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A redox-switchable [2]rotaxane in a liquid-crystalline state†
Takuma Yasuda,Kana Tanabe,Toru Tsuji,Ivan Aprahamian,Takashi Kato
Chemical Communications Pub Date : 01/20/2010 00:00:00 , DOI:10.1039/B922088G
Abstract

Redox-driven mechanical movement, which has been achieved for a liquid-crystalline (LC) bistable [2]rotaxane in the LC phase, is accompanied by obvious electrochromism (electrochemically induced changes in color) of the material. The dumbbell-shaped LC [2]rotaxane with redox-active moieties, which interlocks with an ionic macrocycle, forms ordered redox-active condensed states.

Graphical abstract: A redox-switchable [2]rotaxane in a liquid-crystalline state
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