On the remarkable structural diversity and kinetic lability of TpC*CaX complexes (X = NSi2Me6, OC6H4-p-Me, TpC*) where TpC* = tris[3-(2-methoxy-1,1-dimethylethyl)pyrazolyl]hydroborate†
Malcolm H. Chisholm,Judith C. Gallucci,Gülşah Yaman,Tanya Young
Chemical Communications Pub Date : 02/25/2009 00:00:00 , DOI:10.1039/B818375A
Abstract
The preparation, structures and solution NMR properties of the title compounds are reported and, remarkably, the compounds (TpC*)2M, where M = Ca and Mg, exist as salts in the solid state and undergo facile TpC* ligand exchange in solution.
![Graphical abstract: On the remarkable structural diversity and kinetic lability of TpC*CaX complexes (X = NSi2Me6, OC6H4-p-Me, TpC*) where TpC* = tris[3-(2-methoxy-1,1-dimethylethyl)pyrazolyl]hydroborate](http://hg.y866.cn/compound/lib/scimg/usr/1/B818375A.jpg)
