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Dome-distortion and fluorine-lined channels: synthesis, and molecular and crystal structure of a metal- and C–H bonds-free fluorophthalocyanine†
Hyun-Jin Lee,William W. Brennessel,Joshua A. Lessing,William W. Brucker,Victor G. Young, Jr.,Sergiu M. Gorun
Chemical Communications Pub Date : 06/03/2003 00:00:00 , DOI:10.1039/B303035K
Abstract

The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for ∼ 39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.

Graphical abstract: Dome-distortion and fluorine-lined channels: synthesis, and molecular and crystal structure of a metal- and C–H bonds-free fluorophthalocyanine
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