Cycloaddition reaction of tert-butyl isocyanate and a tellurium diimide dimer: extended helical structure of the ureato telluroxide {[OC(μ-NBut)2TeO]2(thf)} ∞
Gabriele Schatte,Tristram Chivers,Cory Jaska,Nicole Sandblom
Chemical Communications Pub Date : 08/11/2000 00:00:00 , DOI:10.1039/B004137H
Abstract

The reaction of ButNTe(μ-NBut)2TeNBut with ButNCO in a 1∶4 molar ratio in thf produces N,N′-bis(tert-butyl)ureato telluroxide dimers [OC(μ-NBut)2TeO]2, which form an extended helical network via weak [double bond splayed left]C[double bond, length half m-dash]O⋯Te interactions.