960化工网
Grain growth study of perovskite thin films prepared by flash evaporation and its effect on solar cell performance†
Haitao Xu,Yanglin Wu,Fuzong Xu,Jiabin Zhu,Chaowei Ni,Wenzhen Wang,Feng Hong,Run Xu,Jian Huang,Linjun Wang
RSC Advances Pub Date : 05/03/2016 00:00:00 , DOI:10.1039/C6RA07549E
Abstract

Flash evaporation is a vacuum-based evaporation method that is particularly suitable to prepare perovskite films for solar cell devices. Growth pressure has been found to be a critical parameter for perovskite film growth. The transport-determined growth mechanism is discussed in detail. The dense MAPbI3 films can be achieved only under a low growth pressure of 5 × 10−3 Pa, while a rough surface covered by step-like grains and voids is found for MAPbI3 films grown under a high Ar pressure of 10 Pa. In addition, we found that the presence of PbI2 phase in the perovskite films could suppress the growth of the grain size; by using precursors with a high MAI/PbI2 ratio, evaporated MAPbI3 films with grain sizes larger than 500 nm can be achieved. The average power conversion efficiency of the perovskite solar cells increased from 1.82% to 10.01% with increasing grain size, indicating the universal importance of controlling the perovskite grain size for the performance improvement of solar cells based on both solution and evaporated perovskite films.

Graphical abstract: Grain growth study of perovskite thin films prepared by flash evaporation and its effect on solar cell performance
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