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Effect of lanthanum doping on modulating the thermochromic properties of VO2 thin films
Ning Wang,Nigel Tan Chew Shun,Martial Duchamp,Rafal E. Dunin-Borkowski,Zhong Li,Yi Long
RSC Advances Pub Date : 05/09/2016 00:00:00 , DOI:10.1039/C6RA09514C
Abstract

Lanthanum (La) doped vanadium dioxide (VO2) thin films were fabricated through a facile sol–gel technique. The La doping was found to be effective for reducing the phase transition temperature (τc) of VO2 below the 4 at% doping level, with a reducing rate of −1.1 °C per at%. In addition, below the 3 at% La doping level, the band gap (Eg) decreased steadily with the increasing addition of La dopants. 5 at% La doping can enhance both the integrated visible transmission (Tlum) and the solar modulating ability (ΔTsol) simultaneously. The combination of Tlum = 50.1% and ΔTsol = 10.3% represents the best values for VO2 continuous thin films.

Graphical abstract: Effect of lanthanum doping on modulating the thermochromic properties of VO2 thin films
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