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In situ Rheo-GISANS of triblock copolymers: gelation and shear effects on quasi-crystalline structures at interfaces
Gemma E. Newby,Paul A. Staniec
RSC Advances Pub Date : 12/01/2015 00:00:00 , DOI:10.1039/C5RA20215A
Abstract

The behaviour of polymeric systems at surfaces and under flow is extremely important in many applications, ranging from drug delivery to lubrication. We have studied a model triblock copolymer in deuterated water combining in situ rheology and grazing incidence small angle neutron scattering. Several thermotropic phases appear as a function of the temperature, including a bicontinuous phase not present in the bulk. Moreover, gelation can occur following a different route depending on the concentration. We show that shearing can be used to monitor the structural integrity of the micellar systems and in some cases as a tool for modifying the thermotropic phases: an fcc (face centred cubic) phase is sheared into a hcp (hexagonally close packed) phase, and is then recovered by cycling the temperature.

Graphical abstract: In situ Rheo-GISANS of triblock copolymers: gelation and shear effects on quasi-crystalline structures at interfaces
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