95418-58-9 (对叔丁氧基苯乙烯,1-(tert-butoxy)-4-ethenylbenzene)

_98%

反应条件：

1.1 Reagents: Tripotassium phosphate Catalysts: Palladium diacetate , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: 1,4-Dioxane , Water ; 6 h, 100 °C

参考文献：

N-(Carboxymethyl)-N-methyl-glycine

Dailey, Ian; Burke, Martin D., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2010, 1, 1-7

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Tripotassium phosphate Catalysts: Palladium diacetate , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: 1,4-Dioxane , Water ; 6 h, 60 °C

参考文献：

Slow release of organoboronic acids in cross-coupling reactions

, World Intellectual Property Organization, , ,

合成路线：1 步

_98%

反应条件：

1.1 Catalysts: Palladium diacetate , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: 1,4-Dioxane , Water ; 23 °C; 10 min, 23 °C
1.2 Reagents: Tripotassium phosphate Solvents: Water ; 23 °C; 6 h, 60 °C

参考文献：

A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates

Knapp, David M.; Gillis, Eric P.; Burke, Martin D., Journal of the American Chemical Society, 2009, 131(20), 6961-6963

合成路线：1 步

104333-10-0

_96%

反应条件：

1.1 Reagents: Potassium bisulfate Catalysts: Tempo ; rt → 130 °C; 100 mm Hg, 130 °C; 130 °C → 180 °C; 180 °C; 30 min, 180 °C; 180 °C → 190 °C

参考文献：

Novel process for producing styrene compound

, China, , ,

合成路线：1 步

60876-70-2

75-01-4

_86%

反应条件：

1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran ; 1 h, 40 - 50 °C
1.2 Catalysts: Ferrous bromide ; 1 h, 20 - 30 °C

参考文献：

Process for the production of styrene compound, and styrene compound free from biphenyl

, United States, , ,

合成路线：1 步

60876-70-2

74-85-1

_85%

反应条件：

1.1 Reagents: Triethylamine Catalysts: Palladium diacetate , Tri-o-tolylphosphine Solvents: Acetonitrile

参考文献：

Improved preparation of 4-tert-butoxystyrene

, Japan, , ,

合成路线：1 步

104333-10-0

_83%

反应条件：

1.1 Reagents: Sodium bicarbonate Catalysts: Triphenylphosphine , Aluminum chloride Solvents: Nitromethane ; 2 h, rt → 80 °C

参考文献：

Preparation of phenenyl compound

, China, , ,

合成路线：1 步

1225375-38-1

108-05-4

_81%

反应条件：

1.1 Reagents: 2-Methyl-2-butanol , Potassium phosphate Catalysts: 1,4-Bis(diphenylphosphino)butane , Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium Solvents: Toluene ; rt → 100 °C; 2 h, 100 °C

参考文献：

Preparation of vinyl compounds using vinyl acetates as vinylation agents

, Japan, , ,

合成路线：1 步

75-01-4

_80%

反应条件：

1.1 Reagents: Ethyl bromide , Magnesium Solvents: Tetrahydrofuran
1.2 Catalysts: Manganese dichloride Solvents: Tetrahydrofuran

参考文献：

Preparation of biphenyl-free tert-butoxystyrene

, Japan, , ,

合成路线：1 步

60876-70-2

3536-96-7

_75%

反应条件：

1.1 Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Tetrahydrofuran ; 3 h, 0 °C; 0 °C → 5 °C
1.2 Reagents: Hydrochloric acid Solvents: Water ; 0.5 h, 10 °C

参考文献：

Preparation of 4-tert-butoxystyrene

, China, , ,

合成路线：1 步

51503-08-3

67-71-0

_70%

反应条件：

1.1 Reagents: Potassium tert-butoxide Catalysts: (OC-6-44)-Aquadichloro[4,4′-[(2,6-pyridinediyl-κN)bis(methylene)]bis[morpholine-… Solvents: Toluene ; 12 h, 110 °C

参考文献：

Nickel(II)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H2

Landge, Vinod G.; Yadav, Vinita; Subaramanian, Murugan; Dangarh, Pragya; Balaraman, Ekambaram, Chemical Communications (Cambridge, 2019, 55(43), 6130-6133

合成路线：1 步

329318-60-7

79-10-7

_68%

反应条件：

1.1 Reagents: Potassium carbonate Catalysts: Molybdate(42-), triacontakis[μ-(acetato-κO:κO′)]doheptacontaaquaoctacontahecta-μ… Solvents: Dimethyl sulfoxide ; 36 h

参考文献：

Light driven decarboxylative cross coupling of acrylic acid and iodobenzene using [Mo132] type Keplerate as catalyst

Das, Santu; Misra, Archismita; Roy, Soumyajit, Inorganica Chimica Acta, 2017, 460, 77-82

合成路线：1 步

51503-08-3

67-71-0

_63%

反应条件：

1.1 Reagents: Potassium tert-butoxide Catalysts: 1,10-Phenanthroline , Ferrous chloride Solvents: Toluene ; 8 h, 120 °C

参考文献：

Iron-Catalyzed Direct Julia-Type Olefination of Alcohols

Landge, Vinod G.; Babu, Reshma; Yadav, Vinita; Subaramanian, Murugan; Gupta, Virendrakumar; et al, Journal of Organic Chemistry, 2020, 85(15), 9876-9886

合成路线：1 步

677-22-5

100-42-5

反应条件：

1.1 Catalysts: sec-Butyllithium Solvents: Tetrahydrofuran ; -78 °C

参考文献：

Analysis of Homopolymer Distribution in a Polymer Blend Thin Film by Anomalous Grazing Incidence Small-Angle X-ray Scattering at the Bromine K-Edge

Hamamoto, Hiroki; Takagi, Hideaki ; Akiba, Isamu ; Yamamoto, Katsuhiro, Macromolecules (Washington, 2021, 54(1), 488-498

合成路线：1 步