97-99-4 (四氢糠醇,Tetrahydrofurfuryl alcohol)

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Palladium , Carbon Solvents: Isopropanol ; 5 h, 500 psi, 493 K

参考文献：

Single step process for conversion of furfural to tetrahydrofuran using carbon-supported palladium catalyst

, World Intellectual Property Organization, , ,

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Isopropanol ; 5 h, 35 bar, 493 K

参考文献：

Tailoring the Product Distribution with Batch and Continuous Process Options in Catalytic Hydrogenation of Furfural

Biradar, Narayan S.; Hengne, Amol A.; Birajdar, Shobha N.; Swami, Rameshwar; Rode, Chandrashekhar V., Organic Process Research & Development, 2014, 18(11), 1434-1442

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Cobalt oxide Solvents: Ethanol ; 600 min, 3 MPa, 150 °C

参考文献：

Solvent-mediated selectivity control of furfural hydrogenation over a N-doped carbon-nanotube-supported Co/CoOx catalyst

Ranaware, Virendra; Kurniawan, Rizky Gilang; Verma, Deepak; Kwak, Sang Kyu; Ryu, Beom Chan; et al, Applied Catalysis, 2022, (2022),

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Tetrahydrofuran ; 1 MPa, rt; rt → 160 °C; 4 h, 160 °C

参考文献：

Switchable synthesis of furfurylamine and tetrahydrofurfurylamine from furfuryl alcohol over RANEY nickel

Liu, Yingxin; Zhou, Kuo; Shu, Huimin; Liu, Haiyan; Lou, Jiongtao; et al, Catalysis Science & Technology, 2017, 7(18), 4129-4135

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Isopropanol ; 24 h, 2 MPa, 423 K

参考文献：

Synthesis of 1,5-Pentanediol by Hydrogenolysis of Furfuryl Alcohol over Ni-Y2O3 Composite Catalyst

Wijaya, Husni Wahyu; Kojima, Takashi; Hara, Takayoshi; Ichikuni, Nobuyuki; Shimazu, Shogo, ChemCatChem, 2017, 9(14), 2869-2874

合成路线：1 步

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反应条件：

1.1 Catalysts: Palladium , Hexakis[μ-[1,4-benzenedicarboxylato(2-)-κO1:κO′1]]tetra-μ3-hydroxytetra-μ3-oxohe… Solvents: Methanol ; 4 h, 1 MPa, 60 °C

参考文献：

Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol over Pd/UiO-66

Wang, Chunhua; Wang, Anjie; Yu, Zhiquan ; Wang, Yao ; Sun, Zhichao; et al, Catalysis Communications, 2021, 148,

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Isopropanol ; 3 h, 1 MPa, 25 °C

参考文献：

Hydrogenation of Biomass-Derived Furfural to Tetrahydrofurfuryl Alcohol over Hydroxyapatite-Supported Pd Catalyst under Mild Conditions

Li, Chuang; Xu, Guangyue; Liu, Xiaohao; Zhang, Ying ; Fu, Yao, Industrial & Engineering Chemistry Research, 2017, 56(31), 8843-8849

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Aluminum alloy, base, Al 50,Ni 50 , Aluminum hydroxide Solvents: Isopropanol ; 1 h, 453 K

参考文献：

Hydrogenation of Biomass-derived Furfural Over Highly Dispersed-Aluminium Hydroxide Supported Ni-Sn(3.0) Alloy Catalysts

Rodiansono; Astuti, Maria Dewi; Santoso, Uripto Trisno; Shimazu, Shogo, Procedia Chemistry, 2015, 16, 531-539

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Isopropanol ; 1 h, 3 MPa, 453 K

参考文献：

A novel preparation method of Ni-Sn alloy catalysts supported on aluminum hydroxide: application to chemoselective hydrogenation of unsaturated carbonyl compounds

