960化工网
Filled trivacant icosahedra as building fragments in 17-atom endohedral germanides [TM2@Ge17]n− (TM = Co, Ni)†
Christoph Wallach,Yasmin Selic,Benedikt J. L. Witzel,Wilhelm Klein,Thomas F. Fässler
Dalton Transactions Pub Date : 09/15/2021 00:00:00 , DOI:10.1039/D1DT03078G
Abstract

The syntheses and the characterization of two 17-atom endohedral Ge clusters, [Co2@Ge17]6− (1a) and [Ni2@Ge17]4− (2a), are reported. The anions 1a and 2a, which close the gap between the known 16- and 18-atom Ge clusters, are investigated by single crystal X-ray diffraction and by quantum chemical calculations. The structures mark a new example on the pathway for cluster growth towards larger clusters with icosahedral symmetry. Furthermore, the [Co@Ge10]3− anion (3a) is obtained from liquid ammonia.

Graphical abstract: Filled trivacant icosahedra as building fragments in 17-atom endohedral germanides [TM2@Ge17]n− (TM = Co, Ni)
平台客服
平台客服
平台在线客服