Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes†‡
Thomas D. Roberts,Marc A. Little,Floriana Tuna,Colin A. Kilner,Malcolm A. Halcrow
Chemical Communications Pub Date : 05/30/2013 00:00:00 , DOI:10.1039/C3CC43613F
Abstract
Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.
