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Formation of a bifunctional zirconocene complex that favours intramolecular –B(C6F5)2 addition to a Cp ring over σ-ligand abstraction
Michael Hill,Gerald Kehr,Gerhard Erker,Olga Kataeva,Roland Fröhlich
Chemical Communications Pub Date : 03/23/2004 00:00:00 , DOI:10.1039/B400228H
Abstract

The diphenyl-ansa-zirconocene complex 2 adds HB(C6F5)2 at the C[double bond, length as m-dash]C double bond of its pendent Cp-allyl functional group to yield 3. During 3 days at room temperature the –B(C6F5)2 group takes part in an electrophilic substitution reaction at the adjacent Cp-ring to form 5 with formation of one equivalent of benzene. Complex 5 was characterized by X-ray diffraction

Graphical abstract: Formation of a bifunctional zirconocene complex that favours intramolecular –B(C6F5)2 addition to a Cp ring over σ-ligand abstraction
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