：

1.1 Solvents: Dichloromethane ; 5 min, rt

参考文献：

Gold- and Copper-Catalyzed Cycloisomerizations towards the Synthesis of Thujopsanone-Like Compounds

Fehr, Charles; Vuagnoux, Magali; Buzas, Andrea; Arpagaus, Jeremy; Sommer, Horst, Chemistry - A European Journal, 2011, 17(22), 6214-6220

合成路线：1 步

2132411-53-9

反应条件：

1.1 Solvents: Dichloromethane ; 1 h, rt

参考文献：

Recyclable gold(I)-catalyzed oxidative cyclization of 1,4-diyn-3-ols leading to highly substituted 3-formylfurans

Xiao, Xiaoqiang; Liu, Siqi; Cai, Mingzhong, Journal of Organometallic Chemistry, 2022, 982,

合成路线：1 步

反应条件：

1.1 Solvents: 1,2-Dichloroethane ; 20 min, rt

参考文献：

A gold(I)-catalysed chemoselective three-component reaction between phenols, α-diazocarbonyl compounds and allenamides

Yu, Sifan; Chen, Jinzhou; Liu, Gengxin; Lei, Jinping; Hu, Wenhao; et al, Chemical Communications (Cambridge, 2020, 56(11), 1649-1652

合成路线：1 步

反应条件：

1.1 Solvents: 1,4-Dioxane ; 10 min

参考文献：

Why can a gold salt react as a base?

Anania, Mariarosa; Jasikova, Lucie; Jasik, Juraj; Roithova, Jana, Organic & Biomolecular Chemistry, 2017, 15(37), 7841-7852

合成路线：1 步

参考文献：

N,N'-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene gold(I) chloride

Ramon, Ruben S.; Nolan, Steven P., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2011, 1, 1-7

合成路线：1 步

参考文献：

Insights into the Gold-Catalyzed Propargyl Ester Rearrangement/Tandem Cyclization Sequence: Radical versus Gold Catalysis- Myers-Saito- versus Schmittel-Type Cyclization

Rettenmeier, Eva; Hansmann, Max M.; Ahrens, Alexander; Ruebenacker, Katharina; Saboo, Tapish; et al, Chemistry - A European Journal, 2015, 21(41), 14401-14409

合成路线：1 步