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A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device†
Vishwanath Kalyani,V. S. V. Satyanarayana,Abdus Salam Sarkar,Ashwani Kumar,Suman K. Pal,Subrata Ghosh,Kenneth E. Gonsalves,Chullikkattil P. Pradeep
RSC Advances Pub Date : 04/17/2015 00:00:00 , DOI:10.1039/C5RA05550D
Abstract

A new radiation sensitive polyoxometalate/polymer hybrid, POM–MAPDST, has been synthesized from an Mn-Anderson cluster based hybrid and a UV active organic monomer and tested for its photo-response properties by fabricating an ITO/POM–MAPDST/Al device. This device showed improved IV characteristics under illumination possibly due to the synergistic interactions between the polyoxometalate cluster and the organic components of the hybrid polymer.

Graphical abstract: A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device
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