983-80-2 (顺-1,2-双(二苯基膦)乙烯,(Z)-1,2-Bis(diphenylphosphino)ethene)

CAS号:
983-80-2
中文名称:
顺-1,2-双(二苯基膦)乙烯
英文名称:
(Z)-1,2-Bis(diphenylphosphino)ethene
安全信息:
分子式:
C26H22P2
分子量:
396.400408267975

顺-1,2-双(二苯基膦)乙烯(983-80-2)名称与标识符

名称

中文别名:
顺-1,2-双(二苯基膦)乙烯;顺式-1,2-双(二苯基膦)乙烯;
英文别名:
(Z)-1,2-Bis(diphenylphosphino)ethene;cis-1,2-Bis(diphenylphosphino)ethylene;[(Z)-2-diphenylphosphanylethenyl]-diphenylphosphane;cis-1,2-Bis(diphenylphosphino)ethene;cis-Vinylenebis(diphenylphosphine);cis-1,2-Bis(diphenylphosphine)ethylene;cis-Bis(diphenylphosphino)ethylene;cis-Vinylenebis[diphenylphosphine];Phosphine, vinylenebis(diphenyl-, (E)-;NSC-132587;NCKJIJSEWKIXAT-DQRAZIAOSA-N;Phosphine, 1,2-ethenediylbis[diphenyl-, (E)-;[(Z)-2-diphenylphosphanylvinyl]-diphenyl-phosphane;Phosphine, trans-;trans-Vinylenebis[diphenylphosphine];CS-W009728;NSC132588;DTXSID601283879;A845853;NSC132587;983-80-2;cis-1,2-Bis(diphenylphosphino)ethylene, 97%;CHEMBL2114057;NSC-132588;[(1Z)-2-(diphenylphosphanyl)ethenyl]diphenylphosphane;[(Z)-2-(Diphenylphosphino)ethenyl](diphenyl)phosphine #;trans-Vinylenebis(diphenylphosphine);Phosphine, vinylenebis(diphenyl-, trans-;Phosphine,2-ethenediylbis[diphenyl-, (E)-;EINECS 213-569-7;SCHEMBL338474;1,2-bis(diphenylphosphino)ethylene;AKOS002263216;trans-1,2-Bis(diphenylphosphinyl)ethylene;AS-62969;Phosphine, (E)-;NSC 132588;A12963;DB-243274;

标识符

MDL:
MFCD00003046
InChIKey:
NCKJIJSEWKIXAT-DQRAZIAOSA-N
Inchi:
1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21-
SMILES:
P(/C=C\P(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
BRN:
757792

顺-1,2-双(二苯基膦)乙烯(983-80-2)物化性质

实验特性

  • LogP : 5.72340
  • PSA : 27.18000
  • 水溶性 : Insoluble in water.
  • 沸点 : 546.8 °C at 760 mmHg
  • 熔点 : 122-124 °C (lit.)
  • 闪点 : 302.7 °C
  • 颜色与性状 : 未确定。
  • 溶解性 : 未确定
  • 敏感性 : Air Sensitive

计算特性

  • 精确分子量 : 396.12000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 6
  • 同位素质量 : 396.12
  • 重原子数量 : 28
  • 复杂度 : 371
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 1
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 5.9
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

顺-1,2-双(二苯基膦)乙烯(983-80-2)国际标准相关数据

EINECS:
213-569-7

顺-1,2-双(二苯基膦)乙烯(983-80-2)海关数据

海关编码:
2902909090
海关数据:

中国海关编码:

2902909090

概述:

2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

申报要素:

品名, 成分含量

Summary:

2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

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顺-1,2-双(二苯基膦)乙烯(983-80-2)相关文献

顺-1,2-双(二苯基膦)乙烯(983-80-2) MSDS

基础信息

Name:Cis-1 2-Bis(Diphenylphosphino)Ethylene Material Safety Data Sheet
Synonym:
CAS:983-80-2
Section 1 - Chemical Product ? MSDS Name:Cis-1 2-Bis(Diphenylphosphino)Ethylene Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
983-80-2Cis-1,2-Bis(Diphenylphosphino)Ethylene213-569-7
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 983-80-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 122 - 124 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: (C6H5)2PCH=CHP(C7H5)2
Molecular Weight: 396.41

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stability unknown. Thermal decomposition may produce toxic fumes of phosphorous oxides and/or phosphine.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 983-80-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cis-1,2-Bis(Diphenylphosphino)Ethylene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 983-80-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 983-80-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 983-80-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A