99-59-2 (2-氨基-4-硝基苯甲醚,2-Methoxy-5-nitroaniline)

快速询单

结构式：

2-氨基-4-硝基苯甲醚MOL文件

CAS号：

99-59-2

中文名称：

2-氨基-4-硝基苯甲醚

英文名称：

2-Methoxy-5-nitroaniline

安全信息：

分子式：

C₇H₈N₂O₃

分子量：

168.15002155304

2-氨基-4-硝基苯甲醚(99-59-2)名称与标识符

名称

中文别名：

2-氨基-4-硝基苯甲醚;邻氨基对硝基苯甲醚;2-甲氧基-5-硝基苯胺;大红色基R;粗色基R;2-Methoxy-5-nitroaniline 2-甲氧基-5-硝基苯胺;2-甲氧基-5-硝基苯胺(易制爆);溴莫尼定;2-氨基-4-硝基茴香醚;5-硝基邻茴香胺;5-硝基邻甲氧基苯胺;

英文别名：

2-Methoxy-5-nitroaniline;5-Nitro-o-anisidine;Methoxynitroaniline;scarlet base R;2-Amino-4-nitroanisole~5-Nitro-o-anisidine;2-Amino-4-nitro anisidine;2-Methoxy-5-nitroaniline Solution;Azoamine Scarlet K;2-Amino-4-nitroanisole;Fast Scarlet R;2-Methoxy-5-nitrobenzenamine;2-Amino-1-methoxy-4-nitrobenzene;Azoamine Scarlet;5-Nitro-2-methoxyaniline;o-Anisidine nitrate;o-Anisidine, 5-nitro-;Benzenamine, 2-methoxy-5-nitro-;Azogene ecarlate R;3-Amino-4-methoxynitrobenzene;3-Nitro-6-methoxyaniline;Aniline, 2-methoxy-5-nitro-;5-Nitro-ortho-anisidine;Azoic Diazo Component 13, Base;C.I. Azoic Diazo Component 13;W-109372;THY70UTM0O;Z56782014;WLN: WNR CZ DO1;NCGC00091266-03;C.I. 37130;4-Nitro-2-aminoanisole;CAS-99-59-2;2Methoxy-5-nitroaniline;UNII-THY70UTM0O;Tox21_300122;NCGC00091266-02;DTXSID0020943;Q27121416;FT-0612807;C19469;InChI=1/C7H8N2O3/c1-12-7-3-2-5(9(10)11)4-6(7)8/h2-4H,8H2,1H;NSC-5510;2-Methoxy 5-nitro aniline;1-Amino-2-methoxy-5-nitrobenzene;HSDB 4104;NSC5510;MFCD00007261;(2-methoxy-5-nitrophenyl)amine;DTXCID60943;5-NITRO-ORTHO-ANISIDINE [IARC];EINECS 202-770-5;NCGC00254158-01;2-(methyloxy)-5-nitroaniline;2-methoxyl-5-nitroaniline;CHEMBL319398;NCGC00091266-04;AI3-08934;CI 37130;CI Azoic diazo component 13;SCHEMBL269845;CS-0015286;AMY40951;CHEBI:48977;2-Methoxy-5-nitroaniline, 98%;NCI-C01934;YSZC2421;BRN 0879620;AKOS000498225;NCGC00091266-01;5-NITRO-2-METHOXYANILINE [HSDB];AS-58184;Tox21_201636;2-methoxy-5-nitro phenylamine;M0492;AN-652/40187552;1-Methoxy-2-amino-4-nitrobenzene;2-METHOXY-5-NITRO-PHENYLAMINE;EN300-16794;2-methoxy-5-nitro aniline;D72503;CCRIS 440;SY002529;2-amino-4-nitro-1-methoxybenzene;EC 202-770-5;99-59-2;2-AMINO-4-NITRO ANISOLE;NS00003314;F0020-2000;2-amino-4-nitroanisol;NCGC00259185-01;NSC 5510;2Methoxy5nitroaniline;2Amino1methoxy4nitrobenzene;2Amino4nitroanisole;3Nitro6methoxyaniline;oAnisidine, 5nitro;5Nitro2methoxyaniline;5-Nitro-o-anisidine;Azoamine Scarlet K;2-Methoxy-5-nitroaniline;Benzenamine, 2methoxy5nitro;5-NITRO-ORTHO-ANISIDINE (IARC);3Amino4methoxynitrobenzene;Aniline, 2methoxy5nitro;2Methoxy5nitrobenzenamine;STK399982;

标识符

MDL：

MFCD00007261

InChIKey：

NIPDVSLAMPAWTP-UHFFFAOYSA-N

Inchi：

1S/C7H8N2O3/c1-12-7-3-2-5(9(10)11)4-6(7)8/h2-4H,8H2,1H3

SMILES：

O(C)C1C=CC(=CC=1N)[N+](=O)[O-]

BRN：

879620

2-氨基-4-硝基苯甲醚(99-59-2)物化性质

实验特性

LogP : 2.29000
PSA : 81.07000
折射率 : 1.6010 (estimate)
水溶性 : 微溶. <0.01 g/100 mL at 19.5 ºC
沸点 : 337.07°C (rough estimate)
熔点 : 117-119 °C (lit.)
闪点 : 华氏：246.2 °F
摄氏：119 °C
颜色与性状 : 橙红色针状晶体。
稳定性 : Stable, but may be moisture sensitive. Incompatible with water, acids, strong oxidizing agents, acid chlorides, acid anhydrides, chloroformates, liquid anisidine.
溶解性 : 易溶于丙酮、甲醇、乙醇、苯、乙酸乙酯等。不溶于石油醚。
色指数 : 37130
密度 : 1.2068