Rodiansono; Hara, Takayoshi; Ichikuni, Nobuyuki; Shimazu, Shogo, Chemistry Letters, 2012, 41(8), 769-771

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Decalin , Water ; 3 h, 2 MPa, 100 °C

参考文献：

Method for catalytic hydrogenation and upgrading of biomass platform compound in Pickering emulsion system

, China, , ,

合成路线：1 步

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反应条件：

1.1 Reagents: Sodium borohydride Catalysts: Alumina , Nickel Solvents: Water ; 90 min, 100 °C

参考文献：

A Supported Ni Catalyst Produced from Ni-Al Hydrotalcite-Like Precursor for Reduction of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol by NaBH4 in Water

Ren, Dezhang; Wang, Jingyi; Jiang, Xuelei; Song, Zhiyuan; Norinaga, Koyo; et al, ChemistrySelect, 2021, 6(4), 551-556

合成路线：1 步

21915-56-0

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反应条件：

1.1 Solvents: Hexafluorobenzene ; 22 h, 20 °C

参考文献：

Polyether Natural Product Inspired Cascade Cyclizations: Autocatalysis on π-Acidic Aromatic Surfaces

Paraja, Miguel; Hao, Xiaoyu; Matile, Stefan, Angewandte Chemie, 2020, 59(35), 15093-15097

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Ruthenium Solvents: Water ; 255 min, 10 bar, 30 °C

参考文献：

Anionic Amphiphilic Cyclodextrins Bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation

Cocq, Aurelien ; Leger, Bastien; Noel, Sebastien; Bricout, Herve ; Djedaini-Pilard, Florence; et al, ChemCatChem, 2020, 12(4), 1013-1018

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Ethanol ; 1 MPa, 90 °C

参考文献：

Preparation of tetrahydrofurfuryl alcohol

, China, , ,

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Palladium diacetate , Palladium nitrate , Acetic acid, ruthenium(3+) salt Solvents: Water ; 4 h, 0.5 MPa, 30 °C

参考文献：

Method for preparing tetrahydrofurfuryl alcohol

, China, , ,

合成路线：1 步

21915-56-0

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反应条件：

1.1 Reagents: Dibromomethane Catalysts: Hexafluorobenzene ; 5 d, 20 °C

参考文献：

Primary Anion-π Catalysis and Autocatalysis

Zhang, Xiang; Hao, Xiaoyu; Liu, Le; Pham, Anh-Tuan; Lopez-Andarias, Javier; et al, Journal of the American Chemical Society, 2018, 140(51), 17867-17871

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Hydroxylapatite (Ca5(OH)(PO4)3) , Palladium Solvents: Ethanol ; 4 h, 2 MPa, rt → 60 °C

参考文献：

Process for the preparation of tetrahydrofurfuryl alcohol using Pd-loaded apatite as hydrogenation catalyst

, China, , ,

合成路线：1 步

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反应条件：

1.1 Reagents: Hydrogen Catalysts: Alumina , Nickel Solvents: Ethanol ; 2 h, 4 MPa, 353 K

参考文献：

Selective hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol over Ni/γ-Al2O3 catalysts

Sang, Shengya; Wang, Yuan; Zhu, Wei; Xiao, Guomin, Research on Chemical Intermediates, 2017, 43(2), 1179-1195

合成路线：1 步

69406-23-1

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反应条件：

1.1 Reagents: Oxygen Catalysts: 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone , Iron(II) phthalocyanine , 4,4′-Bipyridine Solvents: Toluene ; 24 h, 0.4 MPa, 80 °C

参考文献：

2,3-Dichloro-5,6-dicyano-1,4-benzoquinone-catalyzed aerobic oxidation reactions via multistep electron transfers with iron(II) phthalocyanine as an electron-transfer mediator

Hong, Yiming; Fang, Tiantian; Li, Meichao; Shen, Zhenlu; Hu, Xinquan; et al, RSC Advances, 2016, 6(57), 51908-51913

合成路线：1 步

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