计算特性

精确分子量 : 168.05300
氢键供体数量 : 1
氢键受体数量 : 4
可旋转化学键数量 : 1
同位素质量 : 168.053
重原子数量 : 12
复杂度 : 169
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 1.5
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 81.1

2-氨基-4-硝基苯甲醚(99-59-2)安全信息

符号： GHS07
RTECS号： BZ7175000
WGK Germany： 2
安全术语： 6.1
安全说明： S26-S36-S45-S36/37
包装等级： I; II; III
风险术语： R20/21/22
危险品标志： Xn
危险品运输编号： NONH for all modes of transport
危害声明：H302
警示性声明：P301 + P312 + P330
储存条件： Keep in dark place,Sealed in dry,2-8°C
危险类别码： 36/37/38
信号词： Warning
TSCA： Yes

2-氨基-4-硝基苯甲醚(99-59-2)国际标准相关数据

EINECS：

202-770-5

2-氨基-4-硝基苯甲醚(99-59-2)海关数据

海关编码：

2922299090

海关数据：

中国海关编码：

2922299090

概述：

2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

Summary：

2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2-氨基-4-硝基苯甲醚(99-59-2)推荐厂家更多厂家(43)

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湖北巨胜科技有限公司	18871490354	王珊	1400848866	询单
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2-氨基-4-硝基苯甲醚(99-59-2)上下游

4-氯-8-甲氧基喹啉 3-Bromo-4-methoxyaniline 3-溴-4-甲氧基苯胺 2-碘-4-硝基苯甲醚

2-氨基-4-硝基苯甲醚(99-59-2)相关文献

1. Solution-phase hierarchical self-organization of ultralong Se nanowires into diverse macroarchitectures and their enhanced field emission
Xueli Guo,Lihui Fang,Yiwei Tan Phys. Chem. Chem. Phys. 2015 17 2794
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3. 59. Polyhalogeno-o-anisidines and their derivatives
W. S. W. Harrison,A. T. Peters,F. M. Rowe J. Chem. Soc. 1943 235
4. Mineral identity, natural organic matter, and repeated contaminant exposures do not affect the carbon and nitrogen isotope fractionation of 2,4-dinitroanisole during abiotic reduction
Matthew J. Berens,Bridget A. Ulrich,Jennifer H. Strehlau,Thomas B. Hofstetter,William A. Arnold Environ. Sci.: Processes Impacts 2019 21 51
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6. Large-scale, solution-phase growth of semiconductor nanocrystals into ultralong one-dimensional arrays and study of their electrical properties
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7. 75. Arylpyridines. Part III. Anisyl- and nitroanisylpyridines
J. W. Haworth,I. M. Heilbron,D. H. Hey J. Chem. Soc. 1940 358
8. Organic chemistry
J. Chem. Soc. Abstr. 1916 110 i1
9. 92. A reaction of certain diazosulphonates derived from β-naphthol-1-sulphonic acid. Part XIX. Derivatives of 4′-nitro-2′-methoxybenzene-2-naphthol-1-diazosulphonate
F. M. Rowe,E. J. Cross J. Chem. Soc. 1947 461
10. Formula index
J. Chem. Soc. 1943 678

2-氨基-4-硝基苯甲醚(99-59-2)参考资料

Beilstein：

13,389

PubChem CID：

7447

2-氨基-4-硝基苯甲醚(99-59-2) MSDS

基础信息

Name:	2-Methoxy-5-nitroaniline 99% Material Safety Data Sheet
Synonym:	5-Nitro-o-anisidine; 3-Amino-4-Methoxynitrobenzene; 3-Nitro-6-Methoxyaniline
CAS:	99-59-2

Section 1 - Chemical Product ? MSDS Name:2-Methoxy-5-nitroaniline 99% Material Safety Data Sheet
Synonym:5-Nitro-o-anisidine; 3-Amino-4-Methoxynitrobenzene; 3-Nitro-6-Methoxyaniline

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
99-59-2	2-Methoxy-5-nitroaniline	99.0	202-770-5

Hazard Symbols: T+
Risk Phrases: 26/27/28 33

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.Moisture sensitive.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause cancer according to animal studies.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible material; may burn but does not ignite readily.
Extinguishing Media:
Water or foam may cause frothing. Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 99-59-2: Russia: 1 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: orange to brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.3104 mm Hg @25C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 117.0 - 119.0 deg C
Autoignition Temperature: Not available.
Flash Point: 200 deg C ( 392.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 200 deg C
Solubility in water: 2206 mg/L @25C
Specific Gravity/Density: 1.207 @156C
Molecular Formula: C7H8N2O3
Molecular Weight: 168.15

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates, liquid anisidine.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 99-59-2: BZ7175000 LD50/LC50:
CAS# 99-59-2: Oral, mouse: LD50 = 1060 mg/kg; Oral, rabbit: LD50 = 1 gm/kg; Oral, rat: LD50 = 2250 mg/kg.
Carcinogenicity:
2-Methoxy-5-nitroaniline - California: carcinogen, initial date 10/1/89 Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
? Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 99-59-2: No information available.
Canada
CAS# 99-59-2 is listed on Canada's NDSL List.
CAS# 99-59-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-59-2 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A